ES2579553T3 - Reactor de carbonatación de flujo circulante con alto contenido de materiales sólidos - Google Patents

Reactor de carbonatación de flujo circulante con alto contenido de materiales sólidos Download PDF

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Publication number
ES2579553T3
ES2579553T3 ES12162734.3T ES12162734T ES2579553T3 ES 2579553 T3 ES2579553 T3 ES 2579553T3 ES 12162734 T ES12162734 T ES 12162734T ES 2579553 T3 ES2579553 T3 ES 2579553T3
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ES
Spain
Prior art keywords
carbonation reactor
meco3
cfb
stream
solid materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES12162734.3T
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English (en)
Inventor
Olaf Stallmann
Michael BALFE
Gerhard Heinz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GE Vernova GmbH
Original Assignee
General Electric Technology GmbH
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Filing date
Publication date
Application filed by General Electric Technology GmbH filed Critical General Electric Technology GmbH
Application granted granted Critical
Publication of ES2579553T3 publication Critical patent/ES2579553T3/es
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/82—Solid phase processes with stationary reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/60—Preparation of carbonates or bicarbonates in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B15/00—Fluidised-bed furnaces; Other furnaces using or treating finely-divided materials in dispersion
    • F27B15/02—Details, accessories or equipment specially adapted for furnaces of these types
    • F27B15/16—Arrangements of cooling devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Combustion & Propulsion (AREA)
  • Geology (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)

Abstract

Un método para capturar dióxido de carbono CO2 por carbonatación en un reactor de carbonatación (10) de lecho fluidizado circulante (CFB), que comprende las etapas de: - remitir una corriente rica en un óxido metálico MeO (13) a un reactor de carbonatación (10) de lecho fluidizado circulante (CFB); - remitir una corriente gaseosa (14) rica en dióxido de carbono CO2 a dicho reactor de carbonatación (10) de CFB; - capturar dióxido de carbono CO2 haciendo reaccionar el dióxido de carbono CO2 con un óxido metálico MeO, formando un carbonato metálico MeCO3; - separar el carbonato metálico MeCO3 desde el gas de chimenea en un dispositivo de separación (30); - recoger una corriente de materiales sólidos ricos en un carbonato metálico MeCO3 desde el dispositivo de separación (30); - subsiguientemente enfriar y dividir o dividir y enfriar a dicha corriente de materiales sólidos ricos en un carbonato metálico MeCO3 en dos o más corrientes sólidas enfriadas, formando dos o más porciones; caracterizado por - ajustar el perfil de temperaturas de dicho reactor de carbonatación (10) de CFB por adición de unas porciones enfriadas de dicha corriente de materiales sólidos ricos en un MeCO3 al reactor de carbonatación (10) de CFB en diversos lugares posibles con el fin de optimizar el perfil de temperaturas para las finalidades de captura de CO2.

Description

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Claims (1)

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ES12162734.3T 2012-03-30 2012-03-30 Reactor de carbonatación de flujo circulante con alto contenido de materiales sólidos Active ES2579553T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12162734.3A EP2644257B1 (en) 2012-03-30 2012-03-30 High solids flux circulating carbonation reactor

Publications (1)

Publication Number Publication Date
ES2579553T3 true ES2579553T3 (es) 2016-08-12

Family

ID=48430877

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12162734.3T Active ES2579553T3 (es) 2012-03-30 2012-03-30 Reactor de carbonatación de flujo circulante con alto contenido de materiales sólidos

Country Status (6)

Country Link
US (2) US9573096B2 (es)
EP (1) EP2644257B1 (es)
CN (1) CN104185501B (es)
CA (1) CA2866337A1 (es)
ES (1) ES2579553T3 (es)
WO (1) WO2013144872A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106824094B (zh) * 2017-02-28 2019-06-14 南京师范大学 一种利用改性煤矸石脱除电厂烟气co2的系统及其实施方法
GR1009502B (el) * 2017-11-13 2019-04-04 Εθνικο Κεντρο Ερευνας Και Τεχνολογικης Αναπτυξης (Εκετα)/Ινστιτουτο Χημικων Διεργασιων Και Ενεργειακων Πορων (Ιδεπ) Μεθοδος και διαταξη βελτιστοποιησης αντιδραστηρων ρευστοποιημενης κλινης που δεσμευουν διοξειδιο του ανθρακα με παραμετρο τη χωρικη κατανομη της εγχυσης του στερεου δεσμευτη
JP7305633B2 (ja) * 2018-05-29 2023-07-10 積水化学工業株式会社 触媒、二酸化炭素還元方法、及び二酸化炭素還元装置
CN115591484B (zh) * 2022-09-13 2024-06-07 深圳中科翎碳生物科技有限公司 轮机废热与尾气co2耦合催化制备乙酸的系统与方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2741546A (en) * 1952-07-02 1956-04-10 Exxon Research Engineering Co Floating control for fluidized solids system
SE7503313L (sv) * 1975-03-21 1976-09-22 Stora Kopparbergs Bergslags Ab Sett for omvandling av kolhaltiga material innehallande svavel till i huvudsak svavelfri brennbar gas samt anordning for genomforande av settet
AU6862081A (en) * 1980-03-21 1981-09-24 Conoco Inc. Method of producing a synthetic co2 acceptor and regenerating same
FI96136C (fi) * 1992-10-02 1996-05-10 Einco Oy Menetelmä lämmön siirtämiseksi regeneratiivisesti
FR2814533B1 (fr) * 2000-09-27 2002-10-31 Alstom Power Nv Procede pour reduire simultanement les emissions de co2 de so2 dans une installation de combustion
DE102007015082A1 (de) * 2007-03-29 2008-10-02 Leithner, Reinhard, Prof. Dr. techn. CO2-Abscheidung aus Abgasen mit CaO und Kalzinierung mittels Hochtemperaturwärmetauschern
CN101298023B (zh) * 2008-06-17 2010-12-22 东南大学 高活性钾基吸收剂干法脱除烟气中co2的装置及方法
DE102008050816B4 (de) 2008-10-08 2013-09-05 Alstom Technology Ltd. Verfahren und Anordnung zur Abscheidung von CO2 aus Verbrennungsabgas
FR2937881A1 (fr) * 2008-11-04 2010-05-07 Jean Xavier Morin Procede et dispositif de capture de co2 sur gaz industriels a basse temperature.
ES2339733B1 (es) * 2008-11-21 2011-03-15 Union Fenosa Generacion, S.A. Procedimiento y dispositivo para la combustion de biomasa sin emisionde dioxido de carbono.
EP2614877A1 (en) * 2012-01-13 2013-07-17 Alstom Technology Ltd Method and system for low emission CO2 capture

Also Published As

Publication number Publication date
EP2644257A1 (en) 2013-10-02
CN104185501A (zh) 2014-12-03
US10589227B2 (en) 2020-03-17
US20150017081A1 (en) 2015-01-15
EP2644257B1 (en) 2016-03-30
US9573096B2 (en) 2017-02-21
US20170144104A1 (en) 2017-05-25
CA2866337A1 (en) 2013-10-03
AU2013239157A1 (en) 2014-10-16
CN104185501B (zh) 2017-05-03
WO2013144872A1 (en) 2013-10-03

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