ES2579907R1 - Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento - Google Patents

Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento Download PDF

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Publication number
ES2579907R1
ES2579907R1 ES201590118A ES201590118A ES2579907R1 ES 2579907 R1 ES2579907 R1 ES 2579907R1 ES 201590118 A ES201590118 A ES 201590118A ES 201590118 A ES201590118 A ES 201590118A ES 2579907 R1 ES2579907 R1 ES 2579907R1
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Spain
Prior art keywords
perovskita
high performance
solar cells
organic
cells sensitized
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ES201590118A
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English (en)
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ES2579907B1 (es
ES2579907A2 (es
Inventor
Julian Alexander BURSCHKA
Mohammad Khaja Nazeeruddin
Michael Graetzel
Shahzada Ahmad
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Abengoa Research SL
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Abengoa Research SL
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Priority claimed from EP20130382181 external-priority patent/EP2804232A1/en
Application filed by Abengoa Research SL filed Critical Abengoa Research SL
Publication of ES2579907A2 publication Critical patent/ES2579907A2/es
Publication of ES2579907R1 publication Critical patent/ES2579907R1/es
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G21/00—Compounds of lead
    • C01G21/16—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/24—Lead compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H01G9/2063—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution comprising a mixture of two or more dyes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H10K30/151—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2 the wide bandgap semiconductor comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/50—Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/10—Transparent electrodes, e.g. using graphene
    • H10K2102/101—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO]
    • H10K2102/102—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO] comprising tin oxides, e.g. fluorine-doped SnO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/50—Photovoltaic [PV] devices
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Photovoltaic Devices (AREA)
  • Hybrid Cells (AREA)

Abstract

La presente invención se refiere a un método para producir una célula solar que comprende las etapas de: proporcionar un colector de corriente y una capa nanoporosa; aplicar y/o depositar una película que comprende una o más sales de metal divalente o trivalente sobre dicha capa nanoporosa; exponer y/o poner en contacto la película obtenida en la etapa anterior con una disolución que comprende una o más sales de amonio orgánico en un disolvente, obteniendo de ese modo una capa que comprende una perovskita orgánica-inorgánica; y proporcionar un contraelectrodo. La invención también se refiere a la perovskita orgánica-inorgánica que se obtiene en el método y a la célula solar resultante.
ES201590118A 2013-05-06 2014-05-05 Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento Withdrawn - After Issue ES2579907B1 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13166720 2013-05-06
EP13166720 2013-05-06
EP13382181 2013-05-16
EP20130382181 EP2804232A1 (en) 2013-05-16 2013-05-16 High performance perovskite-sensitized mesoscopic solar cells
PCT/EP2014/059124 WO2014180789A1 (en) 2013-05-06 2014-05-05 High performance perovskite-sensitized mesoscopic solar cells

Publications (3)

Publication Number Publication Date
ES2579907A2 ES2579907A2 (es) 2016-08-17
ES2579907R1 true ES2579907R1 (es) 2017-01-12
ES2579907B1 ES2579907B1 (es) 2017-10-24

Family

ID=50639546

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201590118A Withdrawn - After Issue ES2579907B1 (es) 2013-05-06 2014-05-05 Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento

Country Status (6)

Country Link
US (1) US20160086739A1 (es)
CN (1) CN105474421A (es)
BR (1) BR112015028097A2 (es)
ES (1) ES2579907B1 (es)
MX (1) MX2015015395A (es)
WO (1) WO2014180789A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3396729B1 (en) 2014-05-28 2019-10-09 Alliance for Sustainable Energy, LLC Methods for producing and using perovskite materials and devices therefrom
US9324562B1 (en) 2014-11-12 2016-04-26 Alliance For Sustainable Energy, Llc Metal halide solid-state surface treatment for nanocrystal materials
EP3248229B1 (en) * 2015-01-21 2021-10-27 Commonwealth Scientific and Industrial Research Organisation Process of forming a photoactive layer of a perovskite photoactive device
JP6745214B2 (ja) * 2015-01-29 2020-08-26 積水化学工業株式会社 太陽電池及び太陽電池の製造方法
US9701696B2 (en) 2015-02-27 2017-07-11 Alliance For Sustainable Energy, Llc Methods for producing single crystal mixed halide perovskites
JP6657572B2 (ja) * 2015-03-06 2020-03-04 株式会社リコー 光電変換素子
JP6486737B2 (ja) * 2015-03-19 2019-03-20 株式会社東芝 光電変換素子
JP6572015B2 (ja) * 2015-06-25 2019-09-04 株式会社日本マイクロニクス 二次電池の製造方法
GB201513366D0 (en) * 2015-07-29 2015-09-09 Univ Ulster Photovoltaic device
EP3157025A1 (en) 2015-10-15 2017-04-19 g2e glass2energy SA Porphyrin-based sensitizer for dye-sensitized solar cell
KR101994429B1 (ko) * 2015-10-27 2019-06-28 주식회사 엘지화학 태양전지의 광흡수체 제조 방법
CN105789398B (zh) * 2016-04-11 2017-07-21 郑州大学 以ZnO纳米墙网络作为电子注入层的钙钛矿LED及制备方法
WO2018007586A1 (en) * 2016-07-07 2018-01-11 Technische Universiteit Eindhoven Perovskite contacting passivating barrier layer for solar cells
EP3279960A1 (en) 2016-08-02 2018-02-07 Aalto University Foundation Method for inkjet printing an organic-inorganic perovskite
CN106486602B (zh) * 2016-10-27 2019-01-11 北京科技大学 一种引入廉价添加剂制备高质量钙钛矿薄膜的方法
CN107359252A (zh) * 2017-06-07 2017-11-17 常州市瑞泰物资有限公司 一种晶体均一型钙钛矿薄膜的制备方法
CN109244250B (zh) * 2017-07-11 2023-09-22 松下控股株式会社 太阳能电池模块
CN109904319B (zh) * 2019-01-29 2022-11-18 安徽大学 大尺寸钙钛矿扁平晶体、钙钛矿层制备方法及太阳能电池
JP6675505B2 (ja) * 2019-02-15 2020-04-01 株式会社東芝 光電変換素子の製造方法
JP7429881B2 (ja) * 2019-04-16 2024-02-09 パナソニックＩｐマネジメント株式会社 太陽電池
CN114072930A (zh) * 2019-08-27 2022-02-18 松下知识产权经营株式会社 太阳能电池
CN112599673B (zh) * 2020-12-14 2024-03-01 苏州科技大学 利用氧化铁薄膜构筑的钙钛矿太阳能电池及其制备方法

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Also Published As

Publication number Publication date
WO2014180789A1 (en) 2014-11-13
MX2015015395A (es) 2016-08-04
BR112015028097A2 (pt) 2017-07-25
ES2579907B1 (es) 2017-10-24
CN105474421A (zh) 2016-04-06
ES2579907A2 (es) 2016-08-17
US20160086739A1 (en) 2016-03-24

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