ES2375407T3 - Separación de fases de impurezas de dispositivos electroquímicos. - Google Patents
Separación de fases de impurezas de dispositivos electroquímicos. Download PDFInfo
- Publication number
- ES2375407T3 ES2375407T3 ES07017097T ES07017097T ES2375407T3 ES 2375407 T3 ES2375407 T3 ES 2375407T3 ES 07017097 T ES07017097 T ES 07017097T ES 07017097 T ES07017097 T ES 07017097T ES 2375407 T3 ES2375407 T3 ES 2375407T3
- Authority
- ES
- Spain
- Prior art keywords
- layer
- electrode
- cell
- metal oxides
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012535 impurity Substances 0.000 title claims description 116
- 238000000926 separation method Methods 0.000 title description 13
- 239000002245 particle Substances 0.000 claims abstract description 105
- 239000003792 electrolyte Substances 0.000 claims abstract description 57
- 239000007787 solid Substances 0.000 claims abstract description 41
- 239000011148 porous material Substances 0.000 claims abstract description 26
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 17
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims abstract description 14
- 239000002001 electrolyte material Substances 0.000 claims abstract description 10
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims description 59
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 42
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 21
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 12
- 229910002976 CaZrO3 Inorganic materials 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 9
- 229910014031 strontium zirconium oxide Inorganic materials 0.000 claims description 9
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 9
- 229910021523 barium zirconate Inorganic materials 0.000 claims description 6
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 239000012078 proton-conducting electrolyte Substances 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 2
- 229910021525 ceramic electrolyte Inorganic materials 0.000 claims 1
- 239000010416 ion conductor Substances 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 claims 1
- 239000000725 suspension Substances 0.000 description 48
- 239000012071 phase Substances 0.000 description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 18
- 239000000843 powder Substances 0.000 description 17
- 230000009467 reduction Effects 0.000 description 17
- 238000001179 sorption measurement Methods 0.000 description 17
- 239000000654 additive Substances 0.000 description 13
- 238000001816 cooling Methods 0.000 description 13
- 239000002243 precursor Substances 0.000 description 12
- 239000000446 fuel Substances 0.000 description 11
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 239000012528 membrane Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000005520 cutting process Methods 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 238000010345 tape casting Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052681 coesite Inorganic materials 0.000 description 7
- 229910052906 cristobalite Inorganic materials 0.000 description 7
- 239000000395 magnesium oxide Substances 0.000 description 7
- 238000007650 screen-printing Methods 0.000 description 7
- 235000012239 silicon dioxide Nutrition 0.000 description 7
- 229910052682 stishovite Inorganic materials 0.000 description 7
- 229910052905 tridymite Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000001483 mobilizing effect Effects 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
- 238000007792 addition Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- -1 oxygen ions Chemical class 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 150000002823 nitrates Chemical group 0.000 description 3
- 238000013517 stratification Methods 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 229910052882 wollastonite Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052839 forsterite Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910002085 magnesia-stabilized zirconia Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000007592 spray painting technique Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 229910019526 La0.6Sr0.4Fe0.6Co0.4O3 Inorganic materials 0.000 description 1
- 229910002140 La0.6Sr0.4Fe0.8Co0.2O3−δ Inorganic materials 0.000 description 1
- 229910016978 MnOx Inorganic materials 0.000 description 1
- 241000968352 Scandia <hydrozoan> Species 0.000 description 1
- 229910003383 SrSiO3 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052661 anorthite Inorganic materials 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000012215 calcium aluminium silicate Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000031902 chemoattractant activity Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000010411 electrocatalyst Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- BXNFVPMHMPQBRO-UHFFFAOYSA-N magnesium nickel(2+) oxygen(2-) Chemical compound [O--].[O--].[Mg++].[Ni++] BXNFVPMHMPQBRO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- HJGMWXTVGKLUAQ-UHFFFAOYSA-N oxygen(2-);scandium(3+) Chemical compound [O-2].[O-2].[O-2].[Sc+3].[Sc+3] HJGMWXTVGKLUAQ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- NDTZMEKCGHOCBU-UHFFFAOYSA-N strontium;dioxido(dioxo)manganese Chemical compound [Sr+2].[O-][Mn]([O-])(=O)=O NDTZMEKCGHOCBU-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 239000012720 thermal barrier coating Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
- H01M4/8889—Cosintering or cofiring of a catalytic active layer with another type of layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Catalysts (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07017097A EP2031677B1 (de) | 2007-08-31 | 2007-08-31 | Entfernung von Verunreinigungsphasen aus elektrochemischen Vorrichtungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2375407T3 true ES2375407T3 (es) | 2012-02-29 |
Family
ID=38578566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07017097T Active ES2375407T3 (es) | 2007-08-31 | 2007-08-31 | Separación de fases de impurezas de dispositivos electroquímicos. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9077021B2 (de) |
| EP (1) | EP2031677B1 (de) |
| JP (1) | JP5430009B2 (de) |
| KR (1) | KR101192701B1 (de) |
| CN (1) | CN101796676B (de) |
| AT (1) | ATE528812T1 (de) |
| AU (1) | AU2008291251B2 (de) |
| CA (1) | CA2697467C (de) |
| DK (1) | DK2031677T3 (de) |
| ES (1) | ES2375407T3 (de) |
| NO (1) | NO20100217L (de) |
| RU (1) | RU2446515C2 (de) |
| WO (1) | WO2009027100A1 (de) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5448382B2 (ja) * | 2008-07-22 | 2014-03-19 | 三菱重工業株式会社 | 固体電解質型燃料電池の発電膜の製造方法 |
| JP4872027B1 (ja) * | 2010-11-01 | 2012-02-08 | 日本碍子株式会社 | 固体酸化物型燃料電池 |
| JP4928642B1 (ja) * | 2010-12-03 | 2012-05-09 | 日本碍子株式会社 | 固体酸化物型燃料電池 |
| JP5502180B2 (ja) * | 2011-11-24 | 2014-05-28 | 日本碍子株式会社 | 固体酸化物型燃料電池 |
| WO2013094260A1 (ja) * | 2011-12-19 | 2013-06-27 | 日本碍子株式会社 | 空気極材料、インターコネクタ材料及び固体酸化物型燃料電池セル |
| JP5734215B2 (ja) * | 2012-01-31 | 2015-06-17 | 三菱日立パワーシステムズ株式会社 | 固体電解質型燃料電池 |
| US20140080019A1 (en) * | 2012-09-18 | 2014-03-20 | Board Of Regents, The University Of Texas System | MONOCLINIC Sr1-xAxSi1-yGeyO3-0.5x, WHEREIN A IS K or Na, OXIDE ION CONDUCTOR |
| FR2996685B1 (fr) * | 2012-10-10 | 2015-01-23 | Univ Bourgogne | Procede de preparation d'une pile a combustible |
| JP5840105B2 (ja) * | 2012-10-29 | 2016-01-06 | 三菱日立パワーシステムズ株式会社 | 固体酸化物型燃料電池 |
| EP2814100A1 (de) * | 2013-06-12 | 2014-12-17 | Topsøe Fuel Cell A/S | Imprägnierung einer Kathodenhauptkette einer elektrochemischen Zelle |
| IN2013CH02660A (de) * | 2013-06-19 | 2015-10-02 | Nonferrous Materials Technology Dev Ct | |
| WO2015030215A1 (ja) * | 2013-08-31 | 2015-03-05 | 京セラ株式会社 | セル、セルスタック装置、モジュールおよびモジュール収容装置 |
| WO2015054024A1 (en) | 2013-10-08 | 2015-04-16 | Phillips 66 Company | Gas phase modification of solid oxide fuel cells |
| US10418657B2 (en) | 2013-10-08 | 2019-09-17 | Phillips 66 Company | Formation of solid oxide fuel cells by spraying |
| WO2015054065A1 (en) * | 2013-10-08 | 2015-04-16 | Phillips 66 Company | Liquid phase modification of electrodes of solid oxide fuel cells |
| WO2015059166A1 (en) * | 2013-10-22 | 2015-04-30 | Danmarks Tekniske Universitet | Planar half-cell shaped precursor body |
| US9806344B2 (en) * | 2014-01-09 | 2017-10-31 | Chaozhou Three-Circle (Group) Co., Ltd. | Electrochemical energy conversion devices and cells, and negative electrode-side materials for them |
| US9559366B2 (en) | 2014-03-20 | 2017-01-31 | Versa Power Systems Ltd. | Systems and methods for preventing chromium contamination of solid oxide fuel cells |
| US10084192B2 (en) | 2014-03-20 | 2018-09-25 | Versa Power Systems, Ltd | Cathode contact layer design for preventing chromium contamination of solid oxide fuel cells |
| CN105244523B (zh) * | 2015-08-28 | 2018-04-03 | 山西大学 | 一种具有抗积碳功能的固体氧化物燃料电池 |
| KR102517378B1 (ko) * | 2016-11-07 | 2023-04-04 | 더 리젠츠 오브 더 유니버시티 오브 콜로라도, 어 바디 코포레이트 | 테크니컬 세라믹의 개선된 성능 |
| DE102016223293A1 (de) * | 2016-11-24 | 2018-05-24 | Robert Bosch Gmbh | Anode für eine Brennstoffzelle und Verfahren zur Herstellung der Anode |
| DE102017208222A1 (de) * | 2017-05-16 | 2018-11-22 | Robert Bosch Gmbh | Brennstoffzellenvorrichtung |
| JP7170986B2 (ja) * | 2018-06-11 | 2022-11-15 | 東京瓦斯株式会社 | 燃料電池および燃料電池の製造方法 |
| KR102299406B1 (ko) | 2019-08-16 | 2021-09-08 | 한국과학기술연구원 | 금속 불순물을 이용한 자가 활성화가 가능한 전기화학적 이산화탄소 환원 촉매 전극 및 그 제조방법 |
| AU2022235553B2 (en) * | 2021-10-15 | 2024-09-19 | Toshiba Energy Systems & Solutions Corporation | Interconnector for solid-oxide electrochemical cell stack and solid-oxide electrochemical cell stack |
| CN114890787A (zh) * | 2022-05-31 | 2022-08-12 | 南京理工大学 | 氧电极支撑型固体氧化物电解池及其制备方法 |
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| FR1363861A (fr) * | 1960-05-16 | 1964-06-19 | Accumulateurs Fixes | Procédé de fabrication d'électrodes pour accumulateurs, piles à combustible, etc., et électrodes ainsi obtenues |
| JPH04357165A (ja) * | 1991-05-29 | 1992-12-10 | Ngk Insulators Ltd | ジルコニア磁器およびこれを用いた電気化学的素子 |
| US6099985A (en) | 1997-07-03 | 2000-08-08 | Gas Research Institute | SOFC anode for enhanced performance stability and method for manufacturing same |
| WO2002003489A1 (en) * | 2000-07-03 | 2002-01-10 | Matsushita Electric Industrial Co., Ltd. | Polyelectrolyte fuel cell |
| US6544665B2 (en) * | 2001-01-18 | 2003-04-08 | General Electric Company | Thermally-stabilized thermal barrier coating |
| TW533188B (en) * | 2001-07-20 | 2003-05-21 | Getters Spa | Support for microelectronic, microoptoelectronic or micromechanical devices |
| RU2208271C1 (ru) * | 2002-01-28 | 2003-07-10 | Государственное унитарное предприятие Компания "МЭТИС" (дочернее предприятие ГП "Красная Звезда") | Активный слой электродов для топливных элементов |
| US6838119B2 (en) * | 2002-12-27 | 2005-01-04 | Praxair Technology, Inc. | Manufacturing method to improve oxygen ion conductivity of an ionic conductor |
| US6958196B2 (en) * | 2003-02-21 | 2005-10-25 | Trustees Of The University Of Pennsylvania | Porous electrode, solid oxide fuel cell, and method of producing the same |
| US7070879B2 (en) * | 2003-04-10 | 2006-07-04 | Hewlett-Packard Development Company, L.P. | Fuel cell or electrodes with passive support |
| JPWO2004102704A1 (ja) * | 2003-05-14 | 2006-07-13 | 松下電器産業株式会社 | 固体酸化物型燃料電池とその製造方法 |
| JP4428946B2 (ja) * | 2003-06-27 | 2010-03-10 | 東邦瓦斯株式会社 | 固体酸化物形燃料電池用燃料極 |
| KR101136191B1 (ko) * | 2003-09-10 | 2012-04-17 | 트르스티스 오브 보스톤 유니버시티 | 고체 산화물 연료전지 제조 방법 |
| US7618731B2 (en) * | 2003-12-17 | 2009-11-17 | University Of Dayton | Ceramic-ceramic nanocomposite electrolyte |
| JP5260052B2 (ja) * | 2004-06-10 | 2013-08-14 | テクニカル ユニバーシティ オブ デンマーク | 固体酸化物型燃料電池 |
| US20080003487A1 (en) * | 2004-10-29 | 2008-01-03 | The Tokyo Electric Power Company, Incorporated | Powdery Metal Oxide Mother Particles, Powdery Metal Oxide Child Particles, Process for Producing Powdery Metal Oxide Particles, Powdery Composite Particles, and Electrode for Solid Oxide Fuel Cell |
| JP5208518B2 (ja) * | 2005-02-02 | 2013-06-12 | テクニカル ユニバーシティ オブ デンマーク | 可逆式固体酸化物型燃料電池を製造する方法 |
| US8211590B2 (en) * | 2005-03-15 | 2012-07-03 | Panasonic Corporation | Proton conducting material, and electrode and fuel cell using the same |
| US20080124598A1 (en) * | 2006-11-29 | 2008-05-29 | Monika Backhaus-Ricoult | Activation of solid oxide fuel cell electrode surfaces |
-
2007
- 2007-08-31 AT AT07017097T patent/ATE528812T1/de not_active IP Right Cessation
- 2007-08-31 DK DK07017097.2T patent/DK2031677T3/da active
- 2007-08-31 ES ES07017097T patent/ES2375407T3/es active Active
- 2007-08-31 EP EP07017097A patent/EP2031677B1/de not_active Not-in-force
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2008
- 2008-08-29 US US12/674,943 patent/US9077021B2/en not_active Expired - Fee Related
- 2008-08-29 WO PCT/EP2008/007097 patent/WO2009027100A1/en not_active Ceased
- 2008-08-29 RU RU2010105243/07A patent/RU2446515C2/ru not_active IP Right Cessation
- 2008-08-29 JP JP2010522254A patent/JP5430009B2/ja not_active Expired - Fee Related
- 2008-08-29 AU AU2008291251A patent/AU2008291251B2/en not_active Ceased
- 2008-08-29 CN CN2008801049056A patent/CN101796676B/zh not_active Expired - Fee Related
- 2008-08-29 KR KR1020107007084A patent/KR101192701B1/ko not_active Expired - Fee Related
- 2008-08-29 CA CA2697467A patent/CA2697467C/en not_active Expired - Fee Related
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2010
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Also Published As
| Publication number | Publication date |
|---|---|
| CA2697467A1 (en) | 2009-03-05 |
| EP2031677B1 (de) | 2011-10-12 |
| CN101796676B (zh) | 2013-06-12 |
| RU2010105243A (ru) | 2011-10-10 |
| EP2031677A1 (de) | 2009-03-04 |
| DK2031677T3 (da) | 2011-12-12 |
| WO2009027100A1 (en) | 2009-03-05 |
| ATE528812T1 (de) | 2011-10-15 |
| KR20100072229A (ko) | 2010-06-30 |
| US9077021B2 (en) | 2015-07-07 |
| CA2697467C (en) | 2015-03-03 |
| RU2446515C2 (ru) | 2012-03-27 |
| JP5430009B2 (ja) | 2014-02-26 |
| NO20100217L (no) | 2010-05-27 |
| AU2008291251B2 (en) | 2010-12-16 |
| JP2010537390A (ja) | 2010-12-02 |
| CN101796676A (zh) | 2010-08-04 |
| KR101192701B1 (ko) | 2012-10-19 |
| AU2008291251A1 (en) | 2009-03-05 |
| US20110198216A1 (en) | 2011-08-18 |
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