ES2365803T3 - Procedimiento de fischer-tropsch. - Google Patents

Procedimiento de fischer-tropsch. Download PDF

Info

Publication number: ES2365803T3
Authority: ES; Spain
Prior art keywords: high shear; shear mixing; zones; suspension; reactor vessel
Prior art date: 2001-05-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES02774046T

Other languages

English (en)

Spanish (es)

Inventor

Josephus Johannes Helena Maria Font Freide

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Johnson Matthey Davy Technologies Ltd

BP Exploration Operating Co Ltd

Original Assignee

BP Exploration Operating Co Ltd

Davy Process Technology Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-05-25

Filing date

2002-05-17

Publication date

2011-10-11

2002-05-17 Application filed by BP Exploration Operating Co Ltd, Davy Process Technology Ltd filed Critical BP Exploration Operating Co Ltd

2011-10-11 Application granted granted Critical

2011-10-11 Publication of ES2365803T3 publication Critical patent/ES2365803T3/es

2022-05-17 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 52
239000000725 suspension Substances 0.000 claims abstract description 78
238000002156 mixing Methods 0.000 claims abstract description 74
238000003786 synthesis reaction Methods 0.000 claims abstract description 52
230000015572 biosynthetic process Effects 0.000 claims abstract description 51
239000003054 catalyst Substances 0.000 claims abstract description 47
239000007788 liquid Substances 0.000 claims abstract description 42
229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
239000000376 reactant Substances 0.000 claims abstract description 20
238000006243 chemical reaction Methods 0.000 claims abstract description 13
239000000203 mixture Substances 0.000 claims abstract description 9
239000002245 particle Substances 0.000 claims abstract description 9
239000007789 gas Substances 0.000 claims description 107
238000005086 pumping Methods 0.000 claims description 15
125000004122 cyclic group Chemical group 0.000 claims description 14
238000004064 recycling Methods 0.000 claims description 10
239000004215 Carbon black (E152) Substances 0.000 claims description 9
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 4
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
238000007664 blowing Methods 0.000 claims description 3
239000011787 zinc oxide Substances 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims 1
HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
239000002002 slurry Substances 0.000 description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
239000011440 grout Substances 0.000 description 4
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
229940095068 tetradecene Drugs 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
238000005054 agglomeration Methods 0.000 description 3
230000002776 aggregation Effects 0.000 description 3
238000001816 cooling Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
238000002407 reforming Methods 0.000 description 3
229910052707 ruthenium Inorganic materials 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000011144 upstream manufacturing Methods 0.000 description 3
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
238000004891 communication Methods 0.000 description 2
239000002826 coolant Substances 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
229910052735 hafnium Inorganic materials 0.000 description 2
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000005259 measurement Methods 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229910052702 rhenium Inorganic materials 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
238000004062 sedimentation Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229910052684 Cerium Inorganic materials 0.000 description 1
-1 Group IVB oxides Inorganic materials 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000000889 atomisation Methods 0.000 description 1
238000002453 autothermal reforming Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000000629 steam reforming Methods 0.000 description 1
230000001052 transient effect Effects 0.000 description 1
238000010977 unit operation Methods 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
- B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00628—Controlling the composition of the reactive mixture
- B01J2208/00637—Means for stopping or slowing down the reaction

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Combustion & Propulsion (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

ES02774046T 2001-05-25 2002-05-17 Procedimiento de fischer-tropsch. Expired - Lifetime ES2365803T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB0112801A GB0112801D0 (en)	2001-05-25	2001-05-25	Process
GB0112801		2001-05-25

Publications (1)

Publication Number	Publication Date
ES2365803T3 true ES2365803T3 (es)	2011-10-11

Family

ID=9915321

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES02774046T Expired - Lifetime ES2365803T3 (es)	2001-05-25	2002-05-17	Procedimiento de fischer-tropsch.

Country Status (10)

Country	Link
US (1)	US7005456B2 (de)
EP (1)	EP1397328B1 (de)
JP (1)	JP2004536903A (de)
AR (1)	AR033929A1 (de)
AT (1)	ATE507196T1 (de)
AU (1)	AU2002307958A1 (de)
DE (1)	DE60239866D1 (de)
ES (1)	ES2365803T3 (de)
GB (1)	GB0112801D0 (de)
WO (1)	WO2002096834A2 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ITMI20031777A1 (it) *	2003-09-18	2005-03-19	Enitecnologie Spa	Procedimento per la gestione di un reattore adatto a reazioni eterogenee in combinazioni con reazioni che si realizzano in sistemi trifasici
FR2878845B1 (fr) *	2004-12-03	2007-01-12	Inst Francais Du Petrole	Procede d'interruption provisoire d'une reaction de type fischer-tropsch dans un reacteur a lit triphasique
WO2007127898A2 (en) *	2006-04-27	2007-11-08	Syntroleum Corporation	Method of delivery, replacement, and removal of fischer-tropsch catalyst
US7494627B2 (en) *	2006-08-09	2009-02-24	Total Petrochemicals Research Feluy	Device and method for the optimization of the injection of reactants into a reactor
EP2152655B1 (de) *	2007-05-29	2017-07-05	LG Chem. Ltd.	Verfahren zur hydroformylierung von olefinen und vorrichtung dafür
JP5501365B2 (ja) *	2009-08-31	2014-05-21	独立行政法人石油天然ガス・金属鉱物資源機構	スラリー調製方法、スラリー調製装置、炭化水素合成反応装置、及び炭化水素合成反応システム
KR101298336B1 (ko)	2010-03-09	2013-08-20	주식회사 엘지화학	반응효율이 뛰어난 옥소반응기
JP5869397B2 (ja) *	2012-03-28	2016-02-24	独立行政法人石油天然ガス・金属鉱物資源機構	気泡塔型スラリー床反応器のスタートアップ方法
GB201702248D0 (en)	2017-02-10	2017-03-29	Bp Plc	Start-up procedure for a fischer-tropsch process
CN108285809B (zh) *	2018-01-08	2020-02-21	内蒙古伊泰煤基新材料研究院有限公司	双系列费托反应装置的开车方法
CN110227390A (zh) *	2019-07-10	2019-09-13	佛山市巴盛诺新材料科技有限公司	一种利用脲和醇盐制备聚γ-丁内酯的装置和方法
CN111054279A (zh) *	2019-12-31	2020-04-24	广东雪迪龙环境科技有限公司	一种用于亚硫酸镁的催化氧化工艺装置及方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB728543A (en)	1952-03-05	1955-04-20	Koppers Gmbh Heinrich	Process for the synthesis of hydrocarbons
AU774304B2 (en) *	1999-10-14	2004-06-24	Sasol Technology (Pty) Limited	Handling of a catalyst
GB9928132D0 (en) *	1999-11-26	2000-01-26	Bp Amoco Plc	Process

2001
- 2001-05-25 GB GB0112801A patent/GB0112801D0/en not_active Ceased
2002
- 2002-05-17 DE DE60239866T patent/DE60239866D1/de not_active Expired - Lifetime
- 2002-05-17 ES ES02774046T patent/ES2365803T3/es not_active Expired - Lifetime
- 2002-05-17 US US10/476,613 patent/US7005456B2/en not_active Expired - Lifetime
- 2002-05-17 WO PCT/GB2002/002267 patent/WO2002096834A2/en not_active Ceased
- 2002-05-17 AT AT02774046T patent/ATE507196T1/de not_active IP Right Cessation
- 2002-05-17 AU AU2002307958A patent/AU2002307958A1/en not_active Abandoned
- 2002-05-17 JP JP2003500014A patent/JP2004536903A/ja active Pending
- 2002-05-17 EP EP20020774046 patent/EP1397328B1/de not_active Expired - Lifetime
- 2002-05-24 AR ARP020101944 patent/AR033929A1/es not_active Application Discontinuation

Also Published As

Publication number	Publication date
US20040147623A1 (en)	2004-07-29
WO2002096834A3 (en)	2003-05-30
GB0112801D0 (en)	2001-07-18
US7005456B2 (en)	2006-02-28
DE60239866D1 (de)	2011-06-09
EP1397328B1 (de)	2011-04-27
AU2002307958A1 (en)	2002-12-09
ATE507196T1 (de)	2011-05-15
EP1397328A2 (de)	2004-03-17
JP2004536903A (ja)	2004-12-09
AR033929A1 (es)	2004-01-07
WO2002096834A2 (en)	2002-12-05

Publication	Publication Date	Title
US7115670B2 (en)	2006-10-03	Fischer-Tropsch synthesis process
US7034062B2 (en)	2006-04-25	Fischer-tropsch process
US7005456B2 (en)	2006-02-28	Fischer-Tropsch process
US7138434B2 (en)	2006-11-21	Fischer-Tropsch process
US7071238B2 (en)	2006-07-04	Fischer-tropsch process in the presence of a coolant introduced into the reactor system
OA12695A (en)	2006-06-21	Fischer-tropsch process.
US6903140B2 (en)	2005-06-07	Fischer-tropsch process
AU2002256789A1 (en)	2003-05-08	Fischer-Tropsch process
CN1307285C (zh)	2007-03-28	费托工艺
AU2002302752A1 (en)	2003-05-08	Fischer-Tropsch process
US7008968B2 (en)	2006-03-07	Fischer-tropsch process
AU2002302755B2 (en)	2007-09-27	Fischer-Tropsch process
ZA200308536B (en)	2004-09-03	Fischer-Tropsch process.
AU2002257930A1 (en)	2002-12-09	Fischer-tropsch process
ZA200308545B (en)	2004-09-03	Fischer-Tropsch process.
AU2002302755A1 (en)	2003-05-08	Fischer-Tropsch process