ES2549864T3 - Producción de dihidronepetalactona por hidrogenación de nepetalactona - Google Patents

Producción de dihidronepetalactona por hidrogenación de nepetalactona Download PDF

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Publication number
ES2549864T3
ES2549864T3 ES07863146.2T ES07863146T ES2549864T3 ES 2549864 T3 ES2549864 T3 ES 2549864T3 ES 07863146 T ES07863146 T ES 07863146T ES 2549864 T3 ES2549864 T3 ES 2549864T3
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ES
Spain
Prior art keywords
temperatures
temperature
nepetalactone
dihydronepetalactone
trans
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES07863146.2T
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English (en)
Inventor
Keith W. Hutchenson
Scott Christopher Jackson
Leo Ernest Manzer
Mark A. Scialdone
Mayis Seapan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of ES2549864T3 publication Critical patent/ES2549864T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/94—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un procedimiento para preparar dihidronepetalactona que comprende: (a) poner en contacto en una mezcla de reacción una cantidad inicial de trans-cis nepetalactona, descrita por la estructura de la fórmula I, y una cantidad inicial de cis-trans nepetalactona descrita por la estructura de fórmula II, **Fórmula** con hidrógeno y un primer catalizador de hidrogenación sólido a una primera temperatura o temperaturas, hasta que la cantidad en peso de trans-cis nepetalactona en la mezcla de reacción no es mayor que aproximadamente 50% de su cantidad inicial, para formar una primera mezcla de productos; y (b) poner en contacto la primera mezcla de productos con hidrógeno y un segundo catalizador de hidrogenación sólido a una segunda temperatura o temperaturas, para formar una dihidronepetalactona; en donde la etapa (a) se lleva a cabo a una temperatura o temperaturas en el intervalo de 0ºC a 100ºC, y la etapa (b) se lleva a cabo a una temperatura o temperaturas en el intervalo de 50ºC a 150ºC; y en donde la temperatura o temperaturas en la etapa (b) son mayores que la temperatura o temperaturas en la etapa (a), caracterizado porque el primer y segundo catalizadores de hidrogenación sólidos contienen platino.

Description

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12
14
ES07863146.2T 2006-12-21 2007-12-20 Producción de dihidronepetalactona por hidrogenación de nepetalactona Active ES2549864T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US87656806P 2006-12-21 2006-12-21
US876568P 2006-12-21
PCT/US2007/025987 WO2008079252A1 (en) 2006-12-21 2007-12-20 Production of dihydronepetalactone by hydrogenation of nepetalactone

Publications (1)

Publication Number Publication Date
ES2549864T3 true ES2549864T3 (es) 2015-11-02

Family

ID=39273109

Family Applications (1)

Application Number Title Priority Date Filing Date
ES07863146.2T Active ES2549864T3 (es) 2006-12-21 2007-12-20 Producción de dihidronepetalactona por hidrogenación de nepetalactona

Country Status (8)

Country Link
US (1) US8765975B2 (es)
EP (1) EP2114911B1 (es)
CN (1) CN101563334B (es)
CA (1) CA2673047C (es)
DK (1) DK2114911T3 (es)
ES (1) ES2549864T3 (es)
SI (1) SI2114911T1 (es)
WO (1) WO2008079252A1 (es)

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US7547793B2 (en) * 2003-03-19 2009-06-16 E.I. Du Pont De Nemours And Company Method for making insect repellent composition
CN101442908B (zh) * 2006-05-10 2016-09-28 纳幕尔杜邦公司 配制的壁虱和昆虫驱除组合物
ES2634265T3 (es) * 2006-12-21 2017-09-27 E. I. Du Pont De Nemours And Company Destilación de vapor de plantas de albahaca de gato
US9521844B2 (en) 2006-12-21 2016-12-20 E I Du Pont De Nemours And Company Solvent addition and removal in the hydrogenation of catmint oil
US8558015B2 (en) * 2006-12-21 2013-10-15 E I Du Pont De Nemours And Company Solvent addition and removal in the hydrogenation of catmint oil
US8552210B2 (en) * 2006-12-21 2013-10-08 E I Du Pont De Nemours And Company Hydrogenation of catmint oil
BRPI0719468A2 (pt) * 2006-12-21 2014-02-11 Du Pont "processo para a preparação de um produto de reação, composição da matéria ou um artigo de fabricação e método para proporcionar a fragrância, ou revitalizar, a pele, couro, pêlos, peles, penas ou outra superfície"
CA2673047C (en) 2006-12-21 2014-08-19 E. I. Du Pont De Nemours And Company Production of dihydronepetalactone by hydrogenation of nepetalactone
ES2442010T3 (es) * 2007-11-26 2014-02-07 E. I. Du Pont De Nemours And Company Método para convertir trans-cis nepetalactona en cis-trans nepetalactona utilizando tamices moleculares
US9085747B2 (en) 2009-11-11 2015-07-21 E I Du Pont De Nemours And Company Method for the enhanced recovery of catmint oil
CN104181239B (zh) * 2013-05-23 2015-09-30 湖北航天化学技术研究所 硝酸酯增塑聚醚推进剂中功能助剂含量的测定方法
CN105738545A (zh) * 2014-12-12 2016-07-06 湖北航天化学技术研究所 叠氮聚醚推进剂中有机功能助剂含量色谱测定方法
WO2019113387A1 (en) 2017-12-07 2019-06-13 Zymergen Inc. Engineered biosynthetic pathways for production of (6e)-8-hydroxygeraniol by fermentation
JP2021506316A (ja) 2017-12-21 2021-02-22 ザイマージェン インコーポレイテッド ネペタラクトールオキシドレダクターゼ、ネペタラクトールシンターゼ、及びネペタラクトンを産生する能力がある微生物
WO2024186653A2 (en) * 2023-03-03 2024-09-12 Entomol Products, Llc Methods for making dihydronepetalactone and applications therefor
US12378213B1 (en) 2024-08-13 2025-08-05 William Allen Boulanger Process for the hydrogenation of catnip oil

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US4476147A (en) * 1982-05-20 1984-10-09 International Flavors & Fragrances Inc. Flavoring of alliaceous-flavored foodstuffs
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US20040127553A1 (en) * 2002-03-20 2004-07-01 Hallahan David L. Insect repellent compositions comprising dihydronepetalactone
CA2480116C (en) * 2002-04-03 2011-01-04 E. I. Du Pont De Nemours And Company Production of dihydronepetalactone by hydrogenation of nepetalactone
WO2003086069A2 (en) * 2002-04-08 2003-10-23 Jodi Haenke Materials and methods for controlling wood-boring insects
US7820145B2 (en) * 2003-08-04 2010-10-26 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
BR0318501A (pt) 2003-09-18 2006-09-12 Du Pont método de repelir insetos ou carrapatos de hospedeiros
CA2546820A1 (en) * 2003-11-26 2005-06-16 E. I. Du Pont De Nemours And Company Derivatives of dihydronepetalactone and method for preparation
US20050137252A1 (en) * 2003-12-22 2005-06-23 Scialdone Mark A. Production of dihydronepetalactone
GB0409542D0 (en) * 2004-04-29 2004-06-02 Unilever Plc Cosmetic compositions
WO2006050519A1 (en) 2004-11-03 2006-05-11 E.I. Dupont De Nemours And Company Insect repellent compositions comprising dihydronepetalactone, an alcohol, and an ester
US20060148842A1 (en) * 2004-12-29 2006-07-06 Scialdone Mark A Nepetalactams and N-substituted derivatives thereof
WO2006072037A1 (en) * 2004-12-29 2006-07-06 E. I. Du Pont De Nemours And Company Dihydronepetalactams and n-substituted derivatives thereof
US20060201391A1 (en) * 2005-03-09 2006-09-14 Scialdone Mark A Compositions having sustained-release insect repellency
US7435851B2 (en) * 2005-09-30 2008-10-14 E.I. Du Pont De Nemours And Company Puleganic amides
JP2009510100A (ja) * 2005-09-30 2009-03-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー プレガン酸昆虫忌避剤
CN101442908B (zh) * 2006-05-10 2016-09-28 纳幕尔杜邦公司 配制的壁虱和昆虫驱除组合物
ES2634265T3 (es) * 2006-12-21 2017-09-27 E. I. Du Pont De Nemours And Company Destilación de vapor de plantas de albahaca de gato
BRPI0719468A2 (pt) * 2006-12-21 2014-02-11 Du Pont "processo para a preparação de um produto de reação, composição da matéria ou um artigo de fabricação e método para proporcionar a fragrância, ou revitalizar, a pele, couro, pêlos, peles, penas ou outra superfície"
US8552210B2 (en) * 2006-12-21 2013-10-08 E I Du Pont De Nemours And Company Hydrogenation of catmint oil
US8558015B2 (en) * 2006-12-21 2013-10-15 E I Du Pont De Nemours And Company Solvent addition and removal in the hydrogenation of catmint oil
CA2673047C (en) 2006-12-21 2014-08-19 E. I. Du Pont De Nemours And Company Production of dihydronepetalactone by hydrogenation of nepetalactone
DE102007026049A1 (de) * 2007-05-31 2008-12-04 Beiersdorf Ag Repellentien gegen Wespen
ES2442010T3 (es) * 2007-11-26 2014-02-07 E. I. Du Pont De Nemours And Company Método para convertir trans-cis nepetalactona en cis-trans nepetalactona utilizando tamices moleculares

Also Published As

Publication number Publication date
EP2114911A1 (en) 2009-11-11
CN101563334B (zh) 2012-08-22
SI2114911T1 (sl) 2015-12-31
CA2673047C (en) 2014-08-19
US20100168447A1 (en) 2010-07-01
HK1136295A1 (en) 2010-06-25
CA2673047A1 (en) 2008-07-03
CN101563334A (zh) 2009-10-21
DK2114911T3 (en) 2015-12-14
EP2114911B1 (en) 2015-09-02
WO2008079252A1 (en) 2008-07-03
US8765975B2 (en) 2014-07-01

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