ES2477542T3 - Electrolizador de alta temperatura (EAT) con apilamiento de celdas de electrólisis con seguridad de funcionamiento mejorada y rendimiento elevado - Google Patents

Electrolizador de alta temperatura (EAT) con apilamiento de celdas de electrólisis con seguridad de funcionamiento mejorada y rendimiento elevado Download PDF

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Publication number
ES2477542T3
ES2477542T3 ES11708808.8T ES11708808T ES2477542T3 ES 2477542 T3 ES2477542 T3 ES 2477542T3 ES 11708808 T ES11708808 T ES 11708808T ES 2477542 T3 ES2477542 T3 ES 2477542T3
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Spain
Prior art keywords
plate
box
elementary
cells
stacking
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Active
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ES11708808.8T
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English (en)
Inventor
Patrick Le Gallo
Jean-Luc Sarro
Michel Planque
Magali Reytier
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Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
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Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C25B1/042—Hydrogen or oxygen by electrolysis of water by electrolysis of steam
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/05—Pressure cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/248—Means for compression of the fuel cell stacks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Módulo (M) para electrólisis a altas temperaturas, que comprende: - una envuelta estanca adaptada para contener vapor de agua que contiene como máximo el 1 % de hidrógeno o un gas inerte, - un apilamiento de celdas de electrólisis elementales (C1, C2,... Cn) conformadas cada una de ellas a partir de un cátodo (2.1, 2.2), de un ánodo (4.1, 4.2) y de un electrolito (6.1, 6.2) intercalado entre el cátodo y el ánodo, estando dispuesta al menos una placa interconectora (8) entre dos celdas elementales adyacentes y en contacto eléctrico con un electrodo de una de las dos celdas elementales y un electrodo de la otra de las dos celdas elementales, comprendiendo la placa interconectora al menos un compartimento catódico (11) y al menos un compartimento anódico (9) para la circulación de gases en el cátodo y en el ánodo respectivamente, estando alojado el apilamiento de celdas de electrólisis dentro de la envuelta estanca, en el que la envuelta estanca está constituida por una caja (18) que comprende un fondo (180, 1801) y una tapa (181, 1810, 1811) solidarizados entre sí, estando el apilamiento de celdas de electrólisis elementales ensamblado entre dos placas (19, 20), cuya placa inferior (20) apoya contra el fondo (180, 1801) de la caja por intermedio de un aislante eléctrico (21), en el que medios de apriete (29) están dispuestos al menos en parte entre la placa superior (19) y la tapa (181) de la caja, estando adaptados los medios de apriete para proporcionar un esfuerzo de contacto determinado por compresión entre las placas inferior (20) y superior (19) del apilamiento de celdas, en el que unos medios de apriete comprenden una placa adicional (29) montada con ajuste con juego dentro de la caja y en contacto directo con la placa superior (19), estando adaptada la placa adicional para ser desplazada por el vapor de agua que contiene como máximo el 1 % de hidrógeno desde el exterior de la caja a través de la tapa, generando el desplazamiento de la placa adicional el esfuerzo de apriete entre las placas inferior y superior, permitiendo el juego del ajuste alimentar al menos parcialmente de vapor de agua que contiene como máximo el 1 % de hidrógeno al apilamiento de celdas.
ES11708808.8T 2010-03-12 2011-03-11 Electrolizador de alta temperatura (EAT) con apilamiento de celdas de electrólisis con seguridad de funcionamiento mejorada y rendimiento elevado Active ES2477542T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1051783 2010-03-12
FR1051783A FR2957361B1 (fr) 2010-03-12 2010-03-12 Electrolyseur a haute temperature (eht) a surete de fonctionnement amelioree
PCT/EP2011/053723 WO2011110674A1 (fr) 2010-03-12 2011-03-11 Electrolyseur a haute temperature (eht) a empilement de cellules d'electrolyse a surete de fonctionnement amelioree et rendement eleve

Publications (1)

Publication Number Publication Date
ES2477542T3 true ES2477542T3 (es) 2014-07-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
ES11708808.8T Active ES2477542T3 (es) 2010-03-12 2011-03-11 Electrolizador de alta temperatura (EAT) con apilamiento de celdas de electrólisis con seguridad de funcionamiento mejorada y rendimiento elevado

Country Status (12)

Country Link
US (1) US8945356B2 (es)
EP (1) EP2545206B1 (es)
JP (1) JP5777644B2 (es)
KR (1) KR20130016216A (es)
BR (1) BR112012022387A2 (es)
CA (1) CA2800175C (es)
DK (1) DK2545206T3 (es)
ES (1) ES2477542T3 (es)
FR (1) FR2957361B1 (es)
PL (1) PL2545206T3 (es)
WO (1) WO2011110674A1 (es)
ZA (1) ZA201206358B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2957359B1 (fr) 2010-03-12 2012-04-20 Commissariat Energie Atomique Dispositif d'electrolyse de l'eau a haute temperature a fonctionnement ameliore
FR2957363B1 (fr) 2010-03-12 2012-04-20 Commissariat Energie Atomique Architecture d'electrolyseur a haute temperature, a production cible elevee par cellule d'electrolyse et taux de degradation des cellules limite
FR2964393B1 (fr) 2010-09-06 2012-09-28 Commissariat Energie Atomique Electrolyseur a haute temperature (eht) a surete de fonctionnement amelioree
FR2976591B1 (fr) 2011-06-16 2013-07-12 Commissariat Energie Atomique Module interconnecteur de realisation simplifiee pour dispositif d'electrolyse de l'eau a haute temperature
FR3001232B1 (fr) 2013-01-24 2015-02-20 Commissariat Energie Atomique Procede de realisation d'un module d'interconnecteur pour dispositif d'electrolyse de l'eau a haute temperature ou une pile sofc.
FR3004179B1 (fr) 2013-04-08 2015-05-01 Commissariat Energie Atomique Procedes d'obtention de gaz combustible a partir d'electrolyse de l'eau (eht) ou de co-electrolyse avec h2o/co2 au sein d'une meme enceinte, reacteur catalytique et systeme associes
JP6588021B2 (ja) * 2013-10-12 2019-10-09 ニュー シーオー２ フュエルズ リミテッド 電気化学反応を実施するために余熱を利用するシステム
CN103668307B (zh) * 2013-12-26 2016-01-13 王树金 电解高温水蒸汽制氢装置及制氢方法
DE102014108085A1 (de) * 2014-06-06 2015-12-17 Sunfire Gmbh Elektrolyseverfahren
FR3030893B1 (fr) 2014-12-18 2017-01-20 Commissariat Energie Atomique Motif elementaire pour reacteur d'electrolyse ou de co-electrolyse de l'eau (soec) ou pile a combustible (sofc), a fonctionnement sous pression
FR3042069B1 (fr) * 2015-10-06 2021-01-22 Commissariat Energie Atomique Systeme d’electrolyse de l’eau (soec) ou pile a combustible (sofc) a fonctionnement sous pression dont la regulation est amelioree
FR3045215B1 (fr) 2015-12-15 2023-03-03 Commissariat Energie Atomique Systeme de serrage autonome d'un empilement a oxydes solides de type soec/sofc a haute temperature
FR3047743B1 (fr) 2016-02-16 2020-01-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives Systeme d'electrolyse de l'eau (soec) ou pile a combustible (sofc) a fonctionnement sous pression dans une enceinte etanche dont la regulation est amelioree
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FR3056338B1 (fr) 2016-09-22 2018-09-21 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procedes de co-electrolyse de l'eau et du co2 (soec) ou de production d'electricite a haute temperature (sofc) favorisant ou non les reactions catalytiques au sein de l'electrode h2
FR3061495B1 (fr) 2017-01-02 2019-05-31 Commissariat A L'energie Atomique Et Aux Energies Alternatives Systeme de couplage etanche a haute temperature d'un empilement a oxydes solides de type soec/sofc
FR3066201B1 (fr) 2017-05-15 2022-01-07 Commissariat Energie Atomique Reacteur d'electrolyse ou de co-electrolyse de l'eau (soec) ou pile a combustible (sofc) a fonctionnement sous pression et a systeme de serrage adapte a un tel fonctionnement
FR3073093B1 (fr) 2017-10-26 2022-02-04 Commissariat Energie Atomique Ensemble d'un empilement a oxydes solides de type soec/sofc et d'un systeme de serrage avec systeme de surchauffe des gaz integre
FR3073091B1 (fr) 2017-10-30 2019-10-25 Commissariat A L'energie Atomique Et Aux Energies Alternatives Motif elementaire reversible d'electrolyse ou de co-electrolyse de l'eau (soec) ou de pile a combustible (sofc) a fonctionnement sous pression et effort de compression decouple
FR3075481B1 (fr) 2017-12-19 2020-01-10 Commissariat A L'energie Atomique Et Aux Energies Alternatives Ensemble d'un empilement a oxydes solides de type soec/sofc, d'un systeme de serrage et d'un systeme de couplage etanche
FR3087953B1 (fr) 2018-10-26 2021-07-02 Commissariat Energie Atomique Dispositif electrochimique comprenant un ensemble electrochimique dispose dans une enceinte de confinement
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Also Published As

Publication number Publication date
PL2545206T3 (pl) 2014-07-31
FR2957361A1 (fr) 2011-09-16
CA2800175A1 (en) 2011-09-15
EP2545206A1 (fr) 2013-01-16
US8945356B2 (en) 2015-02-03
BR112012022387A2 (pt) 2016-07-05
FR2957361B1 (fr) 2012-04-20
KR20130016216A (ko) 2013-02-14
CA2800175C (en) 2018-08-21
JP2013522457A (ja) 2013-06-13
US20120325654A1 (en) 2012-12-27
DK2545206T3 (da) 2014-06-23
EP2545206B1 (fr) 2014-04-02
WO2011110674A1 (fr) 2011-09-15
ZA201206358B (en) 2013-05-29
JP5777644B2 (ja) 2015-09-09

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