ES2529191T1 - Premezclas de espuma de poliuretano que contienen agentes de soplado de olefinas halogenadas, y espumas obtenidas de ellas - Google Patents

Premezclas de espuma de poliuretano que contienen agentes de soplado de olefinas halogenadas, y espumas obtenidas de ellas Download PDF

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ES2529191T1
ES2529191T1 ES12797374.1T ES12797374T ES2529191T1 ES 2529191 T1 ES2529191 T1 ES 2529191T1 ES 12797374 T ES12797374 T ES 12797374T ES 2529191 T1 ES2529191 T1 ES 2529191T1
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Prior art keywords
catalyst
blowing agent
foamable composition
methyl
amine
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ES12797374.1T
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David J. Williams
Mary C. Bogdan
Clifford P. Gittere
Andrew J. Poss
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Honeywell International Inc
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Honeywell International Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)

Abstract

Una composición espumable que comprende: a. un agente de soplado hidrohaloolefínico que comprende 1-cloro-3,3,3-trifluoropropeno, b. uno o más polioles, c. uno o más tensioactivos, y d. un catalizador que comprende al menos un catalizador amínico, produciendo dicho agente de soplado y dicho catalizador un Valor de Generación de Fluoruro menor que alrededor de 175 ppm.

Claims (10)

  1. REIVINDICACIONES
    1. Una composición espumable que comprende:
    a. un agente de soplado hidrohaloolefínico que comprende 1-cloro-3,3,3-trifluoropropeno,
    b. uno o más polioles,
    c. uno o más tensioactivos, y 5
    d. un catalizador que comprende al menos un catalizador amínico, produciendo dicho agente de soplado y dicho catalizador un Valor de Generación de Fluoruro menor que alrededor de 175 ppm.
  2. 2. La composición espumable de la reivindicación 1, en la que dicho agente de soplado y dicho catalizador producen una Degradación del Tiempo de Gel menor que alrededor de 50%.
  3. 3. La composición espumable de la reivindicación 1, en la que dicho catalizador comprende además al menos un 10 primer catalizador metálico.
  4. 4. La composición espumable de la reivindicación 9, en la que dicho primer catalizador metálico se selecciona del grupo que consiste en catalizador a base de bismuto, 2-etilhexoato de plomo, benzoato de plomo, naftenato de plomo, cloruro férrico, tricloruro de antimonio, glicolato de antimonio, sales de estaño de ácidos carboxílicos, sales de dialquilestaño de ácidos carboxílicos, acetato de potasio, octoato de potasio, 2-etilhexoato de potasio, sales 15 potásicas de ácidos carboxílicos, sales de cinc de ácidos carboxílicos, 2-etilhexanoato de cinc, sales de glicina, sales de ácidos carboxílicos con metales alcalinos, y N-(2-hidroxi-5-nonilfenol)metil-N-metilglicinato de sodio, 2-etilhexanoato de estaño (II), dilaurato de dibutilestaño, y sus combinaciones.
  5. 5. La composición espumable de la reivindicación 1, en la que dicho agente de soplado comprende al menos alrededor de 50% en peso de 1-cloro-3,3,3-trifluoropropeno. 20
  6. 6. Una composición espumable que comprende:
    a. un agente de soplado hidrohaloolefínico,
    b. uno o más polioles,
    c. uno o más tensioactivos, y
    d. un sistema catalítico que comprende al menos un catalizador amínico, produciendo dicho agente de 25 soplado y dicho catalizador un Valor de Generación de Fluoruro menor que alrededor de 175 ppm.
  7. 7. La composición espumable de la reivindicación 6, en la que dicho agente de soplado y dicho catalizador producen una Degradación del Tiempo de Gel menor que alrededor de 50%.
  8. 8. Una composición espumable que comprende:
    a. un agente de soplado hidrohaloolefínico, 30
    b. uno o más polioles,
    c. uno o más tensioactivos, y
    d. un catalizador que comprende al menos un catalizador amínico, produciendo dicho agente de soplado y dicho catalizador un Valor de Generación de Fluoruro menor que alrededor de 1000 ppm.
  9. 9. La composición espumable de la reivindicación 8, en la que dicho agente de soplado hidrohaloolefínico se 35 selecciona de trans 1233ze, trans-1234ze, y 1336mzzm.
  10. 10. La composición espumable de la reivindicación 9, en la que dicho catalizador amínico se selecciona de uno o más de: n-metildiciclohexil-amina; metil(n-metilamino b-acetato de sodio nonilfenol) 2-; glicerol poli(oxipropileno) triamina; diisopropiletilamina; dietiltoluenodiamina; agua + sal de amina; 1,2 dimetilimidazol; etilenglicol; catalizador trimerizado; n-metilmorfolina; diisopropiletilamina; n-metildiciclohexil-amina; glicerol poli(oxipropileno) triamina; 2,2-40 dimorfolinodietiléter; N,N-dimetilparatoluidina; y 3,5-dimetiltio-2,4-toluenodiamina; dietiltoluenodiamina; 4-metil-2,6-bis(metiltio) 1,3-bencenodiamina/2-metil-4,6-bis (metiltio) 1,3-bencenodiamina; 4-metil-2,6-bis(metiltio) 1,3-bencenodiamina; y 2-metil-4,6-bis (metiltio) 1,3-bencenodiamina.
ES12797374.1T 2011-06-08 2012-06-08 Premezclas de espuma de poliuretano que contienen agentes de soplado de olefinas halogenadas, y espumas obtenidas de ellas Pending ES2529191T1 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161494868P 2011-06-08 2011-06-08
US201161494868P 2011-06-08
US201213491534 2012-06-07
US13/491,534 US20120313035A1 (en) 2011-06-08 2012-06-07 Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
PCT/US2012/041694 WO2012170912A2 (en) 2011-06-08 2012-06-08 Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same

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ES2529191T1 true ES2529191T1 (es) 2015-02-17

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US (1) US20120313035A1 (es)
EP (1) EP2718341A4 (es)
JP (2) JP6049707B2 (es)
CN (1) CN103703042A (es)
CA (1) CA2836514A1 (es)
ES (1) ES2529191T1 (es)
TW (2) TW201811850A (es)
WO (1) WO2012170912A2 (es)

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CA2836514A1 (en) 2012-12-13
JP2017075322A (ja) 2017-04-20
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WO2012170912A3 (en) 2013-04-25
TWI623559B (zh) 2018-05-11
TW201311752A (zh) 2013-03-16
EP2718341A2 (en) 2014-04-16
TW201811850A (zh) 2018-04-01
US20120313035A1 (en) 2012-12-13

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