ES2542080T3 - Sistema catalizador para la polimerización de olefinas - Google Patents

Sistema catalizador para la polimerización de olefinas Download PDF

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Publication number
ES2542080T3
ES2542080T3 ES11772942.6T ES11772942T ES2542080T3 ES 2542080 T3 ES2542080 T3 ES 2542080T3 ES 11772942 T ES11772942 T ES 11772942T ES 2542080 T3 ES2542080 T3 ES 2542080T3
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Spain
Prior art keywords
groups
different
hydrogen
catalyst system
formula
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Active
Application number
ES11772942.6T
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English (en)
Inventor
Giampiero Morini
Simona Guidotti
Alessandro Mignogna
Joachim T. M. Pater
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un sistema catalizador para la polimerización de olefinas que comprende el producto obtenido poniendo en contacto (a) un componente catalizador sólido que contiene Mg, Ti, halógeno y al menos un compuesto donante de electrones seleccionado de diolésteres de la siguiente fórmula (A)**Fórmula** en la que grupos R1-R4, iguales o diferentes entre sí, son hidrógeno o grupos hidrocarburo C1-C15, que opcionalmente contienen un heteroátomo seleccionado de halógeno, P, S, N y Si, con la condición de que R1 y R4 no sean simultáneamente hidrógeno, grupos R, iguales o diferentes entre sí, se seleccionan de grupos hidrocarburo C1- C15 que pueden unirse opcionalmente para formar un ciclo y n es un número entero de 0 a 5; (b) un cocatalizador de alquilaluminio y (c) un éster de fórmula R'OOC-(CR"2)m-COOR' en la que m es un número entero de 2 a 7, los grupos R', iguales o diferentes entre sí, son grupos alquilo C1-C10 y los grupos R", independientemente, son hidrógeno o grupos hidrocarburo C1-C15.

Description

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Claims (1)

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ES11772942.6T 2010-10-19 2011-10-17 Sistema catalizador para la polimerización de olefinas Active ES2542080T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10188015 2010-10-19
EP10188015 2010-10-19
US40525910P 2010-10-21 2010-10-21
US405259P 2010-10-21
PCT/EP2011/068080 WO2012052387A1 (en) 2010-10-19 2011-10-17 Catalyst system for the polymerization of olefins

Publications (1)

Publication Number Publication Date
ES2542080T3 true ES2542080T3 (es) 2015-07-30

Family

ID=44872307

Family Applications (1)

Application Number Title Priority Date Filing Date
ES11772942.6T Active ES2542080T3 (es) 2010-10-19 2011-10-17 Sistema catalizador para la polimerización de olefinas

Country Status (6)

Country Link
US (1) US20130197173A1 (es)
EP (1) EP2630170B1 (es)
CN (1) CN103168054A (es)
BR (1) BR112013008900A2 (es)
ES (1) ES2542080T3 (es)
WO (1) WO2012052387A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2607384A1 (en) * 2011-12-21 2013-06-26 Basell Poliolefine Italia S.r.l. Catalyst system for the polymerization of olefins
CN104513330B (zh) * 2013-09-30 2017-07-28 中国石油化工股份有限公司 一种烯烃聚合用催化剂体系及其应用
TWI639626B (zh) 2013-09-30 2018-11-01 中國石油化工科技開發有限公司 Catalyst composition for olefin polymerization and application thereof
CN104513329B (zh) * 2013-09-30 2017-05-31 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系及其应用
CN104513331B (zh) * 2013-09-30 2017-06-06 中国石油化工股份有限公司 用于烯烃聚合的催化剂组合物及其应用
WO2017117433A1 (en) * 2015-12-31 2017-07-06 Braskem America, Inc. Non-phthalate catalyst system and its use in the polymerization of olefins
EP3798241A4 (en) * 2018-05-21 2022-06-22 China Petroleum & Chemical Corporation OLEFIN POLYMERIZATION CATALYST INGREDIENT, METHOD OF MANUFACTURE THEREOF AND CATALYST THEREOF

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3401157A (en) * 1967-02-21 1968-09-10 Eastman Kodak Co Three-component aluminum-titanium tetrahalide catalysts for olefin polymerization
SE363977B (es) 1968-11-21 1974-02-11 Montedison Spa
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US5093415A (en) * 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1262934B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1256648B (it) 1992-12-11 1995-12-12 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione delle olefine
AUPO591797A0 (en) 1997-03-27 1997-04-24 Commonwealth Scientific And Industrial Research Organisation High avidity polyvalent and polyspecific reagents
IL127230A (en) 1997-03-29 2004-07-25 Montell Technology Company Bv Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
US6657025B2 (en) * 2001-01-12 2003-12-02 Fina Technology, Inc. Production of ultra high melt flow polypropylene resins
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
US20060057374A1 (en) * 2002-09-25 2006-03-16 Basell Poliolefine Italia S.P.A Polypropylene fibres suitable for spunbonded non-woven fabrics
CN1213080C (zh) * 2003-04-21 2005-08-03 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
JP5740159B2 (ja) * 2007-12-21 2015-06-24 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 二座内部供与体を有する自己制限性触媒組成物
CN101724111B (zh) * 2008-10-24 2012-02-01 中国石油化工股份有限公司 一种宽分子量分布聚丙烯的制备方法及其聚合物
US20100249354A1 (en) * 2009-03-26 2010-09-30 Fina Technology, Inc. Injection stretch blow molded articles and syndiotactic polymers for use therein

Also Published As

Publication number Publication date
US20130197173A1 (en) 2013-08-01
CN103168054A (zh) 2013-06-19
EP2630170A1 (en) 2013-08-28
BR112013008900A2 (pt) 2016-06-28
WO2012052387A1 (en) 2012-04-26
EP2630170B1 (en) 2015-04-22

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