ES258575A1 - Improvements in or relating to the decomposition of cyclohexyl peroxide - Google Patents
Improvements in or relating to the decomposition of cyclohexyl peroxideInfo
- Publication number
- ES258575A1 ES258575A1 ES0258575A ES258575A ES258575A1 ES 258575 A1 ES258575 A1 ES 258575A1 ES 0258575 A ES0258575 A ES 0258575A ES 258575 A ES258575 A ES 258575A ES 258575 A1 ES258575 A1 ES 258575A1
- Authority
- ES
- Spain
- Prior art keywords
- salts
- decomposition
- relating
- molecular oxygen
- cyclohexyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- FYLJKQFMQFOLSZ-UHFFFAOYSA-N cyclohexylperoxycyclohexane Chemical group C1CCCCC1OOC1CCCCC1 FYLJKQFMQFOLSZ-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000354 decomposition reaction Methods 0.000 title 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 2
- 229910001882 dioxygen Inorganic materials 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- 239000001361 adipic acid Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The products of the partial oxidation of cyclohexane by molecular oxygen are freed from cyclohexyl peroxides by adding a catalytic amount of dispersible copper and manganese salts and stripping the unreacted cyclohexane therefrom. The residue containing the salts may then be admixed with a monocarboxylic acid, contacted with molecular oxygen and the resulting adipic acid separated. The salts may be acetates or naphthenates and are either soluble in, or capable of being suspended or dispersed in the partially oxidised mixture.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81772659A | 1959-06-03 | 1959-06-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES258575A1 true ES258575A1 (en) | 1960-10-16 |
Family
ID=25223754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0258575A Expired ES258575A1 (en) | 1959-06-03 | 1960-06-02 | Improvements in or relating to the decomposition of cyclohexyl peroxide |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE591336A (en) |
| CH (1) | CH393312A (en) |
| DE (1) | DE1193501B (en) |
| ES (1) | ES258575A1 (en) |
| GB (1) | GB945166A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3222144A1 (en) * | 1982-06-11 | 1983-12-15 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING CYCLOHEXANOL AND CYCLOHEXANONE |
| DE3601218A1 (en) * | 1986-01-17 | 1987-07-23 | Basf Ag | METHOD FOR THE PROCESSING OF REACTION MIXTURES CONTAINING CYCLOHEXYL HYDROPEROXIDE, CYCLOHEXANOL AND CYCLOHEXANONE |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE859465C (en) * | 1941-04-13 | 1952-12-15 | Basf Ag | Process for the production of cycloaliphatic ketones and alcohols in addition to dicarboxylic acids |
| DE1002754B (en) * | 1954-05-12 | 1957-02-21 | Du Pont | Process for the production of mixtures of cyclohexanone and cyclohexanol suitable for the production of adipic acid |
-
1960
- 1960-05-30 BE BE591336A patent/BE591336A/en unknown
- 1960-06-02 CH CH628360A patent/CH393312A/en unknown
- 1960-06-02 ES ES0258575A patent/ES258575A1/en not_active Expired
- 1960-06-02 GB GB1960360A patent/GB945166A/en not_active Expired
- 1960-06-03 DE DES68818A patent/DE1193501B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| GB945166A (en) | 1963-12-23 |
| CH393312A (en) | 1965-06-15 |
| BE591336A (en) | 1960-09-16 |
| DE1193501B (en) | 1965-05-26 |
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