ES2564980T3 - Composición hidrófuga/oleófuga, método para la producción de la misma y artículo - Google Patents

Composición hidrófuga/oleófuga, método para la producción de la misma y artículo Download PDF

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Publication number
ES2564980T3
ES2564980T3 ES08752162.1T ES08752162T ES2564980T3 ES 2564980 T3 ES2564980 T3 ES 2564980T3 ES 08752162 T ES08752162 T ES 08752162T ES 2564980 T3 ES2564980 T3 ES 2564980T3
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monomer
units derived
group
polymerized units
following
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Minako Shimada
Kazunori Sugiyama
Yuuichi Oomori
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AGC Inc
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Asahi Glass Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Una composición hidrófuga/oleófuga que comprende un copolímero que tiene unidades polimerizadas derivadas del siguiente monómero (a) y unidades polimerizadas derivadas del siguiente monómero (b), en la que la proporción de las unidades polimerizadas derivadas del monómero (b) es del 30 al 80% molar en el total (100% molar) de las unidades polimerizadas derivadas del monómero (a) y las unidades polimerizadas derivadas del monómero (b), y en la que el copolímero tiene adicionalmente unidades polimerizadas derivadas del siguiente monómero (c), en la que la proporción de las unidades polimerizadas derivadas del monómero (c) es del 4,9 al 20% en masa en el copolímero (100% en masa): monómero (a): un compuesto de la siguiente fórmula (1): (Z-Y)nX (1) en la que Z es un grupo perfluoroalquilo C1-6 o un grupo de la siguiente fórmula (2), Y es un grupo orgánico bivalente o un enlace sencillo, n es 1 o 2, y X es uno de los grupos de las siguientes fórmulas (3-1) a (3-5) cuando n es 1, o uno de los grupos de las siguientes fórmulas (4-1) a (4-4) cuando n es 2; CiF2i+1O(CFX1CF2O)jCFX2- (2) en la que i es un número entero de 1 a 6, j es un número entero de 0 a 10, y cada uno de X1 y X2 es un átomo de flúor o un grupo trifluorometilo; -CR>=CH2 (3-1) -C(O)OCR>=CH2 (3-2) -OC(O)CR>=CH2 (3-3) -OCH2-Φ-CR>=CH2 (3-4) -OCH>=CH2 (3-5) en las que R es un átomo de hidrógeno, un grupo metilo o un átomo de halógeno, y Φ representa un grupo fenileno; -CH[-(CH2)mCR>=CH2]- (4-1) -CH[-(CH2)mC(O)OCR>=CH2]- (4-2) -CH[-(CH2)mOC(O)CR>=CH2]- (4-3) -OC(O)CH>=CHC(O)O- (4-4) en las que R es un átomo de hidrógeno, un grupo metilo o un átomo de halógeno, y m es un número entero de 0 a 4; monómero (b): un (met)acrilato que no tiene ningún grupo polifluoroalquilo y que tiene un grupo alquilo C20-30; y monómero (c): cloruro de vinilo.
ES08752162.1T 2007-04-27 2008-04-25 Composición hidrófuga/oleófuga, método para la producción de la misma y artículo Active ES2564980T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2007120229 2007-04-27
JP2007120229 2007-04-27
PCT/JP2008/058128 WO2008136436A1 (ja) 2007-04-27 2008-04-25 撥水撥油剤組成物、その製造方法および物品

Publications (1)

Publication Number Publication Date
ES2564980T3 true ES2564980T3 (es) 2016-03-30

Family

ID=39943543

Family Applications (1)

Application Number Title Priority Date Filing Date
ES08752162.1T Active ES2564980T3 (es) 2007-04-27 2008-04-25 Composición hidrófuga/oleófuga, método para la producción de la misma y artículo

Country Status (9)

Country Link
US (1) US8703864B2 (es)
EP (1) EP2141213B1 (es)
JP (1) JP5585078B2 (es)
KR (1) KR101441716B1 (es)
CN (1) CN101668827A (es)
CA (1) CA2681820A1 (es)
ES (1) ES2564980T3 (es)
TW (1) TWI431105B (es)
WO (1) WO2008136436A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009041648A1 (ja) * 2007-09-28 2009-04-02 Asahi Glass Company, Limited 撥水撥油剤組成物および物品
WO2009113589A1 (ja) 2008-03-12 2009-09-17 旭硝子株式会社 共重合体およびその製造方法
EP2284204B1 (en) * 2008-06-04 2013-08-14 Asahi Glass Company, Limited Copolymer, method for producing the same and water repellent oil repellent composition
CN102197106A (zh) * 2008-10-24 2011-09-21 旭硝子株式会社 斥水斥油剂组合物及其制造方法
JP5195373B2 (ja) * 2008-12-08 2013-05-08 旭硝子株式会社 ウレタン／尿素化合物、その製造方法および撥水剤組成物
WO2011001650A1 (ja) * 2009-07-03 2011-01-06 Ａｇｃセイミケミカル株式会社 水性樹脂エマルジョンおよびフロアポリッシュ組成物
KR20120104576A (ko) * 2009-12-25 2012-09-21 아사히 가라스 가부시키가이샤 발수 발유제 조성물, 그 제조 방법 및 물품의 처리 방법
US8975348B2 (en) 2010-02-12 2015-03-10 E I Du Pont De Nemours And Company Non-aqueous composition comprising partially fluorinated methacrylic polymers
KR101789346B1 (ko) * 2010-02-15 2017-10-23 아사히 가라스 가부시키가이샤 박리제 조성물
JPWO2012020806A1 (ja) * 2010-08-11 2013-10-28 旭硝子株式会社 撥水撥油剤組成物および物品
KR101910682B1 (ko) * 2011-04-25 2018-10-22 에이지씨 가부시키가이샤 발수발유제 조성물, 그 제조 방법 및 물품
IN2015DN01516A (es) 2012-08-01 2015-07-03 Asahi Glass Co Ltd
WO2014186962A1 (en) * 2013-05-23 2014-11-27 Evonik Specialty Chemicals (Shanghai) Co., Ltd. Process for emulsion polymerizing fluorine-containing monomers
KR102345704B1 (ko) * 2013-11-26 2021-12-30 에이지씨 가부시키가이샤 발수 발유제 조성물, 물품, 및 물품의 제조 방법
WO2016098823A1 (ja) 2014-12-17 2016-06-23 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品
KR102528045B1 (ko) 2015-05-27 2023-05-02 에이지씨 가부시키가이샤 발수 발유제 조성물, 그 제조 방법 및 물품
JP7103017B2 (ja) * 2017-08-07 2022-07-20 Ａｇｃ株式会社 撥水剤組成物、および物品
CN111836870B (zh) * 2018-03-08 2023-03-24 Ａｇｃ株式会社 拒水拒油剂组合物的制造方法及拒水拒油性物品的制造方法
JP7279480B2 (ja) * 2019-04-09 2023-05-23 Ａｇｃ株式会社 透湿防水布帛の製造方法
JPWO2022220198A1 (es) * 2021-04-15 2022-10-20

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07182267A (ja) * 1993-12-24 1995-07-21 Mitsubishi Electric Corp 出力制御回路
AU707886B2 (en) * 1995-07-27 1999-07-22 Asahi Glass Company Limited Water and oil repellent composition, treating method therewith and copolymer
JP3624615B2 (ja) * 1997-02-28 2005-03-02 ユニマテック株式会社 新規共重合体およびそれを含有する撥水撥油剤
US6380336B1 (en) * 1998-03-24 2002-04-30 Nano-Tex, Llc Copolymers and oil-and water-repellent compositions containing them
DE60233192D1 (de) * 2001-04-13 2009-09-17 Asahi Glass Co Ltd Hydrophobe und lipophobe zusammensetzung
TW200416277A (en) * 2002-10-15 2004-09-01 Asahi Glass Co Ltd Water-and-oil repellant composition
KR100751611B1 (ko) * 2003-11-13 2007-08-22 다이킨 고교 가부시키가이샤 발수 발유제 수성 분산액
EP1788047B1 (en) * 2004-08-25 2013-11-20 Daikin Industries, Ltd. Water-repellent/oil-repellent composition
WO2009008512A1 (ja) * 2007-07-11 2009-01-15 Asahi Glass Company, Limited 撥水撥油剤組成物の製造方法および物品

Also Published As

Publication number Publication date
EP2141213B1 (en) 2016-01-13
EP2141213A1 (en) 2010-01-06
WO2008136436A1 (ja) 2008-11-13
JP5585078B2 (ja) 2014-09-10
CA2681820A1 (en) 2008-11-13
US8703864B2 (en) 2014-04-22
KR101441716B1 (ko) 2014-09-17
KR20100014382A (ko) 2010-02-10
CN101668827A (zh) 2010-03-10
TW200904957A (en) 2009-02-01
TWI431105B (zh) 2014-03-21
US20100087597A1 (en) 2010-04-08
EP2141213A4 (en) 2011-07-27
JPWO2008136436A1 (ja) 2010-07-29

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