ES2562858B2 - Polímero para la inmovilización de especies de mercurio - Google Patents

Polímero para la inmovilización de especies de mercurio Download PDF

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Publication number
ES2562858B2
ES2562858B2 ES201500704A ES201500704A ES2562858B2 ES 2562858 B2 ES2562858 B2 ES 2562858B2 ES 201500704 A ES201500704 A ES 201500704A ES 201500704 A ES201500704 A ES 201500704A ES 2562858 B2 ES2562858 B2 ES 2562858B2
Authority
ES
Spain
Prior art keywords
mercury
polymer
immobilization
spaces
species
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES201500704A
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English (en)
Other versions
ES2562858A1 (es
Inventor
María Riansares MUÑOZ OLIVAS
Carmen CÁMARA RICA
María José MANCHEÑO REAL
Sonia ZARCO FERNÁNDEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Complutense University of Madrid
Original Assignee
Complutense University of Madrid
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Complutense University of Madrid filed Critical Complutense University of Madrid
Priority to ES201500704A priority Critical patent/ES2562858B2/es
Publication of ES2562858A1 publication Critical patent/ES2562858A1/es
Application granted granted Critical
Publication of ES2562858B2 publication Critical patent/ES2562858B2/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/20—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

Polímero para la inmovilización de especies de mercurio.#La elevada toxicidad del mercurio hace necesaria la búsqueda de métodos de limpieza y recuperación de espacios contaminados. Se presenta un nuevo material polimérico altamente eficaz en dicha captura que presenta, además, una afinidad selectiva hacia distintas especies de mercurio.#El polímero se obtiene por polimerización radicalaria de un monómero derivado de tiourea y NOBE.#El nuevo material puede constituir una herramienta novedosa como sistema de limpieza en aguas residuales, vertidos o lixiviados procedentes de fuentes antropogénicas de mercurio, así como elemento de detoxificación de espacios en los que el mercurio se encuentre presente en cualquiera de sus formas más volátiles.

Description

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Claims (1)

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ES201500704A 2015-09-30 2015-09-30 Polímero para la inmovilización de especies de mercurio Active ES2562858B2 (es)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ES201500704A ES2562858B2 (es) 2015-09-30 2015-09-30 Polímero para la inmovilización de especies de mercurio

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201500704A ES2562858B2 (es) 2015-09-30 2015-09-30 Polímero para la inmovilización de especies de mercurio

Publications (2)

Publication Number Publication Date
ES2562858A1 ES2562858A1 (es) 2016-03-08
ES2562858B2 true ES2562858B2 (es) 2016-09-26

Family

ID=55411074

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201500704A Active ES2562858B2 (es) 2015-09-30 2015-09-30 Polímero para la inmovilización de especies de mercurio

Country Status (1)

Country Link
ES (1) ES2562858B2 (es)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR208284A1 (es) * 1973-03-24 1976-12-20 Bayer Ag Resinas sinteticas que contienen grupos tioureicos susceptibles de ser aplicadas para la absorcion de compuestos metalicos y procedimiento para la produccion
DD212190A1 (de) * 1982-12-09 1984-08-08 Bitterfeld Chemie Verfahren zur quecksilbergewinnung aus waessrigen loesungen
US4902765A (en) * 1988-07-19 1990-02-20 American Cyanamid Company Allyl thiourea polymers

Also Published As

Publication number Publication date
ES2562858A1 (es) 2016-03-08

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