ES2549732T3 - Polifosfonatos insolubles y ramificados y métodos relacionados con los mismos - Google Patents

Polifosfonatos insolubles y ramificados y métodos relacionados con los mismos Download PDF

Info

Publication number: ES2549732T3
Authority: ES; Spain
Prior art keywords: reaction mixture; insoluble; time; polyphosphonate; heating
Prior art date: 2007-07-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES08782528.7T

Other languages

English (en)

Spanish (es)

Inventor

Dieter Freitag

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Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

FRX Polymers Inc

Original Assignee

FRX Polymers Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-07-30

Filing date

2008-07-30

Publication date

2015-11-02

2008-07-30 Application filed by FRX Polymers Inc filed Critical FRX Polymers Inc

2015-11-02 Application granted granted Critical

2015-11-02 Publication of ES2549732T3 publication Critical patent/ES2549732T3/es

Status Active legal-status Critical Current

2028-07-30 Anticipated expiration legal-status Critical

Links

238000000034 method Methods 0.000 title claims abstract description 36
239000011541 reaction mixture Substances 0.000 claims abstract description 49
238000006243 chemical reaction Methods 0.000 claims abstract description 45
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 40
239000003054 catalyst Substances 0.000 claims abstract description 37
238000010438 heat treatment Methods 0.000 claims abstract description 28
229930185605 Bisphenol Natural products 0.000 claims abstract description 23
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 19
239000000155 melt Substances 0.000 claims abstract description 10
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims abstract description 9
238000007654 immersion Methods 0.000 claims abstract description 7
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
150000001340 alkali metals Chemical class 0.000 claims abstract description 6
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 61
229920000642 polymer Polymers 0.000 claims description 59
239000000203 mixture Substances 0.000 claims description 48
-1 phosphonic acid diaryl ester Chemical class 0.000 claims description 37
NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical group [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 claims description 21
239000006085 branching agent Substances 0.000 claims description 15
239000000835 fiber Substances 0.000 claims description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
229910052708 sodium Inorganic materials 0.000 claims description 6
239000011734 sodium Substances 0.000 claims description 6
229920000515 polycarbonate Polymers 0.000 claims description 5
238000000576 coating method Methods 0.000 claims description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
239000006260 foam Substances 0.000 claims description 4
239000004417 polycarbonate Substances 0.000 claims description 4
XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims description 3
BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical group C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 claims description 3
UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 claims description 3
229920000106 Liquid crystal polymer Polymers 0.000 claims description 3
239000004952 Polyamide Substances 0.000 claims description 3
229920002732 Polyanhydride Polymers 0.000 claims description 3
239000004698 Polyethylene Substances 0.000 claims description 3
239000004642 Polyimide Substances 0.000 claims description 3
239000004743 Polypropylene Substances 0.000 claims description 3
239000004793 Polystyrene Substances 0.000 claims description 3
229920002396 Polyurea Polymers 0.000 claims description 3
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 3
229920002678 cellulose Polymers 0.000 claims description 3
239000001913 cellulose Substances 0.000 claims description 3
229920003192 poly(bis maleimide) Polymers 0.000 claims description 3
229920000058 polyacrylate Polymers 0.000 claims description 3
229920002239 polyacrylonitrile Polymers 0.000 claims description 3
229920002647 polyamide Polymers 0.000 claims description 3
229920000647 polyepoxide Polymers 0.000 claims description 3
229920000728 polyester Polymers 0.000 claims description 3
229920000573 polyethylene Polymers 0.000 claims description 3
229920001721 polyimide Polymers 0.000 claims description 3
229920001155 polypropylene Polymers 0.000 claims description 3
229920002223 polystyrene Polymers 0.000 claims description 3
229920002635 polyurethane Polymers 0.000 claims description 3
239000004814 polyurethane Substances 0.000 claims description 3
LJSAJMXWXGSVNA-UHFFFAOYSA-N a805044 Chemical compound OC1=CC=C(O)C=C1.OC1=CC=C(O)C=C1 LJSAJMXWXGSVNA-UHFFFAOYSA-N 0.000 claims description 2
239000000853 adhesive Substances 0.000 claims description 2
230000001070 adhesive effect Effects 0.000 claims description 2
150000001450 anions Chemical class 0.000 claims description 2
238000000113 differential scanning calorimetry Methods 0.000 claims description 2
229920001230 polyarylate Polymers 0.000 claims description 2
229920000570 polyether Polymers 0.000 claims description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 2
229920001567 vinyl ester resin Polymers 0.000 claims description 2
OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical class C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 claims 1
239000004215 Carbon black (E152) Substances 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
239000005977 Ethylene Substances 0.000 claims 1
125000003118 aryl group Chemical group 0.000 claims 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 claims 1
150000002430 hydrocarbons Chemical class 0.000 claims 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
229920002554 vinyl polymer Polymers 0.000 claims 1
ZLLNYWQSSYUXJM-UHFFFAOYSA-M tetraphenylphosphanium;phenoxide Chemical compound [O-]C1=CC=CC=C1.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 ZLLNYWQSSYUXJM-UHFFFAOYSA-M 0.000 description 15
238000006116 polymerization reaction Methods 0.000 description 11
230000035484 reaction time Effects 0.000 description 9
229920001707 polybutylene terephthalate Polymers 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
239000000243 solution Substances 0.000 description 8
235000010290 biphenyl Nutrition 0.000 description 6
239000004305 biphenyl Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 5
239000000178 monomer Substances 0.000 description 5
HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 4
238000004821 distillation Methods 0.000 description 4
230000003301 hydrolyzing effect Effects 0.000 description 4
238000012360 testing method Methods 0.000 description 4
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
239000004809 Teflon Substances 0.000 description 3
229920006362 Teflon® Polymers 0.000 description 3
HPUPGAFDTWIMBR-UHFFFAOYSA-N [methyl(phenoxy)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(=O)(C)OC1=CC=CC=C1 HPUPGAFDTWIMBR-UHFFFAOYSA-N 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
239000003431 cross linking reagent Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 3
229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
238000005809 transesterification reaction Methods 0.000 description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
229920000388 Polyphosphate Polymers 0.000 description 2
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
238000013459 approach Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000975 dye Substances 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
230000009970 fire resistant effect Effects 0.000 description 2
239000003063 flame retardant Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000005469 granulation Methods 0.000 description 2
230000003179 granulation Effects 0.000 description 2
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
238000002156 mixing Methods 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 2
229940031826 phenolate Drugs 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
239000001205 polyphosphate Substances 0.000 description 2
235000011176 polyphosphates Nutrition 0.000 description 2
229920000915 polyvinyl chloride Polymers 0.000 description 2
238000012797 qualification Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
USFPINLPPFWTJW-UHFFFAOYSA-N tetraphenylphosphonium Chemical compound C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 USFPINLPPFWTJW-UHFFFAOYSA-N 0.000 description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
CRXRDDSCLVHGAF-UHFFFAOYSA-N 1-phenylfluorene-9,9-diol Chemical compound C=12C(O)(O)C3=CC=CC=C3C2=CC=CC=1C1=CC=CC=C1 CRXRDDSCLVHGAF-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 1
ASURBSPIYIISGI-UHFFFAOYSA-N 4-(3,3,5-trimethylcyclohexyl)phenol Chemical compound C1C(C)(C)CC(C)CC1C1=CC=C(O)C=C1 ASURBSPIYIISGI-UHFFFAOYSA-N 0.000 description 1
ODPYDILFQYARBK-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-1,3,5-triene Chemical class C1=CC=C2SC2=C1 ODPYDILFQYARBK-UHFFFAOYSA-N 0.000 description 1
125000000172 C5-C10 aryl group Chemical group 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000004425 Makrolon Substances 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
239000007983 Tris buffer Substances 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
239000004815 dispersion polymer Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920006351 engineering plastic Polymers 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000010408 film Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
229920005669 high impact polystyrene Polymers 0.000 description 1
125000004464 hydroxyphenyl group Chemical group 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000000976 ink Substances 0.000 description 1
238000010128 melt processing Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
JGTNAGYHADQMCM-UHFFFAOYSA-N perfluorobutanesulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F JGTNAGYHADQMCM-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
229920005596 polymer binder Polymers 0.000 description 1
239000002491 polymer binding agent Substances 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
LVTHXRLARFLXNR-UHFFFAOYSA-M potassium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LVTHXRLARFLXNR-UHFFFAOYSA-M 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
239000012783 reinforcing fiber Substances 0.000 description 1
239000012779 reinforcing material Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical class C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
230000000007 visual effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Compositions Of Macromolecular Compounds (AREA)
Adhesives Or Adhesive Processes (AREA)
Artificial Filaments (AREA)
Fireproofing Substances (AREA)

ES08782528.7T 2007-07-30 2008-07-30 Polifosfonatos insolubles y ramificados y métodos relacionados con los mismos Active ES2549732T3 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US95260807P	2007-07-30	2007-07-30
US952608P		2007-07-30
PCT/US2008/071585 WO2009018336A2 (en)	2007-07-30	2008-07-30	Insoluble and branched polyphosphonates and methods related thereto

Publications (1)

Publication Number	Publication Date
ES2549732T3 true ES2549732T3 (es)	2015-11-02

Family

ID=40120224

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES08782528.7T Active ES2549732T3 (es)	2007-07-30	2008-07-30	Polifosfonatos insolubles y ramificados y métodos relacionados con los mismos

Country Status (7)

Country	Link
US (1)	US9745424B2 (2)
EP (1)	EP2181141B1 (2)
JP (2)	JP5603238B2 (2)
KR (1)	KR101510085B1 (2)
CN (2)	CN104861171B (2)
ES (1)	ES2549732T3 (2)
WO (1)	WO2009018336A2 (2)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9745424B2 (en)	2007-07-30	2017-08-29	Frx Polymers, Inc.	Insoluble and branched polyphosphonates and methods related thereto
US20110237695A1 (en) *	2010-03-23	2011-09-29	Clariant International Ltd.	Flame Retardant Combinations For Polyester Elastomers And Flame Retarded Extrusion Or Molding Compositions Therefrom
WO2012068264A2 (en)	2010-11-17	2012-05-24	Frx Polymers, Inc.	Phosphonate polymers, copolymers, and their respective oligomers as flame retardants for polyester fibers
KR101424525B1 (ko)	2010-12-22	2014-08-01	에프알엑스 폴리머스, 인코포레이티드	올리고머성 포스포네이트 및 이를 포함하는 조성물
KR101362871B1 (ko) *	2010-12-29	2014-02-14	제일모직주식회사	가교형 폴리포스포네이트, 그의 제조 방법 및 이를 포함하는 난연성 열가소성 수지 조성물
KR101649186B1 (ko) *	2011-04-14	2016-08-18	에프알엑스 폴리머스, 인코포레이티드	폴리포스포네이트 및 코폴리포스포네이트 첨가제 혼합물
TWI638005B (zh) *	2011-08-19	2018-10-11	法克斯聚合物股份有限公司	具優越耐火性之熱塑性聚胺基甲酸酯
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2008
- 2008-07-30 US US12/182,590 patent/US9745424B2/en not_active Expired - Fee Related
- 2008-07-30 ES ES08782528.7T patent/ES2549732T3/es active Active
- 2008-07-30 WO PCT/US2008/071585 patent/WO2009018336A2/en not_active Ceased
- 2008-07-30 JP JP2010520151A patent/JP5603238B2/ja not_active Expired - Fee Related
- 2008-07-30 CN CN201510176885.5A patent/CN104861171B/zh not_active Expired - Fee Related
- 2008-07-30 EP EP08782528.7A patent/EP2181141B1/en not_active Not-in-force
- 2008-07-30 KR KR1020107004481A patent/KR101510085B1/ko not_active Expired - Fee Related
- 2008-07-30 CN CN200880106263A patent/CN101802054A/zh active Pending
2014
- 2014-02-25 JP JP2014034420A patent/JP2014139317A/ja active Pending

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Publication number	Publication date
KR20100053589A (ko)	2010-05-20
US20090032770A1 (en)	2009-02-05
WO2009018336A3 (en)	2009-03-19
JP2010535281A (ja)	2010-11-18
CN104861171A (zh)	2015-08-26
WO2009018336A2 (en)	2009-02-05
JP5603238B2 (ja)	2014-10-08
CN101802054A (zh)	2010-08-11
EP2181141A2 (en)	2010-05-05
EP2181141B1 (en)	2015-09-02
JP2014139317A (ja)	2014-07-31
KR101510085B1 (ko)	2015-04-10
CN104861171B (zh)	2018-04-24
US9745424B2 (en)	2017-08-29

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