ES2651675T3 - Producción de grafeno a partir de alcóxido de metal - Google Patents

Producción de grafeno a partir de alcóxido de metal Download PDF

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Publication number
ES2651675T3
ES2651675T3 ES10729930.7T ES10729930T ES2651675T3 ES 2651675 T3 ES2651675 T3 ES 2651675T3 ES 10729930 T ES10729930 T ES 10729930T ES 2651675 T3 ES2651675 T3 ES 2651675T3
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ES
Spain
Prior art keywords
metal alkoxide
solution
graphene production
introducing
droplets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10729930.7T
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English (en)
Inventor
Karl Stuart Coleman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Matter GBR Ltd
Original Assignee
Applied Graphene Materials UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Applied Graphene Materials UK Ltd filed Critical Applied Graphene Materials UK Ltd
Application granted granted Critical
Publication of ES2651675T3 publication Critical patent/ES2651675T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/186—Preparation by chemical vapour deposition [CVD]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/26—Deposition of carbon only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/008—Pyrolysis reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/194—After-treatment
    • C01B32/196—Purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/04—Specific amount of layers or specific thickness
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/20—Graphene characterized by its properties
    • C01B2204/22—Electronic properties

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Un proceso para producir grafeno, caracterizado por la etapa de: introducir una solución (102) de un alcóxido de metal en un disolvente en un aparato de descomposición, en el que la etapa de introducir la solución incluye crear gotitas que comprenden una aspersión o bruma o aerosol (108) de la solución de alcóxido de metal, en el que el aparato de descomposición incluye una primera región (106) que tiene una temperatura suficientemente alta para causar la descomposición térmica del alcóxido de metal, para producir grafeno y en el que se crean las gotitas y se introducen en una corriente de gas (110).

Description

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Claims (1)

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ES10729930.7T 2009-07-27 2010-07-02 Producción de grafeno a partir de alcóxido de metal Active ES2651675T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0913011.3A GB0913011D0 (en) 2009-07-27 2009-07-27 Graphene
GB0913011 2009-07-27
PCT/GB2010/051099 WO2011012874A1 (en) 2009-07-27 2010-07-02 Production of graphene from metal alkoxide

Publications (1)

Publication Number Publication Date
ES2651675T3 true ES2651675T3 (es) 2018-01-29

Family

ID=41066864

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10729930.7T Active ES2651675T3 (es) 2009-07-27 2010-07-02 Producción de grafeno a partir de alcóxido de metal

Country Status (8)

Country Link
US (1) US9932227B2 (es)
EP (1) EP2459484B1 (es)
JP (2) JP5767218B2 (es)
KR (3) KR20120039665A (es)
CN (1) CN102498061A (es)
ES (1) ES2651675T3 (es)
GB (1) GB0913011D0 (es)
WO (1) WO2011012874A1 (es)

Families Citing this family (35)

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WO2011017338A2 (en) * 2009-08-03 2011-02-10 University Of Idaho Method for making graphene
US20140150970A1 (en) 2010-11-19 2014-06-05 Ppg Industries Ohio, Inc. Structural adhesive compositions
US8796361B2 (en) 2010-11-19 2014-08-05 Ppg Industries Ohio, Inc. Adhesive compositions containing graphenic carbon particles
US20110086756A1 (en) * 2010-12-20 2011-04-14 Gao hong-jun Method for preparing silicon intercalated monolayer graphene
AP2013007168A0 (en) * 2011-03-15 2013-10-31 Peerless Worldwide Llc Facile synthesis of graphene, graphene derivativesand abrasive nanoparticles and their various uses , including as tribolofically-beneficial lubricantadditives
KR101349912B1 (ko) 2011-04-27 2014-01-13 한국지질자원연구원 Ｐｔ/ＧＲ(Ｇｒａｐｈｅｎｅ) 나노복합체 및 그 제조방법
US10135059B2 (en) 2011-06-30 2018-11-20 Northwestern University Crumpled particles, methods of synthesizing same and applications using same
US20130266501A1 (en) * 2011-07-05 2013-10-10 Rutgers, The State University Of New Jersey Direct Production of Large and Highly Conductive Low-Oxygen Graphene Sheets and Monodispersed Low-Oxygen Graphene Nanosheets
US9988551B2 (en) 2011-09-30 2018-06-05 Ppg Industries Ohio, Inc. Black pigments comprising graphenic carbon particles
US12421118B2 (en) 2011-09-30 2025-09-23 Ppg Industries Ohio, Inc. Graphenic carbon particles
US9938416B2 (en) 2011-09-30 2018-04-10 Ppg Industries Ohio, Inc. Absorptive pigments comprising graphenic carbon particles
US10294375B2 (en) 2011-09-30 2019-05-21 Ppg Industries Ohio, Inc. Electrically conductive coatings containing graphenic carbon particles
US9832818B2 (en) 2011-09-30 2017-11-28 Ppg Industries Ohio, Inc. Resistive heating coatings containing graphenic carbon particles
US9574094B2 (en) 2013-12-09 2017-02-21 Ppg Industries Ohio, Inc. Graphenic carbon particle dispersions and methods of making same
US10763490B2 (en) 2011-09-30 2020-09-01 Ppg Industries Ohio, Inc. Methods of coating an electrically conductive substrate and related electrodepositable compositions including graphenic carbon particles
US9475946B2 (en) 2011-09-30 2016-10-25 Ppg Industries Ohio, Inc. Graphenic carbon particle co-dispersions and methods of making same
US8486363B2 (en) 2011-09-30 2013-07-16 Ppg Industries Ohio, Inc. Production of graphenic carbon particles utilizing hydrocarbon precursor materials
US10240052B2 (en) 2011-09-30 2019-03-26 Ppg Industries Ohio, Inc. Supercapacitor electrodes including graphenic carbon particles
US9761903B2 (en) 2011-09-30 2017-09-12 Ppg Industries Ohio, Inc. Lithium ion battery electrodes including graphenic carbon particles
DE102011054103A1 (de) * 2011-09-30 2013-04-04 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Verfahren zum Herstellen von Graphen-Nanobändern
CN102515148B (zh) * 2011-11-25 2013-12-25 东南大学 一种石墨烯铸体的铸造方法
CN103159208A (zh) * 2011-12-14 2013-06-19 海洋王照明科技股份有限公司 一种制备石墨烯的方法
CN102627274B (zh) * 2012-04-23 2013-11-06 中国科学院上海微系统与信息技术研究所 一种制备石墨烯的方法
US11430979B2 (en) 2013-03-15 2022-08-30 Ppg Industries Ohio, Inc. Lithium ion battery anodes including graphenic carbon particles
CN103332688B (zh) * 2013-07-16 2015-08-19 中国科学院山西煤炭化学研究所 一种由有机酸金属盐合成石墨烯的方法
CN103601177B (zh) * 2013-11-19 2015-04-29 中国科学院山西煤炭化学研究所 一种碱金属盐催化固体有机酸制备石墨烯的方法
KR101694751B1 (ko) * 2014-08-21 2017-01-10 (주)솔라세라믹 박막 형성을 위한 전구체 공급 장치 및 이를 포함하는 박막 형성 장치
GB201416317D0 (en) * 2014-09-16 2014-10-29 Swan Thomas & Co Ltd Two-dimensional materials
CN105036121A (zh) * 2015-07-07 2015-11-11 哈尔滨工业大学 一种增强型石墨烯表面活性剂的制备方法
KR101813584B1 (ko) 2015-09-02 2017-12-29 한국과학기술연구원 탄소나노구조체 및 이의 제조 방법
US10377928B2 (en) 2015-12-10 2019-08-13 Ppg Industries Ohio, Inc. Structural adhesive compositions
US10351661B2 (en) 2015-12-10 2019-07-16 Ppg Industries Ohio, Inc. Method for producing an aminimide
ITUB20161052A1 (it) * 2016-02-25 2017-08-25 Hygraner S R L Metodo per la sintesi di grafene o di un suo derivato funzionalizzato, grafene o suo derivato funzionalizzato ottenuto da detto metodo e loro usi
CN114026714B (zh) 2019-05-20 2024-11-19 纳诺格拉夫公司 包含低缺陷乱层碳的阳极活性材料
CN110668432B (zh) * 2019-09-27 2021-05-14 北京碳垣新材料科技有限公司 以金属粉末液相为基底生长石墨烯的装置

Family Cites Families (7)

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JPS60218344A (ja) * 1984-04-14 1985-11-01 Res Dev Corp Of Japan アルミニウムアルコキシドの合成方法及びその装置
AU2003292716A1 (en) * 2002-12-27 2004-07-29 Bussan Nanotech Research Institute Inc. Process and apparatus for producing single-walled carbon nanotube
JP4834957B2 (ja) * 2004-02-27 2011-12-14 住友電気工業株式会社 触媒構造体およびこれを用いたカーボンナノチューブの製造方法
US8043596B2 (en) * 2004-09-22 2011-10-25 Showa Denko K.K. Method for producing vapor grown carbon nanotube
US20070298168A1 (en) * 2006-06-09 2007-12-27 Rensselaer Polytechnic Institute Multifunctional carbon nanotube based brushes
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US20090134369A1 (en) * 2007-11-26 2009-05-28 Applied Nanoworks, Inc. Metal alkoxides, apparatus for manufacturing metal alkoxides, related methods and uses thereof

Also Published As

Publication number Publication date
KR101965882B1 (ko) 2019-04-04
US20120114551A1 (en) 2012-05-10
EP2459484B1 (en) 2017-09-13
CN102498061A (zh) 2012-06-13
JP5767218B2 (ja) 2015-08-19
KR20180001601A (ko) 2018-01-04
KR20150082683A (ko) 2015-07-15
US9932227B2 (en) 2018-04-03
KR20120039665A (ko) 2012-04-25
EP2459484A1 (en) 2012-06-06
GB0913011D0 (en) 2009-09-02
WO2011012874A1 (en) 2011-02-03
JP2013500233A (ja) 2013-01-07
KR101987390B1 (ko) 2019-06-10
JP5932090B2 (ja) 2016-06-08
JP2015143187A (ja) 2015-08-06

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