ES2554983T3 - Agente de lavado inhibidor del agrisado - Google Patents
Agente de lavado inhibidor del agrisado Download PDFInfo
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- ES2554983T3 ES2554983T3 ES08735743.0T ES08735743T ES2554983T3 ES 2554983 T3 ES2554983 T3 ES 2554983T3 ES 08735743 T ES08735743 T ES 08735743T ES 2554983 T3 ES2554983 T3 ES 2554983T3
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- alkyl
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- alkylene
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- 239000003795 chemical substances by application Substances 0.000 title abstract description 14
- 238000005406 washing Methods 0.000 title abstract description 10
- 239000003112 inhibitor Substances 0.000 title abstract description 3
- 239000012459 cleaning agent Substances 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 3
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 abstract 1
- 125000000837 carbohydrate group Chemical group 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000005755 formation reaction Methods 0.000 description 7
- 239000004753 textile Substances 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 5
- -1 fatty acid esters Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical class [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical class O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- BLFGQHDZMHMURV-UHFFFAOYSA-N 4-oxo-2-phenylchromene-3-carboxylic acid Chemical class O1C2=CC=CC=C2C(=O)C(C(=O)O)=C1C1=CC=CC=C1 BLFGQHDZMHMURV-UHFFFAOYSA-N 0.000 description 1
- REJHVSOVQBJEBF-UHFFFAOYSA-N 5-azaniumyl-2-[2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical class OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 description 1
- CJIJXIFQYOPWTF-UHFFFAOYSA-N 7-hydroxycoumarin Natural products O1C(=O)C=CC2=CC(O)=CC=C21 CJIJXIFQYOPWTF-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical group 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical class OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001851 cinnamic acid derivatives Chemical class 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 150000004775 coumarins Chemical class 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- ORHBXUUXSCNDEV-UHFFFAOYSA-N umbelliferone Chemical compound C1=CC(=O)OC2=CC(O)=CC=C21 ORHBXUUXSCNDEV-UHFFFAOYSA-N 0.000 description 1
- HFTAFOQKODTIJY-UHFFFAOYSA-N umbelliferone Natural products Cc1cc2C=CC(=O)Oc2cc1OCC=CC(C)(C)O HFTAFOQKODTIJY-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Agente de lavado, que es líquido y contiene hasta un 85 % en peso de agua, que contiene tensioactivo, así como en su caso otros ingredientes habituales de agentes de lavado y limpieza, conteniendo el agente un compuesto inhibidor del agrisado de la fórmula general IV,**Fórmula** en la que R representa alquileno C1-C12; k representa un número mayor que 0, X representa CO-CH>=CH2, CO-C(CH3)>=CH2, CO-O-arilo, alquilen-C2-C6-SO2-CH>=CH2 o CO-NH-R1; y R1 representa alquilo C1-C30, halogenoalquilo C1-C30, hidroxialquilo C1-C30, alquiloxi-C1-C6-alquilo C1-C30, alquilcarboniloxi-C1-C6- alquilo C1-C30, amino-alquilo C1-C30, mono- o di(alquil-C1-C6)-amino-alquilo C1-C30, amonio-alquilo C1-C30, polioxialquilen-alquilo C1-C30, polisiloxanil-alquilo C1-C30, (met)acriloiloxi-alquilo C1-C30, sulfono-alquilo C1-C30, fosfono-alquilo C1-C30, di(alquil-C1-C6)fosfono-alquilo C1-C30, fosfonato-alquilo C1-C30, di(alquil-C1-C6)fosfonatoalquilo C1-C30 o un resto sacarídico, teniendo X este significado solo cuando k representa 1, o X representa (i) el resto de una poliamina al que está unida la parte de fórmula que está entre corchetes a través de grupos (CO)NH o (ii) un armazón polimérico al que está unida la parte de fórmula que está entre corchetes a través de grupos (CO), NH-alquilen-C2-C6-O(CO) o (CO)-O-alquilen-C2-C6-O(CO) o (iii) un armazón polimérico al que está unida la parte de fórmula que está entre corchetes a través de grupos (CO)- polisiloxanil-alquilo C1-C30, cuando k representa un número mayor que 1, y/o un polímero que se puede obtener mediante reacción de un sustrato polimérico, que dispone de grupos funcionales, que se seleccionan de grupos hidroxilo, grupos amino primarios y secundarios, con un compuesto de la fórmula general IV.
Description
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Como inhibidores de espuma que se pueden emplear en los agentes de lavado o limpieza se consideran, por ejemplo, jabones, parafinas o aceites de silicona que pueden estar aplicados, eventualmente, también sobre materiales de soporte.
Son agentes antirredeposición adecuados, que se denominan también "repelentes de suciedad", por ejemplo, los polímeros del ácido ftálico y/o tereftálico conocidos del estado de la técnica o de sus derivados, en especial polímeros de tereftalatos de etileno y/o tereftalatos de polietilenglicol o derivados modificados de modo aniónico y/o no iónico de estos. Especialmente preferidos de estos son los derivados sulfonados de los polímeros de ácido ftálico y tereftálico.
Se pueden añadir aclarantes ópticos a los agentes de lavado y limpieza para quitar zonas amarillentas de la formación plana textil tratada. Estas sustancias se fijan sobre la fibra y causan una iluminación al transformar la radiación ultravioleta invisible para el ojo humano en luz visible de longitud de onda más larga, irradiándose la luz ultravioleta absorbida de la luz solar como fluorescencia débilmente azulada y resultando con el tono amarillo de la ropa amarilleada un blanco puro. Los compuestos adecuados proceden, por ejemplo, de las clases de sustancias de los ácidos 4,4'-diamino-2,2'-estilbenodisulfónico (ácidos flavónicos), 4,4'-diestiril-bifenileno, metilumbeliferonas, cumarinas, dihidroquinolinonas, 1,3-diarilpirazolinas, imidas de ácido naftalénico, sistemas de benzoxazol, bencisoxazol y bencimidazol así como los derivados de pireno sustituidos por heterociclos. Los aclarantes ópticos se emplean habitualmente en cantidades de hasta el 0,5 % en peso, particularmente entre el 0,03 % en peso y el 0,3 % en peso con respecto al agente terminado.
Ya que las formaciones planas textiles, en particular de rayón, viscosilla, algodón y sus mezclas, pueden tender a arrugarse, debido a que las fibras individuales son sensibles a doblamiento, plegado, prensado y apriete transversalmente con respecto a la dirección de la fibra, los agentes pueden contener agentes antiarrugas sintéticos. A esto pertenecen, por ejemplo, productos sintéticos a base de ácidos grasos, ésteres de ácidos grasos, amidas de ácidos grasos, ésteres de alquilol graso, amidas de alquilol graso o alcoholes grasos que la mayoría de las veces se han hecho reaccionar con óxido de etileno, o productos a base de lecitina o ésteres de ácido fosfórico modificados. Para combatir microorganismos, los agentes de lavado y limpieza pueden contener principios activos antimicrobianos. En este caso se diferencia, dependiendo del espectro antimicrobiano y del mecanismo de acción, entre bacteriostáticos y bactericidas, fungistáticos y fungicidas, etc. Son sustancias importantes de estos grupos, por ejemplo, cloruros de benzalconio, sulfonatos de alquilarilo, fenoles halogenados y fenolmercuriacetato, pudiendo prescindirse también completamente de estos compuestos en los agentes de acuerdo con la invención.
Para evitar cambios indeseados causados por la acción de oxígeno y otros procesos oxidativos en los agentes de lavado y limpieza y/o las formaciones planas textiles tratadas, los agentes pueden contener antioxidantes. A esta clase de compuestos pertenecen, por ejemplo, fenoles sustituidos, hidroquinonas, brenzcatequinas y aminas aromáticas así como sulfuros orgánicos, polisulfuros, ditiocarbamatos, fosfitos y fosfonatos. En la utilización de tales antioxidantes los agentes de acuerdo con la invención están libres de agentes de blanqueo oxidantes.
Una mayor comodidad de uso puede resultar a partir del uso adicional de antiestáticos que se añaden adicionalmente a los agentes. Los antiestáticos amplían la conductividad superficial y, por tanto, posibilitan una descarga mejorada de las cargas formadas. Los antiestáticos externos por norma general son sustancias con al menos un ligando de molécula hidrófilo y aplican sobre las superficies una película más o menos higroscópica. Estos antiestáticos la mayoría de las veces con actividad interfacial se pueden clasificar en antiestáticos que contienen nitrógeno (aminas, amidas, compuestos de amonio cuaternario), que contienen fósforo (ésteres de ácido fosfórico) y que contienen azufre (sulfonatos de alquilo, sulfatos de alquilo). Antiestáticos externos son, por ejemplo, cloruros de lauril-(o estearil-)dimetilbencilamonio que son adecuados como antiestáticos para formaciones planas textiles o como aditivo para agentes de lavado, consiguiéndose adicionalmente un efecto de avivamiento.
Para mejorar la capacidad de absorción de agua, la re-humectabilidad de las formaciones planas textiles tratadas y para facilitar el planchado de las formaciones planas textiles tratadas pueden emplearse en los agentes de lavado y limpieza, por ejemplo, derivados de silicona. Estos mejoran adicionalmente el comportamiento de eliminación por enjuagado de los agentes gracias a sus propiedades inhibidoras de espuma. Son derivados de silicona preferidos, por ejemplo, polidialquil-o alquilarilsiloxanos en los que los grupos alquilo presentan de uno a cinco átomos de C y están completa o parcialmente fluorados. Son siliconas preferidas polidimetilsiloxanos que, eventualmente, pueden estar derivatizados y entonces tienen funcionalidad amino o están cuaternizados o que presentan enlaces Si-OH, Si-H y/o Si-CI. Las viscosidades de las siliconas preferidas se encuentran a 25 ºC en el intervalo entre 100 y 100.000 mPas, pudiendo emplearse las siliconas en cantidades entre el 0,2 y el 5 % en peso con respecto a todo el agente.
Finalmente, los agentes de lavado y limpieza pueden contener también absorbedores UV que se fijan sobre las formaciones planas textiles tratadas y que mejoran la resistencia a la luz de las fibras. Los compuestos que presentan estas propiedades deseadas son, por ejemplo, los compuestos eficaces mediante desactivación sin radiación y derivados de la benzofenona con sustituyentes en posición 2 y/o 4. Además también son adecuados benzotriazoles sustituidos, acrilatos sustituidos con fenilo en posición 3 (derivados de ácido cinámico), eventualmente con grupos ciano en posición 2, salicilatos, complejos de Ni orgánicos así como sustancias naturales, tales como umbeliferona y ácido urocánico.
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Claims (1)
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imagen1 imagen2
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007016382A DE102007016382A1 (de) | 2007-04-03 | 2007-04-03 | Vergrauungsinhibierendes Waschmittel |
| DE102007016382 | 2007-04-03 | ||
| DE102007023872 | 2007-05-21 | ||
| DE200710023872 DE102007023872A1 (de) | 2007-05-21 | 2007-05-21 | Vergrauungsinhibierendes Waschmittel |
| DE200710038451 DE102007038451A1 (de) | 2007-08-14 | 2007-08-14 | Vergrauungsinhibierendes Waschmittel |
| DE102007038451 | 2007-08-14 | ||
| PCT/EP2008/053994 WO2008119831A2 (de) | 2007-04-03 | 2008-04-03 | Vergrauungsinhibierendes waschmittel |
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| ES2554983T3 true ES2554983T3 (es) | 2015-12-28 |
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| EP (1) | EP2134826B1 (es) |
| KR (1) | KR20090128443A (es) |
| ES (1) | ES2554983T3 (es) |
| WO (1) | WO2008119831A2 (es) |
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2008
- 2008-04-03 ES ES08735743.0T patent/ES2554983T3/es active Active
- 2008-04-03 KR KR1020097020613A patent/KR20090128443A/ko not_active Withdrawn
- 2008-04-03 WO PCT/EP2008/053994 patent/WO2008119831A2/de not_active Ceased
- 2008-04-03 EP EP08735743.0A patent/EP2134826B1/de not_active Not-in-force
-
2009
- 2009-10-02 US US12/572,634 patent/US8044016B2/en not_active Expired - Fee Related
-
2011
- 2011-09-20 US US13/237,054 patent/US8324145B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20100022428A1 (en) | 2010-01-28 |
| EP2134826B1 (de) | 2015-11-04 |
| WO2008119831A2 (de) | 2008-10-09 |
| KR20090128443A (ko) | 2009-12-15 |
| US8044016B2 (en) | 2011-10-25 |
| WO2008119831A3 (de) | 2009-02-05 |
| EP2134826A2 (de) | 2009-12-23 |
| US8324145B2 (en) | 2012-12-04 |
| US20120004155A1 (en) | 2012-01-05 |
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