ES2354685T3 - Complejo de cobre asimétrico y reacción de ciclopropano que utiliza el mismo. - Google Patents
Complejo de cobre asimétrico y reacción de ciclopropano que utiliza el mismo. Download PDFInfo
- Publication number
- ES2354685T3 ES2354685T3 ES02009051T ES02009051T ES2354685T3 ES 2354685 T3 ES2354685 T3 ES 2354685T3 ES 02009051 T ES02009051 T ES 02009051T ES 02009051 T ES02009051 T ES 02009051T ES 2354685 T3 ES2354685 T3 ES 2354685T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- copper
- acid
- substituted
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
- B01J2231/325—Cyclopropanations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001132016 | 2001-04-27 | ||
| JP2001-132016 | 2001-04-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2354685T3 true ES2354685T3 (es) | 2011-03-17 |
Family
ID=18980097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02009051T Expired - Lifetime ES2354685T3 (es) | 2001-04-27 | 2002-04-23 | Complejo de cobre asimétrico y reacción de ciclopropano que utiliza el mismo. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6858559B2 (2) |
| EP (1) | EP1253135B1 (2) |
| KR (1) | KR20020083457A (2) |
| CN (1) | CN1259322C (2) |
| AT (1) | ATE489356T1 (2) |
| DE (1) | DE60238367D1 (2) |
| ES (1) | ES2354685T3 (2) |
| HU (1) | HU229387B1 (2) |
| ZA (1) | ZA200203301B (2) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL210934B1 (pl) * | 2003-02-07 | 2012-03-30 | Sumitomo Chemical Co | Optycznie czynne pochodne bisoksazoliny, sposób wytwarzania tych związków, substraty i sposób ich wytwarzania |
| CN100398210C (zh) * | 2003-03-31 | 2008-07-02 | 住友化学株式会社 | 光学活性铜催化剂组合物 |
| CN1852887B (zh) * | 2003-09-19 | 2012-08-15 | 住友化学株式会社 | 光学活性环丙烷化合物的制备方法及其所用的不对称铜络合物 |
| ITMI20041211A1 (it) * | 2004-06-16 | 2004-09-16 | Endura Spa | Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo |
| JP5002916B2 (ja) | 2004-07-01 | 2012-08-15 | 住友化学株式会社 | 不斉銅錯体およびそれを用いた光学活性なシクロプロパンカルボン酸エステル化合物の製造方法 |
| EP1783111B1 (en) * | 2004-07-01 | 2015-04-08 | Sumitomo Chemical Company, Limited | Method for producing optically active cyclopropanecarboxylate compound |
| CN100389117C (zh) * | 2004-08-20 | 2008-05-21 | 中国科学院上海有机化学研究所 | 一种具有手性中心的噁唑啉环金属催化剂、合成及用途 |
| CN100348597C (zh) * | 2005-12-29 | 2007-11-14 | 上海交通大学 | 5,5’位连接的1, 1’-联苯类轴手性配体的合成方法 |
| SG193207A1 (en) * | 2008-09-10 | 2013-09-30 | Sumitomo Chemical Co | Method for producing optically active cyclopropane carboxylic acid ester compound, asymmetric copper complex, and optically active salicylideneaminoalcohol compound |
| CN104926747B (zh) * | 2015-06-01 | 2018-09-21 | 中国科学院上海有机化学研究所 | 具有光学活性的环己基噁唑啉配体的合成方法及其用途 |
| CN106045985B (zh) * | 2016-06-14 | 2018-11-09 | 华中师范大学 | 一种双噁唑啉类化合物及制备方法和用途 |
| CN109692708A (zh) * | 2017-10-24 | 2019-04-30 | 沈阳中化农药化工研发有限公司 | 一种不对称环丙化催化剂及其应用 |
| CN111732508B (zh) * | 2019-03-25 | 2022-11-01 | 华东师范大学 | 一种螺环化合物的合成方法 |
| CN114369248B (zh) * | 2020-10-15 | 2022-09-02 | 中国科学院大连化学物理研究所 | 一种手性含硅聚酯及其合成方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4033976A (en) * | 1975-10-28 | 1977-07-05 | Imc Chemical Group, Inc. | Copper-oxazoline complex |
| HU210648B (en) | 1983-09-15 | 1995-06-28 | Jozsef Muskovits | Process for preparing cycloproane-carboxylic acid esters |
| US5298623A (en) | 1991-11-08 | 1994-03-29 | Massachusetts Institute Of Technology | Cu complexes of bis-oxazolines and their use |
| US6011169A (en) | 1997-07-14 | 2000-01-04 | Sumitomo Chemical Company, Limited | Process for producing optically active cyclopropanecaboxylic acid esters |
| CA2244417C (en) | 1997-08-05 | 2006-07-18 | Sumitomo Chemical Co., Ltd. | Optically active bisoxazoline compounds, production and use thereof |
| GB9725455D0 (en) * | 1997-12-02 | 1998-01-28 | Univ Warwick | Supported polymerisation catalyst |
| US20040133009A1 (en) * | 2001-02-17 | 2004-07-08 | Jorg Schottek | Transition metal compound provided as a catalyst constituent, and use thereof for producing polyolefins |
-
2002
- 2002-04-23 AT AT02009051T patent/ATE489356T1/de not_active IP Right Cessation
- 2002-04-23 ES ES02009051T patent/ES2354685T3/es not_active Expired - Lifetime
- 2002-04-23 EP EP02009051A patent/EP1253135B1/en not_active Expired - Lifetime
- 2002-04-23 DE DE60238367T patent/DE60238367D1/de not_active Expired - Lifetime
- 2002-04-24 CN CNB021183279A patent/CN1259322C/zh not_active Expired - Fee Related
- 2002-04-24 HU HU0201357A patent/HU229387B1/hu not_active IP Right Cessation
- 2002-04-24 US US10/128,237 patent/US6858559B2/en not_active Expired - Fee Related
- 2002-04-25 ZA ZA200203301A patent/ZA200203301B/xx unknown
- 2002-04-25 KR KR1020020022698A patent/KR20020083457A/ko not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| ATE489356T1 (de) | 2010-12-15 |
| ZA200203301B (en) | 2002-12-04 |
| US20020177718A1 (en) | 2002-11-28 |
| CN1259322C (zh) | 2006-06-14 |
| KR20020083457A (ko) | 2002-11-02 |
| HU229387B1 (en) | 2013-11-28 |
| DE60238367D1 (de) | 2011-01-05 |
| EP1253135A1 (en) | 2002-10-30 |
| CN1384105A (zh) | 2002-12-11 |
| HU0201357D0 (2) | 2002-06-29 |
| HUP0201357A3 (en) | 2004-06-28 |
| US6858559B2 (en) | 2005-02-22 |
| EP1253135B1 (en) | 2010-11-24 |
| HUP0201357A2 (hu) | 2003-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2354685T3 (es) | Complejo de cobre asimétrico y reacción de ciclopropano que utiliza el mismo. | |
| Kobayashi et al. | Catalytic asymmetric aldol reaction of the silyl enol ether of acetic acid thioester with aldehydes using chiral tin (II) Lewis acid | |
| KR100537324B1 (ko) | 광학활성비스옥사졸린화합물,이의제조방법및용도 | |
| EP1120393B1 (en) | A process for producing 3,3-dimethyl-2-formylcyclopropane-carboxylic acid ester | |
| EP1120401A2 (en) | Chiral copper complex catalyst composition and asymmetric production process using the same | |
| JP5002916B2 (ja) | 不斉銅錯体およびそれを用いた光学活性なシクロプロパンカルボン酸エステル化合物の製造方法 | |
| US7009079B2 (en) | Chiral copper complex and production processes thereof and using the same | |
| EP1607136B1 (en) | Optically active copper catalyst composition | |
| EP0303636B1 (en) | A process for the preparation of pyrethroid type ester compounds | |
| JPH0153850B2 (2) | ||
| JP4126763B2 (ja) | 光学活性なビスオキサゾリン化合物、その製造法およびその用途 | |
| US7709651B2 (en) | Process for producing optically active cyclopropane compound and asymmetric copper complex for use in the same | |
| US6011169A (en) | Process for producing optically active cyclopropanecaboxylic acid esters | |
| US20070287870A1 (en) | Method of Producing Macrocyclic Ketone, and Intermediate Thereof | |
| EP1783111B1 (en) | Method for producing optically active cyclopropanecarboxylate compound | |
| JP3991455B2 (ja) | 光学活性な菊酸エステルの製造法 | |
| JP5002915B2 (ja) | 光学活性なシクロプロパンカルボン酸エステル化合物の製造方法およびそれに用いる不斉銅錯体 | |
| JP4631369B2 (ja) | 光学活性なシクロプロパン化合物の製造方法およびそれに用いる不斉銅錯体 | |
| JP4742423B2 (ja) | 不斉銅錯体の製造法およびそれを用いる光学活性シクロプロパン化合物の製造法 | |
| JP4839528B2 (ja) | 不斉コバルト錯体およびそれを触媒とする光学活性シクロプロパン化合物の製造方法 |