ES2574635T3 - Capa para tuberías hecha a base de una composición de polietileno multimodal - Google Patents

Capa para tuberías hecha a base de una composición de polietileno multimodal Download PDF

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Publication number
ES2574635T3
ES2574635T3 ES09764750.7T ES09764750T ES2574635T3 ES 2574635 T3 ES2574635 T3 ES 2574635T3 ES 09764750 T ES09764750 T ES 09764750T ES 2574635 T3 ES2574635 T3 ES 2574635T3
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Prior art keywords
ethylene copolymer
layer made
polyethylene composition
pipe layer
multimodal polyethylene
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Active
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ES09764750.7T
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English (en)
Inventor
Jari Äärilä
Jarmo Harjuntausta
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Borealis GmbH
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Borealis GmbH
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B32B1/08—Tubular products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • F16L9/133—Rigid pipes of plastics with or without reinforcement the walls consisting of two layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/72—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00—Tubular articles, e.g. hoses, pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Tubería que comprende una capa hecha a base de una composición de polietileno que comprende una resina de base de polietileno, que comprende a. un copolímero de etileno (A) y b. un copolímero de etileno (B), en la que el copolímero de etileno (A) tiene un peso molecular promedio en peso menor que el copolímero de etileno (B), y el copolímero de etileno (A) tiene una densidad de 0,935 a 0,955 g/cm3, y el copolímero de etileno (B) tiene una densidad de 0,880 a 0,930 g/cm3, y la resina de base de polietileno tiene un índice de fluidez MFR2 (2,16 kg/190ºC) de 0,1 a 3,5 g/10 min y una densidad de 0,915 g/cm3 a 0,940 g/cm3, y en la que el copolímero de etileno (A) tiene un contenido de comonómeros entre el 1 y el 10% molar y el copolímero de etileno (B) tiene un contenido de comonómeros entre el 5 y 20% molar.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
h. Contracción
La contracción se midió según la norma AEIC C S5-94
5 i. CTL
La resistencia al desarrollo de fisuras lentas se determina según la norma ISO 6252-1992 (E).
La prueba CTL es una prueba para el desarrollo acelerado de fisuras lentas donde la aceleración se mantiene
10 mediante temperatura elevada de 60ºC. La prueba se realiza en una solución surfactante y la incorporación de una entalla acelera el tiempo hasta el fallo y garantiza una deformación plana en las muestras. La tensión en estas muestras se modificó entre 4,0 MPa y 7,0 MPa (tensión real en la región entallada). El surfactante utilizado en esta prueba fue IGEPAL CO-730. Un ejemplo de las dimensiones de las piezas de prueba puede verse a continuación.
15 Las muestras se preparan presionando una placa (véase la figura 1). Las placas se fresan posteriormente a las dimensiones adecuadas en un dispositivo de fijación en dos de los lados. Una entalla frontal de 2,5 mm de profundidad se corta a continuación en la muestra con una cuchilla instalada en una máquina de entallado (diseño N.BROWN) la velocidad de entallado es de 0,2 mm/min. En los dos lados restantes, se cortan surcos laterales de 0,8. Después de realizar las entallas, la muestra se acondiciona a 23 ± 1ºC y el 50% de humedad relativa durante,
20 como mínimo, 48 horas. Las muestras se montan a continuación en la cámara de prueba en la que se mantiene la solución activa. La solución activa es una solución acuosa al 10% de IGEPAL CO-730 (sustancia química éter nonilfenílico de polietilenglicol).
Las muestras se cargan con un peso muerto. En el momento de la rotura, un temporizador automático se detiene. 25
A: longitud total de 125 a 130 mm
B: Anchura en los extremos 21 ± 0,5 mm
C: Distancia al centro entre soportes 90 mm
D: Longitud paralela 30 ± 0,5 mm 30 E: Anchura de la parte paralela estrecha 9 ± 0,5 mm
F: Diámetro de Hale 10 mm
G: Entalla principal 2,5 ± 0,02 mm
H: Surcos laterales 0,8 mm
I: Grosor de la placa 6 ± 0,2 mm 35
Ejemplos
Ejemplo 1
40 Como catalizador a, se utilizó un catalizador de Ziegler-Natta (ZN) a base de sílice normal. Opcionalmente, puede utilizarse un catalizador ZN a base de MgCl2. El catalizador se preparó según el ejemplo 3 del documento EP 688794.
Condiciones de polimerización: 45
Prepolimerizador
Temp.
ºC 70
Alimentación de catalizador
g/hora 4
H2/C3
g/kg 0,1
C4/C2
g/kg 40
Reactor de bucle
Temp.
ºC 85
H2/C2
mol/kmol 315
C4/C2
mol/kmol 720
MFR2
g/10 min 345
Densidad
kg/m3 948
7
imagen6

Claims (1)

  1. imagen1
ES09764750.7T 2008-12-19 2009-12-09 Capa para tuberías hecha a base de una composición de polietileno multimodal Active ES2574635T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08022192A EP2199650A1 (en) 2008-12-19 2008-12-19 Layer for pipes made of multimodal polyethylene composition
EP08022192 2008-12-19
PCT/EP2009/008807 WO2010069505A1 (en) 2008-12-19 2009-12-09 Layer for pipes made of multimodal polyethylene composition

Publications (1)

Publication Number Publication Date
ES2574635T3 true ES2574635T3 (es) 2016-06-21

Family

ID=40560282

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09764750.7T Active ES2574635T3 (es) 2008-12-19 2009-12-09 Capa para tuberías hecha a base de una composición de polietileno multimodal

Country Status (8)

Country Link
US (1) US20120227852A1 (es)
EP (2) EP2199650A1 (es)
KR (1) KR101374998B1 (es)
CN (1) CN102245951A (es)
AU (1) AU2009328587A1 (es)
BR (1) BRPI0922207B1 (es)
ES (1) ES2574635T3 (es)
WO (1) WO2010069505A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106585014A (zh) * 2016-12-20 2017-04-26 常熟市科恒电工塑胶厂 一种耐热高强度复合塑料制品

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI942949A0 (fi) 1994-06-20 1994-06-20 Borealis Polymers Oy Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav
DE19515678B4 (de) * 1995-04-28 2007-12-27 Basell Polyolefine Gmbh Rohr aus Polyethylen mit verbesserten mechanischen Eigenschaften
BE1011282A3 (fr) * 1997-07-14 1999-07-06 Solvay Composition a base de polyethylene et procede de fabrication d'objets faconnes a partir de la composition.
EP0989140A1 (en) * 1998-09-25 2000-03-29 Fina Research S.A. Production of multimodal polyethylene
DE60106219T2 (de) * 2001-06-27 2006-03-09 Borealis Technology Oy Propylen-Copolymer mit zufälliger Comonomerverteilung und Verfahren zu seiner Herstellung
JP5006516B2 (ja) * 2002-10-10 2012-08-22 中国石油化工股▲分▼有限公司 含ケイ素アルミナ担体、その調製法、ならびに、当該アルミナ担体を含む触媒
US7230054B2 (en) * 2004-06-29 2007-06-12 Equistar Chemicals, Lp Polymer resins with improved environmental stress crack resistance
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
DE602005011421D1 (de) * 2005-06-30 2009-01-15 Borealis Tech Oy Überzug-Schicht für Energie- oder Kommunikationskabel
EP1764389B1 (en) * 2005-09-15 2008-05-21 Borealis Technology Oy Pressureless pipe comprising a multimodal polyethylene composition with an inorganic filler
EP1942135A1 (en) * 2006-12-28 2008-07-09 Borealis Technology Oy Polyolefin composition and pipe with reduced taste and odour

Also Published As

Publication number Publication date
EP2359042A1 (en) 2011-08-24
KR20110079694A (ko) 2011-07-07
CN102245951A (zh) 2011-11-16
EP2199650A1 (en) 2010-06-23
AU2009328587A1 (en) 2010-06-24
BRPI0922207A2 (pt) 2015-12-29
BRPI0922207B1 (pt) 2019-10-08
US20120227852A1 (en) 2012-09-13
EP2359042B1 (en) 2016-04-13
KR101374998B1 (ko) 2014-03-14
WO2010069505A1 (en) 2010-06-24

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