ES2547242T3 - Método de oxidación con oxígeno de hidrocarburos cíclicos saturados - Google Patents

Método de oxidación con oxígeno de hidrocarburos cíclicos saturados Download PDF

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Publication number
ES2547242T3
ES2547242T3 ES05804710.1T ES05804710T ES2547242T3 ES 2547242 T3 ES2547242 T3 ES 2547242T3 ES 05804710 T ES05804710 T ES 05804710T ES 2547242 T3 ES2547242 T3 ES 2547242T3
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ES
Spain
Prior art keywords
oxygen
flow
liquid phase
sky
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES05804710.1T
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English (en)
Inventor
Serge Veracini
Frédéric AUGIER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
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Rhodia Chimie SAS
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Publication of ES2547242T3 publication Critical patent/ES2547242T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Método continuo de oxidación de un hidrocarburo cíclico saturado con oxígeno en una mezcla de hidroperóxido, alcohol, cetona, que consiste en introducir, en el fondo de la columna y a cocorriente, un flujo líquido de hidrocarburo a oxidar y un flujo gaseoso que contiene oxígeno, des gasificar la fase líquida en la cabeza de la columna por formación de un cielo gaseoso y retirar la fase líquida desgasificada, caracterizado por que consiste en alimentar un gas que contiene oxígeno en diferentes plataformas de la columna y en alimentar en el cielo y/o en la fase líquida al nivel de la zona de desgasificación o inmediatamente corriente arriba, un flujo de gas no oxidante con un caudal suficiente para mantener la concentración de oxígeno en el cielo gaseoso en una concentración volumétrica inferior o igual a la concentración límite superior de oxígeno.

Description

imagen1
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Claims (1)

  1. imagen1
ES05804710.1T 2004-10-12 2005-10-06 Método de oxidación con oxígeno de hidrocarburos cíclicos saturados Expired - Lifetime ES2547242T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0410731A FR2876373B1 (fr) 2004-10-12 2004-10-12 Procede d'oxydation par l'oxygene d'hydrocarbures cycliques satures
FR0410731 2004-10-12
PCT/FR2005/002461 WO2006040442A1 (fr) 2004-10-12 2005-10-06 Procede d'oxydation par l'oxygene d'hydrocarbures cycliques satures

Publications (1)

Publication Number Publication Date
ES2547242T3 true ES2547242T3 (es) 2015-10-02

Family

ID=34950887

Family Applications (1)

Application Number Title Priority Date Filing Date
ES05804710.1T Expired - Lifetime ES2547242T3 (es) 2004-10-12 2005-10-06 Método de oxidación con oxígeno de hidrocarburos cíclicos saturados

Country Status (13)

Country Link
US (1) US7741523B2 (es)
EP (1) EP1799628B1 (es)
JP (1) JP2008515957A (es)
KR (1) KR20070057238A (es)
CN (1) CN101039890B (es)
BR (1) BRPI0516313B1 (es)
ES (1) ES2547242T3 (es)
FR (1) FR2876373B1 (es)
PL (1) PL1799628T3 (es)
RU (1) RU2358962C2 (es)
TW (1) TWI366483B (es)
UA (1) UA82798C2 (es)
WO (1) WO2006040442A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2952055B1 (fr) 2009-11-05 2011-11-11 Rhodia Operations Procede de preparation de composes hydroperoxyde d'alkyle
FR2955321B1 (fr) * 2010-01-21 2012-02-10 Rhodia Operations Procede d'oxydation d'hydrocarbures
CN103755544B (zh) * 2014-01-26 2015-07-15 沅江华龙催化科技有限公司 基于气液固多相反应分离同步反应器利用空气氧化环己烷生产ka油和己二酸的方法
CN107556174A (zh) * 2016-07-01 2018-01-09 中国石油化工股份有限公司 一种提高环己烷氧化气含率的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3530185A (en) * 1966-08-08 1970-09-22 Du Pont Oxidation process
SU503846A1 (ru) * 1974-05-13 1976-02-25 Предприятие П/Я Р-6603 Способ получени циклогексанола и циклогексанона
DE3328771A1 (de) * 1983-08-10 1985-02-28 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von sauerstoff enthaltenden verbindungen
US5780683A (en) * 1996-09-11 1998-07-14 Abb Lummus Global Inc. Cyclohexane oxidation
US6362367B2 (en) * 1998-04-21 2002-03-26 Union Carbide Chemicals & Plastics Technology Corp. Preparation of organic acids
FR2830775B1 (fr) 2001-10-12 2004-08-27 Rhodia Polyamide Intermediates Reacteur pour reaction d'oxydation d'un liquide avec un gaz
RU2209812C2 (ru) * 2001-11-02 2003-08-10 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" Способ жидкофазного окисления углеводородов

Also Published As

Publication number Publication date
CN101039890A (zh) 2007-09-19
BRPI0516313A (pt) 2008-09-02
JP2008515957A (ja) 2008-05-15
KR20070057238A (ko) 2007-06-04
EP1799628B1 (fr) 2015-06-24
PL1799628T3 (pl) 2015-12-31
TWI366483B (en) 2012-06-21
RU2358962C2 (ru) 2009-06-20
FR2876373B1 (fr) 2007-01-05
US7741523B2 (en) 2010-06-22
RU2007117727A (ru) 2008-11-20
CN101039890B (zh) 2010-07-21
BRPI0516313B1 (pt) 2015-06-02
TW200635660A (en) 2006-10-16
FR2876373A1 (fr) 2006-04-14
US20090076308A1 (en) 2009-03-19
EP1799628A1 (fr) 2007-06-27
UA82798C2 (uk) 2008-05-12
WO2006040442A1 (fr) 2006-04-20

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