ES2485665T3 - Óxido litiado para electrodo positivo de acumulador alcalino - Google Patents

Óxido litiado para electrodo positivo de acumulador alcalino Download PDF

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Publication number
ES2485665T3
ES2485665T3 ES09786173.6T ES09786173T ES2485665T3 ES 2485665 T3 ES2485665 T3 ES 2485665T3 ES 09786173 T ES09786173 T ES 09786173T ES 2485665 T3 ES2485665 T3 ES 2485665T3
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Spain
Prior art keywords
lithium oxide
positive electrode
alkaline battery
less
formula
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Active
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ES09786173.6T
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English (en)
Inventor
Patrick Bernard
Rémi Najean
Lionel Goubault
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Saft Groupe SAS
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Saft Groupe SAS
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/30—Nickel accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/32—Nickel oxide or hydroxide electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Electrodo positivo de acumulador de electrolito alcalino que comprende un hidróxido a base de níquel y un óxido litiado de fórmula LixMO2 en la que M representa al menos un metal de transición,**Fórmula** 0,1 <= x <= 1, dicho óxido litiado posee una superficie específica medida mediante la técnica BET inferior 5 a 40 m2/g y una granulometría inferior a 1 μm.

Description

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Claims (1)

  1. imagen1
ES09786173.6T 2008-08-29 2009-08-25 Óxido litiado para electrodo positivo de acumulador alcalino Active ES2485665T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0804757A FR2935545B1 (fr) 2008-08-29 2008-08-29 Oxyde lithie pour electrode positive d'accumulateur alcalin
FR0804757 2008-08-29
PCT/IB2009/006626 WO2010023531A2 (fr) 2008-08-29 2009-08-25 Oxyde lithié pour électrode positive d'accumulateur alcalin

Publications (1)

Publication Number Publication Date
ES2485665T3 true ES2485665T3 (es) 2014-08-14

Family

ID=40278927

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09786173.6T Active ES2485665T3 (es) 2008-08-29 2009-08-25 Óxido litiado para electrodo positivo de acumulador alcalino

Country Status (5)

Country Link
US (1) US8530091B2 (es)
EP (1) EP2340233B1 (es)
ES (1) ES2485665T3 (es)
FR (1) FR2935545B1 (es)
WO (1) WO2010023531A2 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011071094A1 (ja) * 2009-12-07 2011-06-16 住友化学株式会社 リチウム複合金属酸化物の製造方法、リチウム複合金属酸化物および非水電解質二次電池
US8298706B2 (en) 2010-03-12 2012-10-30 The Gillette Company Primary alkaline battery
US9570741B2 (en) 2012-03-21 2017-02-14 Duracell U.S. Operations, Inc. Metal-doped nickel oxide active materials
US9028564B2 (en) * 2012-03-21 2015-05-12 The Gillette Company Methods of making metal-doped nickel oxide active materials
US8703336B2 (en) 2012-03-21 2014-04-22 The Gillette Company Metal-doped nickel oxide active materials
US9793542B2 (en) 2014-03-28 2017-10-17 Duracell U.S. Operations, Inc. Beta-delithiated layered nickel oxide electrochemically active cathode material and a battery including said material
KR102098154B1 (ko) * 2016-09-09 2020-04-08 주식회사 엘지화학 3차원 망상 구조의 전극 집전체를 포함하는 전극
CN110582467B (zh) 2017-05-09 2022-07-26 杜拉塞尔美国经营公司 包含β-脱锂层状氧化镍电化学活性阴极材料的电池
AU2018373507B2 (en) * 2017-11-22 2024-02-22 Nemaska Lithium Inc. Processes for preparing hydroxides and oxides of various metals and derivatives thereof
CN111564623A (zh) * 2020-04-29 2020-08-21 湖南科霸汽车动力电池有限责任公司 镍氢动力电池正极浆料
CN113233517B (zh) * 2021-06-29 2024-02-09 上海交通大学 一种单层/少层二维过渡金属氧化物纳米材料水性分散液及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3229800B2 (ja) 1996-03-25 2001-11-19 三洋電機株式会社 アルカリ蓄電池用非焼結式ニッケル極
JPH101316A (ja) * 1996-06-10 1998-01-06 Sakai Chem Ind Co Ltd リチウムコバルト複合酸化物及びその製造方法並びにリチウムイオン二次電池
JP3191751B2 (ja) 1997-03-21 2001-07-23 松下電器産業株式会社 アルカリ蓄電池及びその正極活物質の表面処理方法
JP3543601B2 (ja) 1998-02-23 2004-07-14 松下電器産業株式会社 アルカリ蓄電池
JP3543607B2 (ja) 1998-03-09 2004-07-14 松下電器産業株式会社 アルカリ蓄電池
US6017655A (en) * 1998-08-18 2000-01-25 Ovonic Battery Company Nickel hydroxide positive electrode material exhibiting improved conductivity and engineered activation energy
FR2788886B1 (fr) 1999-01-21 2001-03-30 Cit Alcatel Electrode au nickel non frittee pour generateur electrochimique secondaire a electrolyte alcalin
FR2803104B1 (fr) * 1999-12-23 2002-03-15 Cit Alcatel Electrode au nickel non frittee pour generateur electrochimique secondaire a electrolyte alcalin
US7410511B2 (en) * 2002-08-08 2008-08-12 Matsushita Electric Industrial Co., Ltd. Production method of positive electrode active material for non-aqueous electrolyte secondary battery and positive electrode active material
JP2004265806A (ja) * 2003-03-04 2004-09-24 Canon Inc リチウム金属複合酸化物粒子、前記リチウム金属複合酸化物粒子の製造方法、前記リチウム金属複合酸化物粒子を含有す電極構造体、前記電極構造体の製造方法、及び前記電極構造体を有するリチウム二次電池
JP2005123180A (ja) * 2003-09-26 2005-05-12 Mitsubishi Chemicals Corp リチウム二次電池正極材用リチウム複合酸化物粒子及びその製造方法、並びにそれを用いたリチウム二次電池用正極及びリチウム二次電池
JP4591717B2 (ja) * 2006-09-22 2010-12-01 三菱化学株式会社 リチウム二次電池正極材料用リチウムニッケルマンガンコバルト系複合酸化物粉体、その製造方法、及び噴霧乾燥粉体、並びにそれを用いたリチウム二次電池用正極及びリチウム二次電池
JP4963059B2 (ja) * 2006-11-20 2012-06-27 独立行政法人産業技術総合研究所 チタン及びニッケル含有リチウムマンガン系複合酸化物

Also Published As

Publication number Publication date
WO2010023531A2 (fr) 2010-03-04
WO2010023531A3 (fr) 2010-05-20
FR2935545A1 (fr) 2010-03-05
EP2340233B1 (fr) 2014-05-28
US20110151329A1 (en) 2011-06-23
FR2935545B1 (fr) 2011-06-03
US8530091B2 (en) 2013-09-10
EP2340233A2 (fr) 2011-07-06

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