ES2520091T3 - Método para preparar alfa-olefinas lineales - Google Patents

Método para preparar alfa-olefinas lineales Download PDF

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Publication number
ES2520091T3
ES2520091T3 ES09705284.9T ES09705284T ES2520091T3 ES 2520091 T3 ES2520091 T3 ES 2520091T3 ES 09705284 T ES09705284 T ES 09705284T ES 2520091 T3 ES2520091 T3 ES 2520091T3
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ES
Spain
Prior art keywords
reactor
catalyst
organic amine
linear alpha
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES09705284.9T
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English (en)
Inventor
Wofgang MÜLLER
Peter M. Fritz
Heinz BÖLT
Anton Wellenhofer
Florian Winkler
Uwe Rosenthal
Hans-Jörg ZANDER
Normen Peulecke
Bernd H. Müller
Karl-Heinz Hofmann
Helmut Fritz
Carsten Taube
Andreas Meiswinkel
Richard Schneider
Anina Woehl
Aliyev Vugar
Fuad Mosa
Mohammed Al-Hazmi
Syriac Palackal
Ayed Al-Ayed
Sultan Al-Otaibi
Mohammed Zahoor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Saudi Basic Industries Corp
Original Assignee
Linde GmbH
Saudi Basic Industries Corp
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Application filed by Linde GmbH, Saudi Basic Industries Corp filed Critical Linde GmbH
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Publication of ES2520091T3 publication Critical patent/ES2520091T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Chemistry (AREA)

Abstract

Método para preparar alfa olefinas lineales (LAO) mediante oligomerización del etileno en presencia de un disolvente y un catalizador homogéneo, que comprende las etapas de: (i) colocación del etileno, disolvente y catalizador en un reactor de oligomerización, (ii) oligomerización del etileno en el reactor, (iii) remoción de un flujo de salida del reactor que comprende un disolvente, alfa olefinas lineales, etileno, y catalizador del reactor mediante un sistema de tuberías de salida del reactor, (iv) transferencia del flujo de salida del reactor a una etapa de desactivación y remoción del catalizador, y (v) desactivación y remoción del catalizador del flujo de salida del reactor, caracterizado por que se agrega al menos una amina orgánica en el sistema de tuberías de salida del reactor donde la amina orgánica se remueve del flujo de salida del reactor mediante destilación, extracción o absorción y la amina orgánica removida se recicla en el sistema de tuberías de salida del reactor, la amina orgánica es soluble en fase orgánica que contiene alfa olefinas lineales y la amina orgánica no es soluble o tiene baja solubilidad en agua o una mezcla de agua y elementos cáusticos, y donde el catalizador se desactiva mediante elementos cáusticos.

Description

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Claims (1)

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ES09705284.9T 2008-01-30 2009-01-07 Método para preparar alfa-olefinas lineales Active ES2520091T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08001677 2008-01-30
EP08001677 2008-01-30
PCT/EP2009/000030 WO2009095147A1 (en) 2008-01-30 2009-01-07 Method for preparing linear alpha-olefins

Publications (1)

Publication Number Publication Date
ES2520091T3 true ES2520091T3 (es) 2014-11-11

Family

ID=39473285

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09705284.9T Active ES2520091T3 (es) 2008-01-30 2009-01-07 Método para preparar alfa-olefinas lineales

Country Status (15)

Country Link
US (1) US9593055B2 (es)
EP (1) EP2234945B1 (es)
JP (1) JP5539229B2 (es)
KR (1) KR101545369B1 (es)
CN (2) CN105753622B (es)
BR (1) BRPI0907001B1 (es)
CA (1) CA2711093C (es)
ES (1) ES2520091T3 (es)
MX (1) MX2010008426A (es)
MY (1) MY156865A (es)
RU (1) RU2469014C2 (es)
SG (1) SG187514A1 (es)
TW (1) TWI422558B (es)
WO (1) WO2009095147A1 (es)
ZA (1) ZA201004482B (es)

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EP2455359B1 (en) 2010-11-23 2013-03-27 Linde AG Method for purification of a hydrocarbon stream olefin and amine
EP2581358B1 (en) 2011-10-10 2017-07-12 Saudi Basic Industries Corporation Method for removal of organic amines from hydrocarbon streams
EP2738152B1 (en) 2012-11-28 2019-05-01 Saudi Basic Industries Corporation Method for removal and recovery of organic amines from a hydrocarbon stream
EP3097166A2 (en) * 2014-01-20 2016-11-30 Saudi Basic Industries Corporation Process and apparatus for purifying a hydrocarbon stream comprising linear alpha-olefins (lao) from amines
HRP20190717T1 (hr) * 2014-12-23 2019-07-12 Public Joint Stock Company "Sibur Holding" Postupci taloženja polimera i deaktiviranog organometalnog katalizatora u reakciji oligomerizacije olefina
WO2016129845A1 (ko) * 2015-02-12 2016-08-18 주식회사 엘지화학 비활성화제 및 이를 이용한 올레핀 올리고머화의 부산물 저감 방법
KR101679515B1 (ko) * 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
KR101761395B1 (ko) 2015-04-15 2017-07-25 주식회사 엘지화학 리간드 화합물, 올리고머화 촉매계 및 이를 이용한 올레핀 올리고머화 방법
WO2017046701A1 (en) 2015-09-16 2017-03-23 Sabic Global Technologies B.V. Process for deactivation of an olefin oligomerization catalyst
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
CN105819578B (zh) * 2016-04-16 2017-09-05 浙江杭化科技有限公司 一种用于mto水洗塔除垢剂
RU2726620C1 (ru) * 2016-12-22 2020-07-15 Сабик Глобал Текнолоджис Б.В. Способы получения линейных альфа-олефинов
FR3061175B1 (fr) * 2016-12-22 2020-07-31 Ifp Energies Now Procede de neutralisation d'un systeme catalytique de dimerisation d'olefines contenant au moins un derive halogene.
CN110603239A (zh) * 2017-05-09 2019-12-20 埃克森美孚化学专利公司 使用具有高产物纯度的催化剂失活的线性α-烯烃方法
WO2018208374A1 (en) * 2017-05-09 2018-11-15 Exxonmobil Chemical Patents Inc. Linear alpha olefin process using solvent flash drum for olefin separation
US20200055799A1 (en) * 2017-05-09 2020-02-20 Exxonmobil Chemical Patents Inc. Linear Alpha Olefin Process Using Temperature Control in Oligomerization Reactor
KR102334363B1 (ko) 2017-09-29 2021-12-02 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
KR102329819B1 (ko) 2018-10-19 2021-11-23 한국에너지기술연구원 선형 1차 알코올의 제조방법
WO2020247192A1 (en) 2019-05-24 2020-12-10 Eastman Chemical Company Recycle content cracked effluent
CN113993977B (zh) 2019-05-24 2024-09-13 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
EP3976734A4 (en) 2019-05-24 2023-03-15 Eastman Chemical Company CRACKING A C4-C7 FRACTION OF PYROLYTIC OIL
WO2020242921A1 (en) 2019-05-24 2020-12-03 Eastman Chemical Company Recycle content cellulose ester
US12338211B2 (en) 2019-07-29 2025-06-24 Eastman Chemical Company Recycle content (C4)alkanal
US12534590B2 (en) 2019-07-29 2026-01-27 Eastman Chemical Company Recycle content cyclobutane diol polyester
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
WO2021087057A1 (en) 2019-10-31 2021-05-06 Eastman Chemical Company Pyrolysis method and system for recycled waste
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
CN118851872A (zh) 2019-11-07 2024-10-29 伊士曼化工公司 回收成分丙醇
KR20220093368A (ko) 2019-11-07 2022-07-05 이스트만 케미칼 컴파니 재활용물 알파 올레핀 및 지방 알코올
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US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic

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Also Published As

Publication number Publication date
TW200940479A (en) 2009-10-01
WO2009095147A1 (en) 2009-08-06
JP5539229B2 (ja) 2014-07-02
JP2011510939A (ja) 2011-04-07
CA2711093A1 (en) 2009-08-06
US20110046429A1 (en) 2011-02-24
EP2234945B1 (en) 2014-08-20
BRPI0907001A2 (pt) 2015-07-07
CA2711093C (en) 2013-05-21
TWI422558B (zh) 2014-01-11
CN105753622B (zh) 2019-01-29
EP2234945A1 (en) 2010-10-06
ZA201004482B (en) 2011-09-28
MX2010008426A (es) 2011-02-22
RU2469014C2 (ru) 2012-12-10
MY156865A (en) 2016-04-15
KR20100113534A (ko) 2010-10-21
CN105753622A (zh) 2016-07-13
RU2010136280A (ru) 2012-03-10
KR101545369B1 (ko) 2015-08-18
SG187514A1 (en) 2013-02-28
US9593055B2 (en) 2017-03-14
BRPI0907001B1 (pt) 2018-04-03
CN101932541A (zh) 2010-12-29

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