ES2570141T3 - Composición con propiedades de tenacidad mejoradas - Google Patents
Composición con propiedades de tenacidad mejoradasInfo
- Publication number
- ES2570141T3 ES2570141T3 ES12190582T ES12190582T ES2570141T3 ES 2570141 T3 ES2570141 T3 ES 2570141T3 ES 12190582 T ES12190582 T ES 12190582T ES 12190582 T ES12190582 T ES 12190582T ES 2570141 T3 ES2570141 T3 ES 2570141T3
- Authority
- ES
- Spain
- Prior art keywords
- rubber
- weight
- acrylonitrile
- styrene
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 10
- 239000005060 rubber Substances 0.000 abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 9
- 229920000126 latex Polymers 0.000 abstract 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 5
- 239000002245 particle Substances 0.000 abstract 5
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 abstract 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 2
- -1 -methylstyrene Chemical compound 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 238000009757 thermoplastic moulding Methods 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 238000005199 ultracentrifugation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Procedimiento para la preparación de masas moldeables termoplásticas del tipo ABS que contienen A) al menos un caucho de injerto obtenido mediante polimerización en emulsión de al menos dos monómeros seleccionados de estireno, -metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N-fenilmaleinimida en presencia de uno o varios látex de caucho, ascendiendo el diámetro de partícula promedio d50 del látex de caucho o de los látex de caucho a >290 nm, B) al menos un caucho de injerto obtenido mediante polimerización en emulsión de al menos dos monómeros seleccionados de estireno, α-metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N-fenilmaleinimida en presencia de uno o varios látex de caucho, ascendiendo el diámetro de partícula promedio d50 del látex de caucho o de los látex de caucho >=320 nm, seleccionándose los látex de caucho de polibutadieno, copolímeros de butadieno/estireno con hasta el 20 % en peso de estireno incorporado y copolímeros de butadieno/acrilonitrilo con hasta el 15 % en peso de acrilonitrilo incorporado, y C) al menos una resina polimérica termoplástica libre de caucho obtenida mediante polimerización por radicales de al menos dos monómeros seleccionados de estireno, α-metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N-fenilmaleinimida, usando un reactor amasador, caracterizado por que a) los componentes de caucho de injerto A) y B) se prepararon conjuntamente en una reacción de polimerización, b) la proporción en % en peso del caucho que procede del componente de caucho de injerto A) en la cantidad total de caucho en la masa moldeable del 0 % al 25 % en peso es menor que la proporción de caucho en % en peso que procede del componente de caucho de injerto B) (en cada caso con respecto a 100 partes en peso de caucho de injerto) y c) el diámetro de partícula promedio d50 de la totalidad de todas las partículas de caucho contenidas en la masa moldeable presenta un valor >=300 nm, determinándose los diámetros de partícula promedio d50 mediante medición por ultracentrifugación.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10223646A DE10223646A1 (de) | 2002-05-28 | 2002-05-28 | Verfahren zur Herstellung von ABS-Zusammensetzungen mit verbesserten Zähigkeitseigenschaften |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2570141T3 true ES2570141T3 (es) | 2016-05-17 |
Family
ID=29432373
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03755102.5T Expired - Lifetime ES2497115T3 (es) | 2002-05-28 | 2003-05-15 | Procedimiento para la producción de composiciones de ABS con propiedades de tenacidad mejoradas |
| ES12190582T Expired - Lifetime ES2570141T3 (es) | 2002-05-28 | 2003-05-15 | Composición con propiedades de tenacidad mejoradas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03755102.5T Expired - Lifetime ES2497115T3 (es) | 2002-05-28 | 2003-05-15 | Procedimiento para la producción de composiciones de ABS con propiedades de tenacidad mejoradas |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20030225219A1 (es) |
| EP (2) | EP1511807B1 (es) |
| JP (1) | JP2005527680A (es) |
| KR (1) | KR100933619B1 (es) |
| CN (1) | CN100387650C (es) |
| AU (1) | AU2003232776A1 (es) |
| CA (1) | CA2487139A1 (es) |
| DE (1) | DE10223646A1 (es) |
| ES (2) | ES2497115T3 (es) |
| MX (1) | MXPA04011733A (es) |
| TW (1) | TWI297025B (es) |
| WO (1) | WO2003099926A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1783170A1 (en) * | 2005-10-24 | 2007-05-09 | Basf Aktiengesellschaft | Thermoplastic molding composition comprising finely divided inert materials |
| DE102006056523A1 (de) * | 2006-11-30 | 2008-06-05 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Pfropfkautschuken, Pfropfkautschuke und thermoplastische Formmassen auf Basis dieser Pfropfkautschuke |
| CN101570588B (zh) * | 2008-04-30 | 2010-09-29 | 中国石油天然气股份有限公司 | 一种双峰分布abs的制备方法 |
| CN101667006B (zh) * | 2009-09-25 | 2011-05-25 | 武汉科技学院 | 新型光学全息记录材料及制备方法 |
| FR2969167B1 (fr) * | 2010-12-15 | 2013-01-11 | Arkema France | Composition thermoplastique modifiee choc amelioree |
| KR101533136B1 (ko) * | 2011-12-14 | 2015-07-01 | 주식회사 엘지화학 | 충격강도가 우수한 열가소성 ａｂｓ 수지 조성물 |
| WO2014061429A1 (ja) * | 2012-10-15 | 2014-04-24 | 旭化成ケミカルズ株式会社 | 熱可塑性樹脂組成物及びその成形体 |
| WO2015004112A1 (de) * | 2013-07-11 | 2015-01-15 | Styrolution Group Gmbh | Verfahren zur herstellung von thermoplastischen formmassen, sowie danach hergestellte thermoplastische formmassen |
| WO2015091817A1 (de) * | 2013-12-18 | 2015-06-25 | Styrolution Group Gmbh | Formmassen basierend auf vinylaromat-copolymeren für den 3d druck |
| EP3298079B1 (de) | 2015-05-18 | 2019-01-23 | INEOS Styrolution Group GmbH | Abs-formmasse mit guter eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
| EP3615578B2 (de) | 2017-04-24 | 2023-11-15 | INEOS Styrolution Group GmbH | Verbessertes verfahren zur herstellung von abs-pfropfcopolymeren |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1379391A (en) | 1921-05-24 | Vtiiicanizing-pad | ||
| DE1495626B1 (de) | 1960-03-30 | 1971-06-09 | Bayer Ag | Verfahren zum herstellen von polyestern |
| NL123047C (es) | 1960-09-20 | |||
| FR1580834A (es) | 1968-01-04 | 1969-09-12 | ||
| CA953838A (en) | 1970-01-14 | 1974-08-27 | Donald A. Bennett | Preparation of graft copolymers |
| CA942446A (en) * | 1970-07-30 | 1974-02-19 | Walter Laber | Incorporating rubber into thermoplastics |
| DE2232877B2 (de) | 1972-07-05 | 1980-04-10 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zur Herstellung von Polyestern |
| CH578138A5 (es) | 1973-02-28 | 1976-07-30 | Jylland Gummivarefabriken As | |
| DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
| DE2420358B2 (de) | 1974-04-26 | 1980-02-07 | Bayer Ag, 5090 Leverkusen | Formmassen |
| JPS5292295A (en) | 1976-01-29 | 1977-08-03 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester |
| IT1116721B (it) | 1976-04-02 | 1986-02-10 | Allied Chem | Copolimero bisfenolo a tereftalato carbonato lavorabili in massa fusa |
| DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
| DE2724360C3 (de) | 1977-05-28 | 1988-03-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten |
| EP0007810A3 (en) | 1978-07-31 | 1980-02-20 | Monsanto Company | A process for emulsion grafting diene rubber particles |
| DE2842005A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Polycarbonate mit alkylphenyl-endgruppen, ihre herstellung und ihre verwendung |
| JPS5594930A (en) | 1979-01-10 | 1980-07-18 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester by improved bulk polymerization process |
| DD144415A1 (de) | 1979-06-20 | 1980-10-15 | Frans Steffers | Verfahren zum agglomerieren von butadien-copolymerisatlatices |
| IT1127266B (it) | 1979-11-27 | 1986-05-21 | Montedison Spa | Procedimento per agglomerare lattici di gomme |
| DE3506472A1 (de) | 1985-02-23 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Neue polydiorganosiloxan-polycarbonat-blockcopolymere |
| DE3639904A1 (de) | 1986-11-22 | 1988-06-01 | Bayer Ag | Bifunktionelle emulgatoren auf basis von perhydrobisphenolen und carbonsaeureanhydriden |
| JPH0618618B2 (ja) | 1987-03-20 | 1994-03-16 | 三菱重工業株式会社 | 撹拌装置 |
| DE3844633A1 (de) | 1988-08-12 | 1990-04-19 | Bayer Ag | Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten |
| DE3913509A1 (de) | 1989-04-25 | 1990-10-31 | Bayer Ag | Neue emulgatoren und verfahren zur herstellung grobteiliger homodisperser polymerdispersionen unter verwendung dieser emulgatoren |
| DE4018069A1 (de) | 1990-06-06 | 1991-12-12 | Bayer Ag | Selbstreinigender reaktor/mischer mit grossem nutzvolumen |
| DE4118884A1 (de) | 1991-06-07 | 1992-12-10 | List Ag | Mischkneter |
| DE4126425A1 (de) | 1991-08-09 | 1993-02-11 | Bayer Ag | Vollstaendig selbstreinigender reaktor/mischer mit grossem nutzvolumen |
| DE4131872A1 (de) | 1991-09-25 | 1993-04-08 | Basf Ag | Verfahren zur herstellung schlagzaehmodifizierter thermoplaste |
| US5817266A (en) * | 1994-01-27 | 1998-10-06 | Basf Aktiengesellschaft | Dewatering of water-moist graft rubber |
| DE4402394B4 (de) | 1994-01-27 | 2005-02-10 | Basf Ag | Verfahren zur Entwässerung von wasserfeuchtem Pfropfkautschuk |
| DE59600015D1 (de) * | 1995-03-27 | 1997-08-28 | Basf Ag | Verfahren zur Herstellung von Thermoplasten |
| DE59600302D1 (de) | 1995-03-27 | 1998-08-06 | Basf Ag | Verfahren zur Herstellung von Thermoplasten |
| EP0734826B1 (de) | 1995-03-27 | 1998-01-21 | Basf Aktiengesellschaft | Verfahren zur Herstellung von Thermoplasten |
| EP0735077B1 (de) * | 1995-03-27 | 1998-07-29 | BASF Aktiengesellschaft | Verfahren zur Herstellung von Thermoplasten |
| DE19639592A1 (de) * | 1996-09-26 | 1998-04-02 | Basf Ag | Thermoplastische Formmassen |
| DE19649255A1 (de) * | 1996-11-28 | 1998-06-04 | Bayer Ag | Thermoplastische Hochglanz-Formmassen vom ABS-Typ |
| DE19713039A1 (de) | 1997-03-27 | 1998-10-01 | Bayer Ag | Verfahren zur Herstellung von elastomermodifizierten Thermoplasten |
| TWI230727B (en) * | 1999-03-25 | 2005-04-11 | Bayer Ag | Compositions containing polycarbonate and grafted rubber having improved low-temperature toughness |
| US6528583B1 (en) | 2000-03-30 | 2003-03-04 | Bayer Corporation | Thermoplastic molding composition having improved dimensional stability and low gloss |
-
2002
- 2002-05-28 DE DE10223646A patent/DE10223646A1/de not_active Withdrawn
-
2003
- 2003-05-15 MX MXPA04011733A patent/MXPA04011733A/es active IP Right Grant
- 2003-05-15 CA CA002487139A patent/CA2487139A1/en not_active Abandoned
- 2003-05-15 WO PCT/EP2003/005104 patent/WO2003099926A1/de not_active Ceased
- 2003-05-15 ES ES03755102.5T patent/ES2497115T3/es not_active Expired - Lifetime
- 2003-05-15 CN CNB038171228A patent/CN100387650C/zh not_active Expired - Fee Related
- 2003-05-15 KR KR1020047019169A patent/KR100933619B1/ko not_active Expired - Lifetime
- 2003-05-15 AU AU2003232776A patent/AU2003232776A1/en not_active Abandoned
- 2003-05-15 EP EP03755102.5A patent/EP1511807B1/de not_active Expired - Lifetime
- 2003-05-15 ES ES12190582T patent/ES2570141T3/es not_active Expired - Lifetime
- 2003-05-15 JP JP2004508173A patent/JP2005527680A/ja not_active Withdrawn
- 2003-05-15 EP EP12190582.2A patent/EP2584001B1/de not_active Expired - Lifetime
- 2003-05-21 US US10/442,459 patent/US20030225219A1/en not_active Abandoned
- 2003-05-27 TW TW092114201A patent/TWI297025B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TWI297025B (en) | 2008-05-21 |
| WO2003099926A1 (de) | 2003-12-04 |
| KR20050014840A (ko) | 2005-02-07 |
| CN100387650C (zh) | 2008-05-14 |
| DE10223646A1 (de) | 2003-12-11 |
| EP2584001A1 (de) | 2013-04-24 |
| ES2497115T3 (es) | 2014-09-22 |
| TW200412360A (en) | 2004-07-16 |
| AU2003232776A1 (en) | 2003-12-12 |
| CA2487139A1 (en) | 2003-12-04 |
| CN1668694A (zh) | 2005-09-14 |
| JP2005527680A (ja) | 2005-09-15 |
| EP2584001B1 (de) | 2016-03-16 |
| EP1511807B1 (de) | 2014-06-25 |
| MXPA04011733A (es) | 2005-07-14 |
| EP1511807A1 (de) | 2005-03-09 |
| KR100933619B1 (ko) | 2009-12-23 |
| US20030225219A1 (en) | 2003-12-04 |
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