ES2277396T3 - Procedimiento de fabricacion de papel utilizando un nuevo sistema de retencion que comprende una silice precipitada y un polimero cationico. - Google Patents
Procedimiento de fabricacion de papel utilizando un nuevo sistema de retencion que comprende una silice precipitada y un polimero cationico. Download PDFInfo
- Publication number
- ES2277396T3 ES2277396T3 ES98958307T ES98958307T ES2277396T3 ES 2277396 T3 ES2277396 T3 ES 2277396T3 ES 98958307 T ES98958307 T ES 98958307T ES 98958307 T ES98958307 T ES 98958307T ES 2277396 T3 ES2277396 T3 ES 2277396T3
- Authority
- ES
- Spain
- Prior art keywords
- paper
- silica
- cationic polymer
- retention
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000014759 maintenance of location Effects 0.000 title claims abstract description 65
- 229920006317 cationic polymer Polymers 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000000725 suspension Substances 0.000 claims abstract description 24
- 125000002091 cationic group Chemical group 0.000 claims abstract description 23
- 229920002472 Starch Polymers 0.000 claims abstract description 20
- 239000008107 starch Substances 0.000 claims abstract description 19
- 235000019698 starch Nutrition 0.000 claims abstract description 19
- 239000012764 mineral filler Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 15
- 229920001131 Pulp (paper) Polymers 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000006467 substitution reaction Methods 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 229920000926 Galactomannan Polymers 0.000 claims description 7
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 238000010952 in-situ formation Methods 0.000 claims 1
- 229920002907 Guar gum Polymers 0.000 abstract description 3
- 239000000665 guar gum Substances 0.000 abstract description 3
- 229960002154 guar gum Drugs 0.000 abstract description 3
- 235000010417 guar gum Nutrition 0.000 abstract description 3
- 229920003043 Cellulose fiber Polymers 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 42
- 229910052500 inorganic mineral Inorganic materials 0.000 description 16
- 239000011707 mineral Substances 0.000 description 16
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 239000000835 fiber Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 241000282372 Panthera onca Species 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000219748 Cyamopsis Species 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/31—Gums
- D21H17/32—Guar or other polygalactomannan gum
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9709891A FR2766849B1 (fr) | 1997-08-01 | 1997-08-01 | Procede de fabrication de papier utilisant un nouveau systeme de retention comprenant une silice precipitee et un polymere cationique |
| PCT/FR1998/002598 WO2000032873A1 (fr) | 1997-08-01 | 1998-12-02 | Procede de fabrication de papier utilisant un nouveau systeme de retention comprenant une silice precipitee et un polymere cationique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2277396T3 true ES2277396T3 (es) | 2007-07-01 |
Family
ID=26233725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98958307T Expired - Lifetime ES2277396T3 (es) | 1997-08-01 | 1998-12-02 | Procedimiento de fabricacion de papel utilizando un nuevo sistema de retencion que comprende una silice precipitada y un polimero cationico. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1135555B1 (de) |
| AT (1) | ATE352670T1 (de) |
| AU (1) | AU1439699A (de) |
| CA (1) | CA2354647C (de) |
| DE (1) | DE69836985T2 (de) |
| DK (1) | DK1135555T3 (de) |
| ES (1) | ES2277396T3 (de) |
| FR (1) | FR2766849B1 (de) |
| NO (1) | NO331149B1 (de) |
| WO (1) | WO2000032873A1 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2799663B1 (fr) * | 1999-10-15 | 2001-12-07 | Rhodia Chimie Sa | Utilisation de galactomannanes comme agent emulsifiant |
| FR2879631B1 (fr) * | 2004-12-16 | 2007-02-23 | Snf Sas Soc Par Actions Simpli | Procede pour la fabrication de papier |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0017353B2 (de) * | 1979-03-28 | 1992-04-29 | Ciba Specialty Chemicals Water Treatments Limited | Herstellung von Papier und Pappe |
| JPS60209098A (ja) * | 1984-03-28 | 1985-10-21 | 三井東圧化学株式会社 | 軽量紙およびその製法 |
| SE8403062L (sv) * | 1984-06-07 | 1985-12-08 | Eka Ab | Forfarande vid papperstillverkning |
| US5176891A (en) * | 1988-01-13 | 1993-01-05 | Eka Chemicals, Inc. | Polyaluminosilicate process |
| FR2627176B1 (fr) * | 1988-02-11 | 1990-06-15 | Rhone Poulenc Chimie | Suspension aqueuse stable de silice de precipitation |
| SE9003954L (sv) * | 1990-12-11 | 1992-06-12 | Eka Nobel Ab | Saett foer framstaellning av ark- eller banformiga cellulosafiberinnehaallande produkter |
| US5194120A (en) * | 1991-05-17 | 1993-03-16 | Delta Chemicals | Production of paper and paper products |
| FR2722185B1 (fr) * | 1994-07-07 | 1996-09-27 | Rhone Poulenc Chimie | Suspension concentree de silice de precipitation, procedes pour sa preparation et utilisations de cette suspension |
-
1997
- 1997-08-01 FR FR9709891A patent/FR2766849B1/fr not_active Expired - Fee Related
-
1998
- 1998-12-02 AU AU14396/99A patent/AU1439699A/en not_active Abandoned
- 1998-12-02 CA CA002354647A patent/CA2354647C/fr not_active Expired - Fee Related
- 1998-12-02 WO PCT/FR1998/002598 patent/WO2000032873A1/fr not_active Ceased
- 1998-12-02 DK DK98958307T patent/DK1135555T3/da active
- 1998-12-02 DE DE69836985T patent/DE69836985T2/de not_active Expired - Lifetime
- 1998-12-02 AT AT98958307T patent/ATE352670T1/de not_active IP Right Cessation
- 1998-12-02 EP EP98958307A patent/EP1135555B1/de not_active Expired - Lifetime
- 1998-12-02 ES ES98958307T patent/ES2277396T3/es not_active Expired - Lifetime
-
2001
- 2001-05-30 NO NO20012666A patent/NO331149B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO20012666D0 (no) | 2001-05-30 |
| EP1135555B1 (de) | 2007-01-24 |
| ATE352670T1 (de) | 2007-02-15 |
| EP1135555A1 (de) | 2001-09-26 |
| FR2766849A1 (fr) | 1999-02-05 |
| NO331149B1 (no) | 2011-10-24 |
| DE69836985D1 (de) | 2007-03-15 |
| DK1135555T3 (da) | 2007-05-21 |
| CA2354647A1 (fr) | 2000-06-08 |
| CA2354647C (fr) | 2006-09-19 |
| FR2766849B1 (fr) | 1999-12-24 |
| DE69836985T2 (de) | 2007-06-28 |
| WO2000032873A1 (fr) | 2000-06-08 |
| NO20012666L (no) | 2001-08-02 |
| AU1439699A (en) | 2000-06-19 |
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