ES2360289T3 - Proceso de recubrimiento de inversión de múltiples pasos. - Google Patents

Proceso de recubrimiento de inversión de múltiples pasos. Download PDF

Info

Publication number: ES2360289T3
Authority: ES; Spain
Prior art keywords: moiety; zinc; ions; phosphate; process defined
Prior art date: 2003-12-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES04028997T

Other languages

English (en)

Spanish (es)

Inventor

Bernd Schenzle

Michael L. Sienkowski

Bruce H. Goodreau

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-12-29

Filing date

2004-12-07

Publication date

2011-06-02

2004-12-07 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2011-06-02 Application granted granted Critical

2011-06-02 Publication of ES2360289T3 publication Critical patent/ES2360289T3/es

2024-12-07 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 94
230000008569 process Effects 0.000 title claims abstract description 87
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 76
229910019142 PO4 Inorganic materials 0.000 claims abstract description 75
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 73
229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 73
239000010452 phosphate Substances 0.000 claims abstract description 71
239000011701 zinc Substances 0.000 claims abstract description 66
229910052725 zinc Inorganic materials 0.000 claims abstract description 63
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 57
229910052782 aluminium Inorganic materials 0.000 claims abstract description 54
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 52
238000000576 coating method Methods 0.000 claims abstract description 52
239000011248 coating agent Substances 0.000 claims abstract description 44
229910000831 Steel Inorganic materials 0.000 claims abstract description 39
239000010959 steel Substances 0.000 claims abstract description 39
229910001335 Galvanized steel Inorganic materials 0.000 claims abstract description 31
239000008397 galvanized steel Substances 0.000 claims abstract description 31
229910052751 metal Inorganic materials 0.000 claims abstract description 27
239000002184 metal Substances 0.000 claims abstract description 27
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 19
239000002131 composite material Substances 0.000 claims abstract description 18
239000000126 substance Substances 0.000 claims abstract description 14
229910000838 Al alloy Inorganic materials 0.000 claims abstract description 12
229910001297 Zn alloy Inorganic materials 0.000 claims abstract description 11
-1 nitrite ions Chemical class 0.000 claims description 73
239000000203 mixture Substances 0.000 claims description 45
238000011282 treatment Methods 0.000 claims description 39
229920000642 polymer Polymers 0.000 claims description 34
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 25
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 25
239000002253 acid Substances 0.000 claims description 18
125000004432 carbon atom Chemical group C* 0.000 claims description 18
125000000217 alkyl group Chemical group 0.000 claims description 16
125000003118 aryl group Chemical group 0.000 claims description 16
229910002651 NO3 Inorganic materials 0.000 claims description 15
239000000956 alloy Substances 0.000 claims description 14
229920000620 organic polymer Polymers 0.000 claims description 14
229910045601 alloy Inorganic materials 0.000 claims description 13
229920001665 Poly-4-vinylphenol Polymers 0.000 claims description 11
150000002500 ions Chemical class 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 8
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
239000000047 product Substances 0.000 claims description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
125000004103 aminoalkyl group Chemical group 0.000 claims description 5
150000001450 anions Chemical class 0.000 claims description 5
229920001577 copolymer Polymers 0.000 claims description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
125000005358 mercaptoalkyl group Chemical group 0.000 claims description 5
229910052708 sodium Inorganic materials 0.000 claims description 5
239000011734 sodium Substances 0.000 claims description 5
230000004580 weight loss Effects 0.000 claims description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 claims description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
150000003863 ammonium salts Chemical class 0.000 claims description 4
239000011737 fluorine Substances 0.000 claims description 4
229910052731 fluorine Inorganic materials 0.000 claims description 4
229920001519 homopolymer Polymers 0.000 claims description 4
229910052700 potassium Inorganic materials 0.000 claims description 4
239000011591 potassium Substances 0.000 claims description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
125000002252 acyl group Chemical group 0.000 claims description 3
125000006177 alkyl benzyl group Chemical group 0.000 claims description 3
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 3
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
150000001768 cations Chemical group 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
229910001431 copper ion Inorganic materials 0.000 claims description 3
125000001188 haloalkyl group Chemical group 0.000 claims description 3
229910052744 lithium Inorganic materials 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical class [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 3
150000004714 phosphonium salts Chemical class 0.000 claims description 3
238000012643 polycondensation polymerization Methods 0.000 claims description 3
125000006684 polyhaloalkyl group Chemical group 0.000 claims description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
150000003335 secondary amines Chemical class 0.000 claims description 3
XBMIINABKLOSJG-SOUVJXGZSA-N (2r,3s,4s)-6-[benzyl(methyl)amino]-2-ethenylhexane-1,2,3,4,5,5-hexol Chemical compound OC[C@](O)(C=C)[C@@H](O)[C@H](O)C(O)(O)CN(C)CC1=CC=CC=C1 XBMIINABKLOSJG-SOUVJXGZSA-N 0.000 claims description 2
HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical class CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims description 2
239000007859 condensation product Substances 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 2
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
229910001437 manganese ion Inorganic materials 0.000 claims 1
125000005395 methacrylic acid group Chemical class 0.000 claims 1
108090000623 proteins and genes Proteins 0.000 claims 1
239000000758 substrate Substances 0.000 abstract description 16
239000010802 sludge Substances 0.000 abstract description 15
239000003973 paint Substances 0.000 abstract description 13
238000006243 chemical reaction Methods 0.000 abstract description 5
238000012544 monitoring process Methods 0.000 abstract description 2
238000003618 dip coating Methods 0.000 abstract 1
239000000243 solution Substances 0.000 description 80
239000000463 material Substances 0.000 description 21
239000010410 layer Substances 0.000 description 18
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
230000015572 biosynthetic process Effects 0.000 description 12
238000007654 immersion Methods 0.000 description 12
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 11
230000007797 corrosion Effects 0.000 description 10
238000005260 corrosion Methods 0.000 description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
239000013078 crystal Substances 0.000 description 8
239000007921 spray Substances 0.000 description 8
229910052759 nickel Inorganic materials 0.000 description 7
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238000005536 corrosion prevention Methods 0.000 description 5
FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 4
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BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
239000003513 alkali Substances 0.000 description 4
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229910052742 iron Inorganic materials 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
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239000010960 cold rolled steel Substances 0.000 description 3
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
239000011572 manganese Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 2
SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
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JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 2
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RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical class CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
LDDQLRUQCUTJBB-UHFFFAOYSA-O azanium;hydrofluoride Chemical compound [NH4+].F LDDQLRUQCUTJBB-UHFFFAOYSA-O 0.000 description 1
239000002585 base Substances 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000011365 complex material Substances 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 description 1
230000002950 deficient Effects 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
229960004419 dimethyl fumarate Drugs 0.000 description 1
LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical class C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
PQJYOOFQDXGDDS-ZCXUNETKSA-N dinonyl (z)-but-2-enedioate Chemical compound CCCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCCC PQJYOOFQDXGDDS-ZCXUNETKSA-N 0.000 description 1
TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 1
NQPOXJIXYCVBDO-UHFFFAOYSA-N dioctyl 2-methylidenebutanedioate Chemical compound CCCCCCCCOC(=O)CC(=C)C(=O)OCCCCCCCC NQPOXJIXYCVBDO-UHFFFAOYSA-N 0.000 description 1
FNMTVMWFISHPEV-WAYWQWQTSA-N dipropan-2-yl (z)-but-2-enedioate Chemical compound CC(C)OC(=O)\C=C/C(=O)OC(C)C FNMTVMWFISHPEV-WAYWQWQTSA-N 0.000 description 1
IJBBERPAEBYDJT-UHFFFAOYSA-N dipropan-2-yl 2-methylidenebutanedioate Chemical compound CC(C)OC(=O)CC(=C)C(=O)OC(C)C IJBBERPAEBYDJT-UHFFFAOYSA-N 0.000 description 1
DFQSWFGKYUFIFW-UHFFFAOYSA-N dipropyl 2-methylidenebutanedioate Chemical compound CCCOC(=O)CC(=C)C(=O)OCCC DFQSWFGKYUFIFW-UHFFFAOYSA-N 0.000 description 1
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical compound [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 1
230000008570 general process Effects 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
239000004519 grease Substances 0.000 description 1
PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
150000002443 hydroxylamines Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
229910000398 iron phosphate Inorganic materials 0.000 description 1
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229920005610 lignin Chemical class 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
WFKDPJRCBCBQNT-UHFFFAOYSA-N n,2-dimethylprop-2-enamide Chemical compound CNC(=O)C(C)=C WFKDPJRCBCBQNT-UHFFFAOYSA-N 0.000 description 1
DLJMSHXCPBXOKX-UHFFFAOYSA-N n,n-dibutylprop-2-enamide Chemical compound CCCCN(C(=O)C=C)CCCC DLJMSHXCPBXOKX-UHFFFAOYSA-N 0.000 description 1
KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 description 1
ZIWDVJPPVMGJGR-UHFFFAOYSA-N n-ethyl-2-methylprop-2-enamide Chemical compound CCNC(=O)C(C)=C ZIWDVJPPVMGJGR-UHFFFAOYSA-N 0.000 description 1
KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229940005654 nitrite ion Drugs 0.000 description 1
229920003986 novolac Chemical class 0.000 description 1
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229940085991 phosphate ion Drugs 0.000 description 1
238000005554 pickling Methods 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
235000010288 sodium nitrite Nutrition 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229920001864 tannin Chemical class 0.000 description 1
239000001648 tannin Chemical class 0.000 description 1
235000018553 tannin Nutrition 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1
MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
- C23C22/365—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations containing also zinc and nickel cations
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process

Landscapes

Chemical & Material Sciences (AREA)
Metallurgy (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Treatment Of Metals (AREA)
Laminated Bodies (AREA)
Application Of Or Painting With Fluid Materials (AREA)
Road Signs Or Road Markings (AREA)
Compounds Of Unknown Constitution (AREA)
Auxiliary Devices For Music (AREA)

ES04028997T 2003-12-29 2004-12-07 Proceso de recubrimiento de inversión de múltiples pasos. Expired - Lifetime ES2360289T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US745539		1996-11-12
US10/745,539 US20050145303A1 (en)	2003-12-29	2003-12-29	Multiple step conversion coating process

Publications (1)

Publication Number	Publication Date
ES2360289T3 true ES2360289T3 (es)	2011-06-02

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ID=34574735

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES04028997T Expired - Lifetime ES2360289T3 (es)	2003-12-29	2004-12-07	Proceso de recubrimiento de inversión de múltiples pasos.

Country Status (7)

Country	Link
US (1)	US20050145303A1 (de)
EP (1)	EP1550740B1 (de)
AT (1)	ATE501284T1 (de)
CA (1)	CA2488199A1 (de)
DE (1)	DE602004031707D1 (de)
ES (1)	ES2360289T3 (de)
PL (1)	PL1550740T3 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP5462467B2 (ja) *	2008-10-31	2014-04-02	日本パーカライジング株式会社	金属材料用化成処理液および処理方法
IT1397902B1 (it) *	2010-01-26	2013-02-04	Np Coil Dexter Ind Srl	Processi di pretrattamento alla verniciatura, a basso impatto ambientale, alternativi ai trattamenti tradizionali di fosfatazione.
DE102010030697A1 (de) *	2010-06-30	2012-01-05	Henkel Ag & Co. Kgaa	Verfahren zur selektiven Phosphatierung einer Verbundmetallkonstruktion
US20130230425A1 (en) *	2011-09-02	2013-09-05	Ppg Industries Ohio, Inc.	Two-step zinc phosphating process
DE102012215679A1 (de)	2012-09-04	2014-05-15	Henkel Ag & Co. Kgaa	Verfahren zur korrosionsschützenden Oberflächenbehandlung von metallischen Bauteilen in Serie
US10435806B2 (en)	2015-10-12	2019-10-08	Prc-Desoto International, Inc.	Methods for electrolytically depositing pretreatment compositions

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5165041A (en) *	1974-12-04	1976-06-05	Nippon Packaging Kk	Kinzokuno rinsanenhimakukeiseihoho
FR2389683A1 (en) *	1977-05-03	1978-12-01	Parker Ste Continentale	Phosphating soln. contg. boron fluoride - for phosphating ferrous and non-ferrous surfaces, e.g. steel, zinc and aluminium
US4191596A (en)	1978-09-06	1980-03-04	Union Carbide Corporation	Method and compositions for coating aluminum
AU2448684A (en) *	1983-03-02	1984-09-06	Parker Chemical Company	Metal treatment before phosphate coating
JPS63100185A (ja)	1986-10-16	1988-05-02	Nippon Parkerizing Co Ltd	冷延鋼板または亜鉛めっき鋼板のりん酸塩化成処理方法
US5039770A (en)	1987-12-04	1991-08-13	Henkel Corporation	Treatment and after-treatment of metal with polyphenol compounds
DE3824063A1 (de) *	1988-07-15	1990-01-18	Metallgesellschaft Ag	Verfahren zur verminderung der verkrustung von phosphatieranlagen
KR100197145B1 (ko) *	1989-12-19	1999-06-15	후지이 히로시	금속표면의 인산아연 처리방법
US6019858A (en) *	1991-07-29	2000-02-01	Henkel Corporation	Zinc phosphate conversion coating and process
DE4317217A1 (de) *	1993-05-24	1994-12-01	Henkel Kgaa	Chromfreie Konversionsbehandlung von Aluminium
EP0653502A3 (de) *	1993-11-11	1995-08-09	Nihon Parkerizing	Verbundstahlwerkstück plattiert mit Zink-enthaltenden Metall und Verfahren zur seiner Herstellung.
JP3185966B2 (ja) *	1996-04-10	2001-07-11	日本ペイント株式会社	金属成型物のリン酸亜鉛皮膜処理方法
DE19735314C2 (de)	1996-09-13	2001-05-23	Bayerische Motoren Werke Ag	Verfahren zur Vorbehandlung von Bauteilen
US5900073A (en) *	1996-12-04	1999-05-04	Henkel Corporation	Sludge reducing zinc phosphating process and composition
DE19705701A1 (de) *	1997-02-14	1998-08-20	Henkel Kgaa	Verfahren zur Niedrig-Nickel-Phosphatierung mit metallhaltiger Nachspülung
CA2303183C (en)	1997-09-10	2009-09-01	Henkel Kommanditgesellschaft Auf Aktien	Pretreatment before painting of composite metal structures containing aluminum portions
US6720032B1 (en) *	1997-09-10	2004-04-13	Henkel Kommanditgesellschaft Auf Aktien	Pretreatment before painting of composite metal structures containing aluminum portions
US6868426B1 (en) *	1999-07-07	2005-03-15	Jeffrey W. Mankoff	Virtual document organizer system and method
CN1387587A (zh)	1999-11-04	2002-12-25	亨凯尔公司	锌磷化处理法和污染可能性减小的组合物
JP4658339B2 (ja) *	2001-01-17	2011-03-23	日本ペイント株式会社	金属表面処理方法
ES2462291T3 (es) *	2001-02-16	2014-05-22	Henkel Ag & Co. Kgaa	Proceso de tratamiento de artículos polimetálicos
DE10118552A1 (de) *	2001-04-14	2002-10-17	Henkel Kgaa	Bestimmung der Beschleunigerkonzentration in Phosphatierbäder
EP1371756A2 (de) *	2002-06-12	2003-12-17	Nissan Motor Co., Ltd.	Vorrichtung und Verfahren zur Vorbehandlung vor einer Lackierung

2003
- 2003-12-29 US US10/745,539 patent/US20050145303A1/en not_active Abandoned
2004
- 2004-11-22 CA CA002488199A patent/CA2488199A1/en not_active Abandoned
- 2004-12-07 AT AT04028997T patent/ATE501284T1/de not_active IP Right Cessation
- 2004-12-07 PL PL04028997T patent/PL1550740T3/pl unknown
- 2004-12-07 EP EP04028997A patent/EP1550740B1/de not_active Expired - Lifetime
- 2004-12-07 DE DE602004031707T patent/DE602004031707D1/de not_active Expired - Lifetime
- 2004-12-07 ES ES04028997T patent/ES2360289T3/es not_active Expired - Lifetime

Also Published As

Publication number	Publication date
PL1550740T3 (pl)	2011-08-31
US20050145303A1 (en)	2005-07-07
ATE501284T1 (de)	2011-03-15
EP1550740A1 (de)	2005-07-06
CA2488199A1 (en)	2005-06-29
EP1550740B1 (de)	2011-03-09
DE602004031707D1 (de)	2011-04-21

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US6395105B1 (en)	2002-05-28	Phosphating process with a metalliferous re-rinsing stage
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CN1131444A (zh)	1996-09-18	单面镀锌钢条的磷化处理方法
JP2004501280A (ja)	2004-01-15	化成処理溶液に加える接合剤
EP1669475B1 (de)	2009-10-28	Vorbehandlung für eine Metalloberfläche und Pulverbeschichtungsschritt für ein Fahrgestell
ITMI941715A1 (it)	1996-02-05	Soluzione fosfatica acquosa acida e processo di fosfatazione di superfici metalliche che la utilizza
AU705531B2 (en)	1999-05-27	Zinc-phosphatizing using low concentrations of nickel and/or cobalt
CN101137766A (zh)	2008-03-05	化学转化处理剂和表面处理的金属
WO2006138540A1 (en)	2006-12-28	Method for treatment of chemically passivated galvanized surfaces to improve paint adhesion
AU7573498A (en)	1998-12-11	Water-based liquid treatment for aluminum and its alloys
MXPA00002319A (en)	2001-05-17	Pretreatment before painting of composite metal structures containing aluminum portions
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