ES2547536T3 - Producción y acondicionamiento de gas de síntesis obtenido a partir de una biomasa - Google Patents

Producción y acondicionamiento de gas de síntesis obtenido a partir de una biomasa Download PDF

Info

Publication number
ES2547536T3
ES2547536T3 ES09737591.9T ES09737591T ES2547536T3 ES 2547536 T3 ES2547536 T3 ES 2547536T3 ES 09737591 T ES09737591 T ES 09737591T ES 2547536 T3 ES2547536 T3 ES 2547536T3
Authority
ES
Spain
Prior art keywords
synthesis gas
crude synthesis
temperature
steam
biomass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES09737591.9T
Other languages
English (en)
Inventor
Esteban Chornet
Boris Valsecchi
Guillaume Drolet
Martin Gagnon
Betty Nguyen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enerkem Inc
Original Assignee
Enerkem Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41254742&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2547536(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Enerkem Inc filed Critical Enerkem Inc
Application granted granted Critical
Publication of ES2547536T3 publication Critical patent/ES2547536T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/005—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/007—Removal of contaminants of metal compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/06—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials combined with spraying with water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/102—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids containing free acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/14—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic
    • C10K1/143—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic containing amino groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • C10K1/165—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids at temperatures below zero degrees Celsius
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/006—Reducing the tar content by steam reforming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0877—Methods of cooling by direct injection of fluid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/158—Screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1612—CO2-separation and sequestration, i.e. long time storage
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1621—Compression of synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un método para la producción y el tratamiento de gas de síntesis, que comprende: (a) gasificar un material rico en biomasa en presencia de (i), al menos, un agente oxidante seleccionado de entre el aire, el aire enriquecido con oxígeno y el oxígeno con o sin (ii) vapor en un gasificador, que contiene un lecho fluidizado y una sección de espacio abierto, a una temperatura que no supera los 750 °C en el lecho fluidizado para producir un gas de síntesis crudo; someter dicho gas de síntesis crudo a un reformado con vapor en la sección de espacio abierto a una temperatura de 750 °C a 1000 °C, en la que el alquitrán y los finos de carbón pirolítico del gas de síntesis crudo se convierten mediante oxidación controlada en intermedios, y los intermedios se convierten en CO y H2 mediante reformado con vapor, en el que, antes de la refrigeración, el gas de síntesis crudo se somete a un reformado térmico a una temperatura de desde 900 °C hasta 1200 °C mediante la adición de un gas oxidante, convirtiendo de este modo los hidrocarburos ligeros presentes en el gas de síntesis crudo en CO y H2; (b) refrigerar dicho producto de gas de síntesis crudo de la etapa (a); (c) posteriormente a la refrigeración, lavar dicho gas de síntesis refrigerado de la etapa (b); y (d) someter dicho gas de síntesis lavado a, al menos, una etapa de adsorción para proporcionar un gas de síntesis limpio.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
imagen10
E09737591
17-09-2015
sobrenadante de alquitrán o partículas finas, una bomba de recirculación opcional, y un intercambiador de calor agua/agua para enfriar el agua. El alquitrán y los finos se enviaron al tanque de emulsión descrito anteriormente en el presente documento. Una fracción del agua recirculada se purgó y se envió a una planta de tratamiento de aguas residuales.
5 El sintegas procedente del segundo circuito de lavado estaba esencialmente a su nivel de saturación de humedad a aproximadamente 30 °C. Seguidamente se precalentó a de 350 °C a 400 °C y se hizo pasar a través de un lecho de óxido de calcio u óxido de calcio/óxido de magnesio para eliminar cualquier cloruro de hidrógeno adicional (así como cualquier traza de fluoruro de hidrógeno y otros halógenos). El sintegas entró después a un lecho de ZnO en el que
10 cualquier azufre residual formó ZnS estable. Estas operaciones se llevaron a cabo típicamente a 0,2-0,4 MPa. El lecho de óxido de calcio también filtró particulados finos que todavía estaban presentes en el gas después del lavado.
El sintegas que sale del lecho de óxido de cinc estaba a 350-400 °C. A continuación se calentó adicionalmente hasta
15 750-800 °C mediante la inyección de oxígeno/vapor. A esta temperatura entró en la unidad de reformado catalítico en la que una formulación catalítica patentada que puede tratar el alquitrán residual, convierte los hidrocarburos de peso molecular en H2 y CO adicional. El reformador catalítico era: (i) un lecho fijo de perlas catalíticas granulares; o
(ii) un lecho fluidizado en el que el catalizador (preparado en forma de partículas no abrasivas que tienen un diámetro de 200 micrómetros como tamaño típico) actúa como lecho él mismo.
20 A la salida del reformador catalítico el calor se recuperó a través de un intercambiador de calor y se usó en la planta. El vapor se condensó en forma de agua caliente. Esta también se reutilizó.
El sintegas frío se comprimió después a una presión total de 1-1,5 MPa. El gas entró en una torre de lavado en la
25 que el CO2 se retiró hasta un nivel deseado (típicamente un 2,5-3,5 % v/v de CO2) El lavado se efectuó con metanol frío. (De modo alternativo, el lavado se puede efectuar con aminas.) El CO2 recuperado del lavado era esencialmente puro.
El sintegas que contenía H2, CO, CO2 (2,5-3,5 % v/v), metano residual (típicamente aproximadamente un 1 % v/v) y
30 trazas de otros hidrocarburos, se puede usar en la síntesis de metanol. El sintegas se hizo pasar a través de una columna de carbón activado para disminuir la concentración de carbonilos metálicos esencialmente a niveles traza, evitando, de este modo, la contaminación del catalizador de la síntesis de metanol.
Ejemplo 1
35 Gasificación de madera con oxígeno y vapor
Se usó madera triturada, que se obtuvo de diversas especies de árboles caducifolios y árboles coníferos, y que tenía un contenido de humedad del 22 % p/p, como prototipo de biomasa residual obtenida de aserraderos que procesan
40 madera de demolición, postes de transmisión de electricidad, traviesas de ferrocarril, y materiales similares. La madera triturada se convirtió en sintegas de acuerdo con la metodología descrita anteriormente en el presente documento. La madera triturada tenía la siguiente composición en base seca:
materiales inertes (obtenidos en forma de cenizas a 750 °C) 0,7 % p/p
carbono 50,0 % p/p
hidrógeno 6,0 % p/p
oxígeno 42,5 % p/p
nitrógeno 0,1 % p/p
azufre trazas
cloro 0,7 % p/p
45 La madera triturada se alimentó a la sección de lecho fluidizado del gasificador a 185 kg/h. La gasificación se efectuó a una presión de 0,15 MPa en presencia de una mezcla de un 21 % v/v de oxígeno y un 79 % v/v de vapor. El agente fluidizante incluía partículas de alúmina que tenían un tamaño de desde aproximadamente 400 micrómetros hasta aproximadamente 600 micrómetros. La gasificación se efectuó en un modo autotérmico, es decir, sin ninguna aportación externa de calor puesto que el calor requerido fue proporcionado como resultado de la
50 oxidación parcial de la alimentación descompuesta térmicamente a la entrada al gasificador.
La conversión de la madera a sintegas se efectuó durante un período de 37 horas.
El rendimiento de sintegas, tras la secuencia de lavado con agua, fue de 0,86 Nm3 de sintegas seco/kg de biomasa
55 seca. Tal y como se usa en el presente documento, el término "N" significa condiciones normales, es decir, 0 °C y 0,1 MPa como presión absoluta. El sintegas seco incluía los siguientes componentes (en % v/v) tal y como se
12
E09737591
17-09-2015
muestra en la Tabla 1 a continuación.
Tabla 1
Componente del gas
Después del lavado con agua (antes de los lechos de CaO y ZnO) Después del reformado catalítico a una presión total de 0,3 MPa, 800 °C (usando una relación vapor/carbono de 1,3 mol/mol) Tras la eliminación del CO2 del sintegas
N2 y Ar
0,26 0,15 0,21
H2
20,46 45,02 64,87
CHO
21,95 22,42 32,32
CO2
40,85 32,33 2,48
CH4
7,10 0,08 0,12
C2s
4,67 0 0
C3s
3,46 0 0
>C3
1,24 0 0
Benceno (como parte de >C3)
1,01 0 0
Tolueno (como parte de >C3)
0,1226 0 0
Etilbenceno (como parte de >C3)
0,0204 0 0
Xilenos (como parte de >C3)
0,0153 0 0
Estireno (como parte de >C3)
0,1270 0 0
Fenol (como parte de >C3)
0,0002 0 0
Metilestireno (como parte de >C3)
0,0088 0 0
Indeno (como parte de >C3)
0,0068 0 0
Naftaleno (como parte de >C3)
0,0049 0 0
Metilnaftaleno (como parte de >C3)
0,0080 0 0
Fenantreno (como parte de >C3)
0,0000 0 0
NH3
0,0105 0,0000 0
H2S
0,0000 0,0000 0
Particulados (mg/Nm3)
8 2 <1
5 Los lechos de CaO y ZnO no cambiaron la composición del gas pero disminuyeron el nivel de particulados a 2 mg/l. Los compuestos orgánicos listados en la Tabla 1 son componentes del alquitrán de bajo peso molecular. La síntesis de metanol se llevó a cabo con el gas acondicionado usando un reactor de tres fases en el que se
10 suspendió un catalizador de Cu/ZnO/Al2O3. Este funcionó bien a una presión total de 6,5 MPa y 230 °C, y
13
imagen11
imagen12
E09737591
17-09-2015
Tabla 3
Elemento
Elemento en la materia prima alimentada al reactor de gasificación (kg/h) Elemento en el sintegas tras la secuencia de acondicionamiento del gas: N en forma de NH3; Cl en forma de HCl; S en forma de H2S + COS (kg/h) Elemento en los residuos sólidos del proceso (recuperados en los ciclones y retirados del lecho fluido (kg/h) Elemento en el agua de lavado (kg/h) Elementos encontrados en los filtros de CaO y ZnO (kg/h)
N
0,566 0,0000418 0,057 0,00556 0
Cl
0,871 0 0,557 (en CaCl2) 0,08712 (en NaCl y CaCl2) 0
F
0,000001448 0 0,00000130 trazas 0
S
0,317 0 0,142 (en CaS) 0,0173 (en CaSO4) 0
Sb
0,000079646 0,000009271 0,00006372 0,00000048 0,000006181
As
0,000162926 0,000018860 0,00007332 trazas 0,000044006
Cd
0,000181029 0,000004258 0,00008146 0,00008146 0,000000473
Cr
0,015613714 0,000015397 0,01537951 0,00015614 0,000035927
Hg
0,000056571 0,000015436 0,00000113 0,00000396 0,000036017
Pb
0,013350857 0,000078103 0,01228279 0,00066754 0,000312410
Co
0,000226286 0,000001948 0,00022400 0,00000011 0,000000216
Cu
0,002828571 0,000004964 0,00280752 0,00001344 0,000001241
Mn
0,017876571 0,000005212 0,01780085 0,00004469 0,000003475
Ni
0,004865143 0,000056461 0,00457964 0,00004573 0,000131742
Sn
0,005657143 0,000075578 0,00533627 0,00014143 0,000075578
V
0,000565714 0,000027774 0,00049779 0,00000665 0,000018516
TI
0,000090514 0,000004073 0,00008146 0,00000226 0,000000453
Inorgánicos totales
20,69 (en forma de cenizas) 0,002 (en forma de particulados) 29,11 (incluye el carbono sin convertir) 1,54 (incluye el carbono sin convertir) 0,0416
Los resultados anteriores muestran que el gas, antes del reformado catalítico está bastante limpio sin Cl o S y con una concentración de particulados (0,002/212,65=1,337 mg/Nm3) que no influye en el rendimiento de los 5 reformadores.
Ejemplo 4
Se convirtió una muestra de CDR en sintegas. La gasificación del CDR se efectuó en presencia de aire y vapor en
10 una relación de 75 % en volumen de aire y 25 % en volumen de vapor. El vapor se introdujo en forma de agua, ambos como humedad que acompañaba a la alimentación sólida, y de la emulsión, que también incluía alquitranes y particulados, que se recicló al gasificador. El CDR tenían un contenido de humedad del 10 % p/p y fue alimentado al gasificador a una velocidad de flujo de 130 kg/h. La gasificación se efectuó a 740 °C y a una presión de 0,15 MPa. Tras la gasificación y el acondicionamiento de acuerdo con la metodología descrita anteriormente en el presente
15 documento, se efectuó un reformado catalítico en presencia de un catalizador de níquel.
Las cantidades de cloro, azufre, y nitrógeno se monitorizaron en diversas etapas del proceso de conversión y acondicionamiento. Los resultados se muestran en la Tabla 4 a continuación.
16
E09737591
17-09-2015
Componente
Introducido en el gasificador a partir de la carga de alimentación (kg/h) Recuperado en los residuos sólidos de los ciclones y del lecho fluidizado (kg/h) Encontrado en el agua residual (kg/h) En el sintegas después del lavado (kg/h) En el sintegas tras los lechos de CaO y ZnO (kg/h)
Cl
0,9009 0,8903 0,0101 0,0004 (2 mg/Nm3) 0
S
0,3585 0,3214 0,0163 0,0208 0
N (en forma de NH3 equivalente)
0,604 0 0,0009 0,0294 0,0294
Los resultados anteriores muestran que todo el cloro y el azufre se pueden eliminar antes del reformado catalítico. El nitrógeno, presente en forma de NH3, entra en la etapa de reformado catalítico. Como resultado del reformado catalítico en presencia de un catalizador de níquel, el NH3 se convirtió en N2 y H2. La mayor parte del nitrógeno en el CDR de entrada antes de la gasificación estaba en forma de grupos NH2 que estaban presentes en los aminoácidos que quedaban en el CDR tras la clasificación mecánica, y el biosecado y la biocompostación realizados antes de la gasificación.
17

Claims (1)

  1. imagen1
ES09737591.9T 2008-04-29 2009-04-27 Producción y acondicionamiento de gas de síntesis obtenido a partir de una biomasa Active ES2547536T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12583708P 2008-04-29 2008-04-29
US125837 2008-04-29
PCT/CA2009/000575 WO2009132449A1 (en) 2008-04-29 2009-04-27 Production and conditioning of synthesis gas obtained from biomass

Publications (1)

Publication Number Publication Date
ES2547536T3 true ES2547536T3 (es) 2015-10-07

Family

ID=41254742

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09737591.9T Active ES2547536T3 (es) 2008-04-29 2009-04-27 Producción y acondicionamiento de gas de síntesis obtenido a partir de una biomasa

Country Status (12)

Country Link
US (1) US8137655B2 (es)
EP (1) EP2274404B1 (es)
CN (1) CN102015973A (es)
AU (1) AU2009242929B2 (es)
BR (1) BRPI0910716B1 (es)
CA (1) CA2664028C (es)
DK (1) DK2274404T3 (es)
ES (1) ES2547536T3 (es)
HU (1) HUE027651T2 (es)
PL (1) PL2274404T3 (es)
WO (1) WO2009132449A1 (es)
ZA (1) ZA201006945B (es)

Families Citing this family (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10323774A1 (de) * 2003-05-26 2004-12-16 Khd Humboldt Wedag Ag Verfahren und Anlage zur thermischen Trocknung eines nass vermahlenen Zementrohmehls
US8088832B2 (en) 2006-04-05 2012-01-03 Woodland Biofuels Inc. System and method for converting biomass to ethanol via syngas
PL2190950T3 (pl) * 2007-07-20 2017-04-28 Upm-Kymmene Oyj Sposób i urządzenie do wytwarzania ciekłego biopaliwa ze stałej biomasy
US8747656B2 (en) 2008-10-10 2014-06-10 Velocys, Inc. Process and apparatus employing microchannel process technology
US8192647B2 (en) 2008-12-19 2012-06-05 Enerkem Inc. Production of synthesis gas through controlled oxidation of biomass
EP2438280A4 (en) 2009-06-02 2014-03-19 Thermochem Recovery Int Inc CARBURETTOR WITH INTEGRATED FUEL CELL POWER GENERATION SYSTEM
KR100977081B1 (ko) * 2010-03-31 2010-08-19 한국전력공사 가스 연료화 장치 및 방법
CN102892480B (zh) * 2010-05-24 2015-09-09 气体产品与化学公司 用于合成气处理的方法和系统
US8636923B2 (en) * 2010-10-29 2014-01-28 Enerkem, Inc. Production of synthesis gas by heating oxidized biomass with a hot gas obtained from oxidation of residual products
CN103402632A (zh) 2010-11-02 2013-11-20 沙特基础工业公司 通过使用zsm-5-基催化剂生产低碳烯烃的方法
BR112013010886A2 (pt) 2010-11-05 2016-08-02 Thermochem Recovery Int Inc sistema de circulação de sólidos e processo para captura e conversão de sólidos reativos
US8535418B2 (en) * 2010-11-22 2013-09-17 General Electric Company Gaseous byproduct removal from synthesis gas
IT1403189B1 (it) * 2011-01-05 2013-10-15 High Tech En Sro Sistema e metodo per la produzione di syngas da materiale a base carbonica
CA2828250A1 (en) * 2011-03-09 2012-09-13 Linc Energy Ltd Method and apparatus for treating a raw ucg product stream
US9005319B2 (en) * 2011-06-10 2015-04-14 General Electric Company Tar removal for biomass gasification systems
ITFI20110133A1 (it) 2011-07-05 2013-01-06 Rewood S R L Processo di gassificazione.
US8834834B2 (en) * 2011-07-21 2014-09-16 Enerkem, Inc. Use of char particles in the production of synthesis gas and in hydrocarbon reforming
US8987530B2 (en) 2011-09-14 2015-03-24 Enerkem, Inc. Production of alcohols having at least four carbon atoms from carbonaceous materials
US8981165B2 (en) 2011-09-14 2015-03-17 Enerkem, Inc. Production of alcohols having three carbon atoms from carbonaceous materials
AU2012315914B2 (en) 2011-09-27 2015-07-09 Thermochem Recovery International, Inc. System and method for syngas clean-up
FI20116107L (fi) * 2011-11-09 2013-05-10 Upm Kymmene Corp Menetelmä ja järjestelmä nestemäisen polttoaineen tuottamiseksi biomassasta
EP2666533B1 (en) * 2012-05-24 2018-11-14 Grupo Guascor, S.L. Unipersonal Reducing tar balls in gasification system
US9150488B2 (en) 2012-06-22 2015-10-06 Enerkem, Inc. Production of acrylic acid and ethanol from carbonaceous materials
US9950966B2 (en) 2012-07-05 2018-04-24 Gestalt Chemical Products, Inc. Manufacturing of nitrogen-containing materials
SG11201507677VA (en) 2013-03-15 2015-10-29 Celanese Int Corp Process for separating product gas using carbonylation processes
US10190065B2 (en) * 2013-03-15 2019-01-29 Mark E. Koenig Feed delivery system and method for gasifier
US9550630B2 (en) 2013-03-15 2017-01-24 Mark E. Koenig System for processing material for a gasifier
US9034786B2 (en) 2013-03-18 2015-05-19 Enerkem, Inc. Catalysts for producing hydrogen and synthesis gas
US9540241B2 (en) 2013-03-18 2017-01-10 Enerkem, Inc. Catalysts for producing hydrogen and synthesis gas
US9738569B2 (en) 2013-05-15 2017-08-22 Enerkem, Inc. Production of acrylic acid and ethanol from carbonaceous materials
DE102013008422A1 (de) * 2013-05-16 2014-11-20 Ecoloop Gmbh Verfahren zur Reinigung von Synthesegasen
ES2411101B2 (es) 2013-05-21 2013-10-22 Urbaser S. A. Procedimiento para convertir la fracción CDR en un gas de síntesis
US9683184B2 (en) 2013-06-06 2017-06-20 General Electric Company Method and apparatus for gasification
CN103525474B (zh) * 2013-10-30 2014-10-08 西南化工研究设计院有限公司 一种超精脱硫剂及其制备方法
CN103695043B (zh) * 2013-12-26 2015-05-27 上海国际化建工程咨询公司 利用低温甲醇洗干燥、净化和冷却变换粗合成气和sng产品气的方法及其装置
FR3019830B1 (fr) * 2014-04-14 2017-11-24 Gdf Suez Procede et dispositif de traitement d'un gaz de synthese provenant d'une etape de gazeification de biomasse
US9562201B2 (en) 2014-06-28 2017-02-07 Saudi Arabian Oil Company Energy efficient apparatus employing energy efficient process schemes providing enhanced integration of gasification-based multi-generation and hydrocarbon refining facilities and related methods
WO2016118474A1 (en) 2015-01-20 2016-07-28 Midrex Technologies, Inc. Methods and systems for producing high carbon content metallic iron using coke over gas
US10369549B2 (en) 2015-03-20 2019-08-06 Sabic Global Technologies B.V. Use of nickel-manganese olivine and nickel-manganese spinel as bulk metal catalysts for carbon dioxide reforming of methane
CN104910969B (zh) * 2015-05-19 2017-08-04 中国矿业大学(北京) 一种褐煤气化系统及方法
KR101617392B1 (ko) * 2015-11-13 2016-05-09 김현영 산업용 고온 개질기 및 개질 방법
US11058967B2 (en) * 2016-01-19 2021-07-13 Mitsubishi Power Americas, Inc. Waste water evaporation methods and apparatus
ES2940894T3 (es) 2016-02-16 2023-05-12 Thermochem Recovery Int Inc Sistema y método de generación de gas producto de energía integrada de dos etapas
EP3433340B1 (en) 2016-03-25 2022-06-29 ThermoChem Recovery International, Inc. Three-stage energy-integrated product gas generation system
US11473777B2 (en) 2016-06-03 2022-10-18 Wildfire Energy Pty Ltd Methods of producing a gas from a combustible material
US10197014B2 (en) 2016-08-30 2019-02-05 Thermochem Recovery International, Inc. Feed zone delivery system having carbonaceous feedstock density reduction and gas mixing
US10364398B2 (en) 2016-08-30 2019-07-30 Thermochem Recovery International, Inc. Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas
US10197015B2 (en) 2016-08-30 2019-02-05 Thermochem Recovery International, Inc. Feedstock delivery system having carbonaceous feedstock splitter and gas mixing
CN110049944B (zh) 2016-10-25 2022-09-27 内斯特化学股份公司 从源自于废物气化的合成气中制备纯氢气的方法和相关装置
PL3433341T3 (pl) * 2017-01-17 2021-09-27 NextChem S.p.A. Sposób i powiązane urządzenie do wytwarzania czystego bio-metanolu z gazu syntezowego pochodzącego ze zgazowania odpadów
US10329506B2 (en) 2017-04-10 2019-06-25 Thermochem Recovery International, Inc. Gas-solids separation system having a partitioned solids transfer conduit
US10717102B2 (en) 2017-05-31 2020-07-21 Thermochem Recovery International, Inc. Pressure-based method and system for measuring the density and height of a fluidized bed
US9920926B1 (en) 2017-07-10 2018-03-20 Thermochem Recovery International, Inc. Pulse combustion heat exchanger system and method
US10099200B1 (en) 2017-10-24 2018-10-16 Thermochem Recovery International, Inc. Liquid fuel production system having parallel product gas generation
CN107653007A (zh) * 2017-11-08 2018-02-02 中科合肥煤气化技术有限公司 一种高温热煤气水洗除尘循环装置
CN108531219A (zh) * 2018-03-27 2018-09-14 中冶华天工程技术有限公司 一种生物质气化发电系统
AT521211A1 (de) * 2018-04-18 2019-11-15 Gs Gruber Schmidt Kohlendioxid und Wasserdampf Vergasung von biogenen Reststoffen zur Erzeugung von Syngas für Dimethylether
CN109504468A (zh) * 2018-12-26 2019-03-22 陕西煤业化工集团神木天元化工有限公司 一种热解煤气中煤焦油的回收系统
SI25771A (sl) * 2019-01-07 2020-07-31 Teos Perne Naprava za uplinjanje trdnih materialov z vsebnostjo ogljika, s poudarjeno koncentracijo katranov in njihovo katalitsko pretvorbo v ogljikov monoksid in vodik
CA3135515C (en) * 2019-04-12 2022-10-11 Enerkem Inc. Production of synthesis gas from gasifying and reforming carbonaceous material
US12378487B2 (en) 2020-01-23 2025-08-05 Sekisui Chemical Co., Ltd. Method for producing organic substance and apparatus for producing organic substance
CN115210382A (zh) * 2020-01-23 2022-10-18 积水化学工业株式会社 有机物质的制造方法和有机物质制造装置
US11555157B2 (en) 2020-03-10 2023-01-17 Thermochem Recovery International, Inc. System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas
GB2593939B (en) * 2020-04-09 2022-04-27 Velocys Tech Limited Manufacture of a synthetic fuel
US11466223B2 (en) 2020-09-04 2022-10-11 Thermochem Recovery International, Inc. Two-stage syngas production with separate char and product gas inputs into the second stage
GB2612221B (en) * 2020-12-03 2024-11-06 Velocys Tech Ltd Process
GB2601570B (en) * 2020-12-03 2023-03-08 Velocys Tech Ltd Process
CN112678772B (zh) * 2021-01-07 2022-05-03 浙江工业大学 一种甘油沥青资源化处理方法
EP4086328B1 (en) 2021-05-06 2024-08-28 GIDARA Energy B.V. Method and apparatus for industrial production of renewable synthetic fuels
DE202022000489U1 (de) 2022-02-25 2022-05-16 Ralf Abraham Vorrichtung zur Produktion von Synthesegas aus biogenen Rest- und Abfallstoffen
DE102022105359A1 (de) * 2022-03-08 2023-09-14 BHYO GmbH Verfahren zur Herstellung von Wasserstoff aus Biomasse

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4592762A (en) * 1981-10-22 1986-06-03 Institute Of Gas Technology Process for gasification of cellulosic biomass
CN1034422C (zh) * 1991-07-10 1997-04-02 同济大学 高温煤气二步脱硫法
CN1046213C (zh) * 1993-04-26 1999-11-10 中国石化齐鲁石油化工公司 常温氧化锌脱硫剂和制备方法
CA2114965C (fr) 1994-02-04 2004-07-27 Denis Ngoy Bangala Catalyseur de reformage a la vapeur et sa methode de preparation
US6902711B1 (en) * 1996-04-23 2005-06-07 Ebara Corporation Apparatus for treating wastes by gasification
CA2372111A1 (en) * 1999-05-14 2000-11-23 Kemestrie Inc. Process and apparatus for gasification of refuse
WO2001004045A1 (en) 1999-07-09 2001-01-18 Ebara Corporation Process and apparatus for production of hydrogen by gasification of combustible material and method for electric power generation using fuel cell and electric power generation system using fuel cell
CN1228420C (zh) * 2000-02-29 2005-11-23 三菱重工业株式会社 生物质气化炉和利用通过生物质气化所得的气体的甲醇或二甲基醚合成系统
CA2325072A1 (en) * 2000-10-30 2002-04-30 Questair Technologies Inc. Gas separation for molten carbonate fuel cell
CH694696A5 (it) * 2000-12-21 2005-06-15 Nesi Plant S A Procedimento e dispositivo per la produzione di idrogeno e anidride carbonica da gassificazione di materie prime.
US20030115800A1 (en) * 2001-12-18 2003-06-26 Muneyoshi Yamada Method for gasifying biomass and catalyst used for said method
US7753973B2 (en) * 2002-06-27 2010-07-13 Galloway Terry R Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
AU2003274439A1 (en) * 2002-10-28 2004-05-13 Sasol Technology (Proprietary) Limited Production of synthesis gas and synthesis gas derived products
JP2008542481A (ja) * 2005-06-03 2008-11-27 プラスコ エネルギー グループ インコーポレーテッド 石炭を特定の組成のガスへ変換するためのシステム
US7503947B2 (en) * 2005-12-19 2009-03-17 Eastman Chemical Company Process for humidifying synthesis gas
AU2007230919B2 (en) * 2006-03-24 2011-09-22 Res Usa, Llc Biomass gasification system
CN100584924C (zh) * 2006-04-05 2010-01-27 上海兖矿能源科技研发有限公司 一种以可燃含碳固体为原料联产油品、甲醇和电能的方法
CN100577775C (zh) * 2007-05-31 2010-01-06 宋建元 一种循环流化床煤气化装置及使用该装置生成煤气的方法

Also Published As

Publication number Publication date
EP2274404A4 (en) 2012-12-05
BRPI0910716B1 (pt) 2024-04-30
US20100051875A1 (en) 2010-03-04
PL2274404T3 (pl) 2015-12-31
US8137655B2 (en) 2012-03-20
WO2009132449A1 (en) 2009-11-05
ZA201006945B (en) 2012-03-28
CN102015973A (zh) 2011-04-13
AU2009242929B2 (en) 2013-06-27
CA2664028A1 (en) 2009-10-29
DK2274404T3 (en) 2015-10-05
BRPI0910716A2 (pt) 2018-02-06
CA2664028C (en) 2015-02-03
EP2274404B1 (en) 2015-07-15
AU2009242929A1 (en) 2009-11-05
EP2274404A1 (en) 2011-01-19
HUE027651T2 (en) 2016-10-28

Similar Documents

Publication Publication Date Title
ES2547536T3 (es) Producción y acondicionamiento de gas de síntesis obtenido a partir de una biomasa
US9957161B2 (en) Polygeneration production of hydrogen for use in various industrial processes
CN102159683B (zh) 碳质原料的气化方法
US7056487B2 (en) Gas cleaning system and method
ES2602330T3 (es) Método para reducir CO2 en una corriente por conversión a un gas de síntesis para producción de energía
CA2781195C (en) Method and system for biomass hydrogasification
ES2254711T3 (es) Metodo y sistema para gasificar biomasa.
JP6960930B2 (ja) メタン生成を含む電力生産のためのシステムおよび方法
KR20190051032A (ko) 부분 산화를 이용한 동력 생산을 위한 시스템 및 방법
ES2785988T3 (es) Procedimiento de producción de una composición de hidrocarburo
AU2010202465A1 (en) Methods of recycling carbon dioxide to the gasification system
AU2011202128B2 (en) System for integrating acid gas removal and carbon capture
EA029814B1 (ru) Двухстадийная газификация с двойным гашением
CN102238995A (zh) 用于气体料流净化的集成的暖气体脱硫作用和气体轮换反应
Umar et al. An outlook on tar abatement, carbon capture and its utilization for a clean gasification process
DK2419497T3 (en) Process for producing a combustible gas from a fuel
ES2832742T3 (es) Proceso y sistema para la regeneración de un catalizador de reformador de alquitrán
AU2017373374B2 (en) Plant and method for generation of synthesis gas
JP6293472B2 (ja) 水素製造装置および水素製造方法
JP2024532389A (ja) 合成ガス炭素利用率及びバイオ燃料への変換の最大化