ES2712504T3 - Composición herbicida con efecto sinérgico que contiene fluroxipir y profoxidim - Google Patents
Composición herbicida con efecto sinérgico que contiene fluroxipir y profoxidim Download PDFInfo
- Publication number
- ES2712504T3 ES2712504T3 ES16185362T ES16185362T ES2712504T3 ES 2712504 T3 ES2712504 T3 ES 2712504T3 ES 16185362 T ES16185362 T ES 16185362T ES 16185362 T ES16185362 T ES 16185362T ES 2712504 T3 ES2712504 T3 ES 2712504T3
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- Spain
- Prior art keywords
- mixture
- synergistic effect
- herbicidal
- fluroxypyr
- oil
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Classifications
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/04—Halogen directly attached to a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/18—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Una mezcla herbicida con efecto sinérgico que comprende una cantidad eficaz como herbicida de (a) fluroxipir y (b) un herbicida inhibidor de la ACCasa, en donde el herbicida inhibidor de la ACCasa es profoxidim.
Description
DESCRIPCION
Composicion herbicida con efecto sinergico que contiene fluroxipir y profoxidim
La proteccion de los cultivos contra las malas hierbas y otra vegetacion que inhiben el crecimiento de los cultivos y afectan negativamente a la calidad y al rendimiento del cultivo es un problema que constantemente se repite en la agricultura. Para ayudar a combatir este problema, los investigadores en el campo de la smtesis qmmica han producido una amplia variedad de productos qmmicos y formulaciones qmmicas eficaces en el control de tal crecimiento no deseado. En la bibliograffa se han descrito herbicidas qmmicos de muchos tipos y un gran numero son de uso comercial.
En algunos casos, se ha demostrado que los ingredientes activos herbicidas eran mas eficaces en combinacion que cuando se aplicaban de forma individual y esto se conoce como "sinergismo". Como se describe en Herbicide Handbook of the Weed Science Society of America, Octava edicion, 2002, p. 462 “'sinergismo' [es] una interaccion de dos o mas factores de tal manera que el efecto combinado es mayor que el efecto previsto basado en la respuesta a cada factor aplicado por separado”. La presente invencion se basa en el descubrimiento de que fluroxipir y profoxidim exhiben un efecto sinergico cuando se aplican combinados. Ambos herbicidas ya se conodan individualmente por su eficacia herbicida. Ademas, las mezclas de herbicidas sinergicas que comprenden un herbicida de ciclohexanodiona, tal como profoxidim, y otro herbicida diferente de fluroxipir, se habfan descrito en el documento WO 97/10710 A1.
La presente invencion se refiere a una mezcla herbicida con efecto sinergico que comprende una cantidad eficaz como herbicida de (a) fluroxipir y (b) el herbicida inhibidor de acetil CoA carboxilasa (ACCasa) profoxidim. Las composiciones pueden contener tambien un adyuvante y/o un portador agncolamente aceptable.
La presente invencion tambien se refiere a composiciones herbicidas y a metodos para controlar el crecimiento de vegetacion indeseable, particularmente en arroz, pero tambien en otros cultivos de monocotiledoneas tales como mafz, trigo, cebada, avena, centeno, sorgo, cesped, pastos, praderas, pastizales, tierra en barbecho e IVM, y al uso de estas composiciones con efecto sinergico.
Los espectros de especies del inhibidor de ACCasa profoxidim, es decir, las especies de malas hierbas que el compuesto controla, es amplio y sumamente complementario con los de fluroxipir. Se ha encontrado, sorprendentemente, que una mezcla de profoxidim y fluroxipir exhibe una accion sinergica en el control de hierba de corral (Echinochloa crus-galli; ECHCG) y zacate chino (Leptochloa chinensis (L.); LEFCH) a tasas de aplicacion iguales o inferiores a las tasas de los compuestos individuales.
Profoxidim es el nombre comun para 2-[1-[[2-(4-clorofenoxi)-propoxi]-imino]-butil]-3-hidroxi-5-(tetrahidro-2H-tiopiran-3-il)-2-ciclohexen-1-ona. Su actividad herbicida se describe en The Pesticide Manual, Decimocuarta Edicion, 2006. Profoxidim proporciona un control posterior a la emergencia de malas hierbas en arroz.
Fluroxipir es el nombre comun para el acido [(4-amino-3,5-dicloro-6-fluoro-2-piridinil)oxi]acetico. Su actividad herbicida se describe en The Pesticide Manual, Decimocuarta Edicion, 2006. Fluroxipir controla una amplia gama de malas hierbas de hoja ancha de importancia economica. Se puede utilizar como el propio acido o como una sal o ester agncolamente aceptable. Se prefiere el uso como ester, siendo el ester meptflico el mas preferido.
El termino herbicida se usa en el presente documento refiriendose a un ingrediente activo que mata, controla o de otro modo afecta negativamente el crecimiento de las plantas. Una cantidad eficaz como herbicida o que controla la vegetacion es una cantidad de ingrediente activo que provoca un efecto que afecta negativamente e incluye desviaciones del desarrollo natural, muerte, regulacion, desecado, retraso y similares. Los terminos plantas y vegetacion incluyen semillas germinantes, plantulas emergentes, plantas que emergen de propagulos vegetativos, y vegetacion habitual.
La actividad herbicida es exhibida por los compuestos de la mezcla con efecto sinergico cuando se aplican directamente a la planta o al locus de la planta en cualquier etapa de crecimiento o antes de la plantacion o de la emergencia. El efecto observado depende de las especies de plantas a controlar, de la etapa de crecimiento de la planta, de los parametros de aplicacion de la dilucion y del tamano de la gota de pulverizacion, del tamano de partfcula de los componentes solidos, de las condiciones ambientales en el momento de su uso, del compuesto espedfico empleado, de los adyuvantes y portadores espedficos empleados, del tipo de suelo, y similares, asf como de la cantidad aplicada del producto qmmico. Estos y otros factores se pueden ajustar como se conoce en la tecnica para promover la accion herbicida no selectiva o selectiva. Generalmente, se prefiere aplicar la composicion de la presente invencion despues de la emergencia de la vegetacion indeseable relativamente inmadura para lograr el maximo control de las malas hierbas.
En la composicion de esta invencion, la relacion en peso de fluroxipir (equivalente acido) frente a profoxidim (ingrediente activo) a la que el efecto herbicida es sinergico cae dentro del intervalo entre 1:10 y 75:1.
La tasa a la que la composicion con efecto sinergico se aplica dependera del tipo particular de mala hierba a controlar, del grado de control requerido y del momento y del procedimiento de aplicacion. En general, la
composicion de la invencion se puede aplicar a una tasa de aplicacion de profoxidim entre 7,5 g ai/ha y 350 g ai/ha y una tasa de aplicacion de fluroxipir entre 35 g ea/ha y 560 g ea/ha.
Los componentes de la mezcla con efecto sinergico de la presente invencion se pueden aplicar ya sea por separado o como parte de un sistema herbicida de varias partes.
La mezcla con efecto sinergico de la presente invencion se puede aplicar en union con uno o mas de otros herbicidas para controlar una amplia variedad de vegetacion indeseable. Cuando se utiliza en union con otros herbicidas, la formulacion se puede formular con el otro herbicida o los otros herbicidas, mezclar en tanque con el otro herbicida o los otros herbicidas o aplicar secuencialmente con el otro herbicida o los otros herbicidas. Algunos de los herbicidas que se pueden emplear en union con la composicion con efecto sinergico de la presente invencion incluyen: 2,4-D, acetoclor, acifluorfen, aclonifen, AE0172747, alaclor, amidosulfuron, aminotriazol, tiocianato de amonio, anilifos, atrazina, AVH 301, azimsulfuron, benfuresato, bensulfuron-metil, bentazona, bentiocarb, benzobiciclona, bifenox, bispiribac-sodio, bromacil, bromoxinil, butaclor, butafenacil, butralina, cafenstrol, carbetamida, carfentrazona-etil, clorflurenol, clorimuron, clorprofam, cinosulfuron, cletodim, clomazona, clopiralid, cloransulam-metil, ciclosulfamuron, cicloxidim, dicamba, diclobenil, diclorprop-P, diclosulam, diflufenican, diflufenzopir, dimetenamida, dimetenamida-p, diquat, ditiopir, diuron, EK2612, EPTC, esprocarb, ET-751, etoxisulfuron, etbenzanid, F7967, fenoxaprop, fenoxaprop-etil, fenoxaprop-etil+isoxadifen-etil, fentrazamida, flazasulfuron, florasulam, fluazifop, fluazifop-P-butil, flucetosulfuron (LGC-42153), flufenacet, flufenpir-etil, flumetsulam, flumiclorac-pentil, flumioxazin, fluometuron, flupirsulfuron, fomesafen, foramsulfuron, flumiclorac, glufosinato, glufosinato-amonio, glifosato, halosulfuron, haloxifop-metil, haloxifop-R, imazametabenz, imazamox, imazapic, imazapir, imazaquin, imazetapir, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxinil, ipfencarbazona (HOK-201), IR 5790, isoproturon, isoxaben, isoxaflutol, KUH-021, lactofen, linuron, MCPA, MCPA ester y amina, mecoprop-P, mefenacet, mesosulfuron, mesotriona, metazosulfuron (NC-620), metolaclor, metosulam, metribuzina, metsulfuron, molinato, MSMA, napropamida, nicosulfuron, norflurazon, OK-9701, ortosulfamuron, orizalina, oxadiargilo, oxadiazon, oxaziclomefona, oxifluorfen, paraquat, pendimetalina, penoxsulam, pentoxazona, petoxamida, picloram, picolinafen, piperofos, pretilaclor, primisulfuron, propaclor, propanil, propirisulfuron (TH-547), propizamida, prosulfocarb, prosulfuron, piraclonil, pirazogil, pirazosulfuron, piribenzoxim (LGC-40863), piriftalid, piriminobac-metil, pirimisulfan (KUH-021), piroxsulam, piroxasulfona (KIH-485), quinclorac, quizalofop-etil-D, quizalofop-P-etil, S-3252, setoxidim, simazina, SL-0401, SL-0402, S-metolaclor, sulcotriona, sulfentrazona, sulfosato, tebutiuron, tefuriltriona (AVH-301), terbacil, tiazopir, tiobencarb, triclopir, trifluralin y tritosulfuron.
La composicion con efecto sinergico de la presente invencion se puede utilizar, ademas, en union con glifosato, glufosinato, dicamba, imidazolinonas, sulfonilureas o 2,4-D en cultivos tolerantes a glifosato, tolerantes a glufosinato, tolerantes a dicamba, tolerantes a imidazolinonas, tolerantes a sulfonilureas o tolerantes a 2,4-D. Generalmente se prefiere utilizar la composicion con efecto sinergico de la presente invencion con herbicidas que son selectivos para el cultivo que este siendo tratado y que complemente el espectro de malas hierbas controladas por estos compuestos a la tasa de aplicacion empleada. Generalmente se prefiere aplicar la composicion con efecto sinergico de la presente invencion y otros herbicidas complementarios al mismo tiempo, ya sea como una formulacion de combinacion o como una mezcla de tanque.
La composicion con efecto sinergico de la presente invencion se puede emplear generalmente en combinacion con protectores herbicidas conocidos, tales como benoxacor, bentiocarb, brasinolida, cloquintocet (mexil), ciometrinil, daimuron, diclormid, diciclonon, dimepiperato, disulfoton, fenclorazol-etil, fenclorim, flurazol, fluxofenim, furilazol, protemas de horquilla, isoxadifen-etil, mefenpir-dietil, MG 191, MON 4660, anlddrido naftalico (NA), oxabetrinil, R29148 y amidas del acido W-fenil-sulfonilbenzoico, para realzar su selectividad. Cloquintocet (mexil) es un protector particularmente preferido para las composiciones con efecto sinergico de la presente invencion, espedficamente antagonistas de cualquier efecto nocivo de las composiciones con efecto sinergico sobre arroz y cereales.
En la practica, es preferible utilizar la composicion con efecto sinergico de la presente invencion en mezclas que contengan una cantidad herbicidamente eficaz de los componentes herbicidas junto con al menos un adyuvante o portador agncolamente aceptable. Adyuvantes o portadores adecuados no deben ser fitotoxicos para los cultivos valiosos, particularmente en las concentraciones empleadas en la aplicacion de las composiciones para el control selectivo de malas hierbas en presencia de cultivos, y no debenan reaccionar qmmicamente con los componentes herbicidas u otros ingredientes de la composicion. Tales mezclas se pueden disenar para su aplicacion directamente sobre las malas hierbas o su locus o pueden ser concentrados o formulaciones que normalmente se diluyen con portadores y adyuvantes adicionales antes de la aplicacion. Pueden ser solidos, tales como, por ejemplo, polvos espolvoreables, granulos, granulos dispersables en agua, o polvos humectables, o lfquidos, tales como, por ejemplo, concentrados emulsionables, disoluciones, emulsiones o suspensiones.
Adyuvantes agncolas y portadores adecuados que son utiles en la preparacion de las mezclas herbicidas de la invencion son bien conocidos por los expertos en la tecnica. Algunos de estos adyuvantes incluyen, pero no se limitan a, concentrado de aceite de cultivo (aceite mineral (85%) emulsionantes (15%)); etoxilato de nonilfenol; sal de bencilcocoalquildimetil-amonio cuaternario; mezcla de hidrocarburos de petroleo, esteres de alquilo, acido organico, y tensioactivo anionico; alquilo Cg-Cn-poliglicosido; etoxilato de alcohol fosfatado; etoxilato de alcohol primario (C12-C16) natural; copolfmero de bloques EO-PO di-sec-butilfenol; tapa de polisiloxano-metilo; etoxilato de nonilfenol urea y nitrato de amonio; aceite de semilla metilado emulsionado; etoxilato de alcohol tridedlico
(sintetico) (8 EO); etoxilato de amina de sebo (15 EO) y PEG (400) dioleato-99.
Portadores lfquidos que pueden emplearse incluyen agua, tolueno, xileno, nafta de petroleo, aceite de cultivo, acetona, metil-etil-cetona, ciclohexanona, tricloroetileno, percloroetileno, acetato de etilo, acetato de amilo, acetato de butilo, eter monometilico de propilenglicol y eter monometflico de dietilenglicol, alcohol metilico, alcohol etilico, alcohol isoprc^lico, alcohol airnlico, etilenglicol, propilenglicol, glicerol, N-metil-2-pirrolidinona, N,N-dimetilalquilamidas, dimetilsulfoxido, fertilizantes Kquidos, latex y similares. El agua es, generalmente, el portador elegido para la dilucion de los concentrados.
Portadores solidos adecuados incluyen KCl, talco, arcilla de pirofilita, sflice, arcilla de atapulgita, arcilla de caolm, kieselguhr, tiza, tierra de diatomeas, cal, carbonato calcico, arcilla de bentonita, tierra de Fuller, cascaras de semillas de algodon, harina de trigo, harina de soja, piedra pomez, harina de madera, harina de cascara de nuez, lignina, diversas formas de celulosa, grano de mazorca de mafz y similares.
Por lo general, es deseable incorporar uno o mas agentes tensioactivos en las composiciones de la presente invencion. Tales agentes tensioactivos se emplean ventajosamente tanto en composiciones solidas como lfquidas, especialmente las disenadas para ser diluidas con un portador antes de la aplicacion. Los agentes tensioactivos pueden ser de caracter anionico, cationico o no ionico y se pueden emplear como agentes emulsionantes, agentes humectantes, agentes de suspension, o para otros fines. Tensioactivos tradicionalmente usados en la tecnica de la formulacion y que tambien se pueden usar en las presentes formulaciones se describen, entre otros, en "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, Nueva Jersey, 1998 y en "Encyclopedia of Surfactants”, Vol. I-III, Chemical Publishing Co., Nueva York, 1980-81. Agentes tensioactivos tfpicos incluyen sales de alquilsulfatos, tales como laurilsulfato de dietanolamonio; sales de alquilarilsulfonato, tales como dodecilbencenosulfonato de calcio; productos de adicion alquilfenol-oxido de alquileno, tales como etoxilato C18 de nonilfenol; productos de adicion alcohol-oxido de alquileno, tales como etoxilato C16 de alcohol tridedlico; jabones, tales como estearato de sodio; sales de alquilnaftalen-sulfonato, tales como dibutilnaftalensulfonato de sodio; esteres dialqrnlicos de sales sulfosuccinato, tales como di(2-etilhexil)-sulfosuccinato sodico; esteres de sorbitol, tales como oleato de sorbitol; aminas cuaternarias, tales como cloruro de lauril-trimetilamonio; esteres de polietilenglicol de acidos grasos, tales como estearato de polietilenglicol; copolfmeros de bloques de oxido de etileno y oxido de propileno; y sales de esteres de mono- y di-alquilfosfato; aceites vegetales tales como aceite de soja, aceite de colza, aceite de oliva, aceite de ricino, aceite de semilla de girasol, aceite de coco, aceite de mafz, aceite de semilla de algodon, aceite de canola, aceite de linaza, aceite de palma, aceite de cacahuete, aceite de cartamo, aceite de sesamo, aceite de tung y similares; y esteres de los aceites vegetales anteriores.
Otros aditivos normalmente usados en composiciones agncolas incluyen agentes de compatibilidad, agentes antiespumantes, agentes secuestrantes, agentes neutralizantes y tampones, inhibidores de la corrosion, colorantes, odorizantes, agentes esparcidores, adyuvantes de penetracion, agentes adherentes, agentes dispersantes, agentes espesantes, depresores de la temperatura de congelacion, agentes antimicrobianos, y similares. Las composiciones tambien pueden contener otros componentes compatibles, por ejemplo, otros herbicidas, reguladores del crecimiento de las plantas, fungicidas, insecticidas, y similares, y pueden formularse con fertilizantes lfquidos o portadores fertilizantes solidos en partfculas, tales como nitrato de amonio, urea y similares.
La concentracion de los ingredientes activos en la composicion con efecto sinergico de la presente invencion es generalmente de 0,001 a 98 por ciento en peso. A menudo se emplean concentraciones de 0,01 a 90 por ciento en peso. En composiciones disenadas para ser empleadas como concentrados, los ingredientes activos estan presentes generalmente en una concentracion desde 1 a 98 por ciento en peso, preferiblemente 10 a 90 por ciento en peso. Tales composiciones se diluyen tfpicamente con un portador inerte, tal como agua, antes de la aplicacion, o aplicado como una formulacion seca o lfquida directamente en los campos de arroz inundados. Las composiciones diluidas, normalmente aplicadas a las malas hierbas o al locus de las malas hierbas, contienen generalmente 0,0001 a 10 por ciento en peso de ingrediente activo y contienen, preferiblemente, 0,001 a 5,0 por ciento en peso.
Las presentes composiciones pueden aplicarse a las malas hierbas o a su locus mediante el uso convencional de la mano, espolvoreadores terrestres o aereos, pulverizadores, y aplicadores de granulos, mediante la adicion al agua de riego o arrozal, y por otros medios convencionales conocidos por los expertos en la tecnica.
Los siguientes ejemplos ilustran la presente invencion.
Ejemplos
Evaluacion de la Actividad Herbicida de Mezclas en Invernadero Despues de la Emergencia
Semillas de las especies de plantas de ensayo deseadas se plantaron en mezcla de siembra de 80% de suelo mineral/20% de grano, que tiene tfpicamente un pH de 7,2 y un contenido de materia organica de 2,9 por ciento, en macetas de plastico con una superficie de 128 centfmetros cuadrados (cm2). El medio de cultivo se esterilizo con vapor. Las plantas se cultivaron durante 7-19 dfas en invernadero con un fotopenodo aproximado de 14 horas (h) que se mantuvo a 29 °C durante el dfa y a 26 °C durante la noche. Los nutrientes y el agua fueron anadidos en una base regular y se proporciono iluminacion complementaria con luminarias de 1.000 vatios de haluros metalicos suspendidas segun fuera necesario. Las plantas fueron tratadas con aplicaciones foliares despues de brotar cuando
llegaron a la tercera a cuarta etapa de hoja verdadera. Todos los tratamientos se aplicaron utilizando un diseno de prueba de bloques completes al azar, con 4 repeticiones portratamiento.
Evaluacion de la Actividad Herbicida de Mezclas en Invernadero Despues de la Emergencia
Los tratamientos consistieron en los compuestos enumerados en la Tabla con cada compuesto aplicado solo y combinado. Las cantidades formuladas de profoxidim y ester meptilico de fluroxipir, se colocaron en viales de vidrio de 60 mililitros (ml) y se disolvieron en un volumen de 60 ml de una disolucion acuosa que contema concentrado de aceite de cultivo Agri-dex en una proporcion de 1% de volumen por volumen (v/v). Los requisitos del compuesto se basan en un volumen de aplicacion de 12 ml a una tasa de 187 litros por hectarea (l/ha). Las disoluciones de pulverizacion de las mezclas se prepararon mediante la adicion de disoluciones madre a la cantidad apropiada de disolucion de dilucion para formar 12 ml de disolucion de pulverizacion con ingredientes activos en combinaciones individuales y de dos direcciones. Los compuestos formulados se aplicaron al material vegetal con un pulverizador de carril Mandel suspendido equipado con boquillas 8002E calibradas para distribuir 187 l/ha a una altura de pulverizacion de 18 pulgadas (43 centimetros (cm)) por encima de la media de las copas de la planta.
Las plantas tratadas y las plantas de control se colocaron en un invernadero como se ha descrito anteriormente y se regaron mediante sub-irrigacion para impedir la eliminacion por lavado de los compuestos de ensayo. Los tratamientos se han valorado a los 21 dfas despues de la aplicacion en comparacion con plantas de control no tratadas. El porcentaje del control visual de las malas hierbas se puntuo en una escala de 0 a 100 por ciento, donde 0 correspondfa a ningun dano y 100 correspondfa a destruccion completa.
La ecuacion de Colby se utilizo para determinar los efectos herbicidas que se esperan de las mezclas (Colby, S.R. Calculation of the sinergistic and antagonistic response of herbicide combinations. Weeds 1967, 15, 20-22).
La siguiente ecuacion se utilizo para calcular la actividad esperada de las mezclas que conteman dos ingredientes activos, A y B:
Esperado = A B - (A x B/100)
A = eficacia observada de ingrediente activo A a la misma concentracion utilizada en la mezcla.
B = eficacia observada de ingrediente activo B a la misma concentracion utilizada en la mezcla.
Tabla. Actividad Sinergica de Composiciones Herbicidas de Fluroxipir-meptilo Profoxidim sobre las Malas Hierbas Clave en arroz en el Invernadero a 21 DAA.
ECHCG = Echinochloa crus-galli, hierba de corral
LEFCH = Leptochloa chinensis, zacate chino
Obs = valor observado (% control)
Ex = valor esperado, calculado usando el Analisis de Colby (% de control)
DAA = dfas despues de la aplicacion
g ae/ha = gramos de acido equivalente por hectarea
g ai/ha = gramos de ingrediente activo por hectarea
Claims (7)
1. Una mezcla herbicida con efecto sinergico que comprende una cantidad eficaz como herbicida de (a) fluroxipir y (b) un herbicida inhibidor de la ACCasa, en donde el herbicida inhibidor de la ACCasa es profoxidim.
2. La mezcla de la reivindicacion 1, en la que fluroxipir es el acido propiamente dicho o una sal o un ester agncolamente aceptable.
3. La mezcla de la reivindicacion 2, en la que fluroxipir es el ester meptflico.
4. La mezcla de la reivindicacion 1, en la que la relacion en peso de fluroxipir (equivalente acido) al herbicida inhibidor de ACCasa (ingrediente activo) esta entre 1:10 y 75:1.
5. Una composicion herbicida que comprende una cantidad herbicidamente eficaz de la mezcla herbicida de la reivindicacion 1 y un adyuvante y/o portador agncolamente aceptable.
6. Un metodo de controlar vegetacion indeseable, que comprende poner en contacto la vegetacion o el locus de la misma, o aplicar al agua para impedir el crecimiento de la vegetacion, con una cantidad herbicidamente eficaz de la mezcla herbicida de la reivindicacion 1.
7. El metodo de la reivindicacion 6, en el que la vegetacion indeseable se controla en arroz.
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| TWI601481B (zh) * | 2011-06-22 | 2017-10-11 | 陶氏農業科學公司 | 具有自附（ｂｕｉｌｔ－ｉｎ）佐劑之可乳化除草劑的濃縮液 |
| BR102012017793B1 (pt) * | 2011-06-22 | 2019-06-18 | Dow Agrosciences Llc | Composição herbicida em grânulos, e método para controlar vegetação indesejável em um ambiente aquático |
| BR102012027933A2 (pt) * | 2011-11-01 | 2015-11-17 | Dow Agrosciences Llc | composições pesticidas estáveis |
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| DK2787829T3 (en) * | 2011-12-06 | 2016-12-05 | Dow Agrosciences Llc | Herbicidal composition containing 4-amino-3-chloro-6- (4-CHLORO-2-FLUORO-3-methoxy-phenyl) pyridine-2-carboxylic acid or a derivative thereof and Fluroxypyr OR DERIVATIVES |
| AP3904A (en) * | 2012-01-25 | 2016-11-18 | Dow Agrosciences Llc | Improved solid herbicide compositions with built-in adjuvant |
| HK1212862A1 (zh) | 2012-09-28 | 2016-06-24 | 美国陶氏益农公司 | 來自施用環丙嘧啶酸和氯氟吡氧乙酸的協同雜草控制 |
| CN103444720B (zh) * | 2013-08-22 | 2015-05-20 | 河北省林业科学研究院 | 一种用于萱草茎叶处理的除草剂 |
| CN103583523A (zh) * | 2013-10-14 | 2014-02-19 | 广东中迅农科股份有限公司 | 一种水稻田除草组合物 |
| AR100785A1 (es) * | 2014-06-09 | 2016-11-02 | Dow Agrosciences Llc | Control herbicida de maleza a partir de combinaciones de fluroxipir e inhibidores de als |
| CN104285957B (zh) * | 2014-09-19 | 2016-01-13 | 河南中天恒信生物化学科技有限公司 | 一种含氰氟草酯、氯氟吡氧乙酸和双草醚的复合除草剂及其应用 |
| US20170055529A1 (en) * | 2015-08-26 | 2017-03-02 | Dow Agrosciences Llc | Broad spectrum weed control in flooded rice by in-water application of auxin herbicides |
| CN106376576A (zh) * | 2016-10-12 | 2017-02-08 | 陕西上格之路生物科学有限公司 | 一种三元除草组合物 |
| CN106376568A (zh) * | 2016-10-19 | 2017-02-08 | 陕西上格之路生物科学有限公司 | 一种三元除草组合物 |
| CN106577671A (zh) * | 2016-10-31 | 2017-04-26 | 浙江天丰生物科学有限公司 | 一种含有氰氟草酯、氯氟吡氧乙酸异辛酯和二氯喹啉酸的协同除草组合物 |
| CN106376593A (zh) * | 2016-11-08 | 2017-02-08 | 陕西上格之路生物科学有限公司 | 一种三元除草组合物 |
| CN106857553A (zh) * | 2017-01-05 | 2017-06-20 | 浙江天丰生物科学有限公司 | 含有噁唑酰草胺、氯氟吡氧乙酸异辛酯和异噁草松的除草组合物 |
| CN107156147A (zh) * | 2017-04-12 | 2017-09-15 | 浙江天丰生物科学有限公司 | 含五氟磺草胺、氯氟吡氧乙酸异辛酯、噁唑酰草胺的稻田除草组合物 |
| CN106973916A (zh) * | 2017-06-07 | 2017-07-25 | 章寿明 | 含有噁唑酰草胺的除草组合物及其应用 |
| CN107094771A (zh) * | 2017-06-08 | 2017-08-29 | 上海虎印实业有限公司 | 一种含有环苯草酮和噁唑酰草胺的除草组合物 |
| CN107683855A (zh) * | 2017-09-19 | 2018-02-13 | 浙江天丰生物科学有限公司 | 一种稻田除草组合物 |
| CN108432774A (zh) * | 2018-03-26 | 2018-08-24 | 孟州传奇生物科技有限公司 | 一种水稻田的除草剂组合物 |
| CA3147473C (en) * | 2019-07-27 | 2024-10-15 | Qingdao Kingagroot Chemical Compound Co., Ltd. | Herbicidal composition comprising r-pyridyloxycarboxylic acid and derivative and an application thereof |
| CN112335660A (zh) * | 2020-11-03 | 2021-02-09 | 安徽众邦生物工程有限公司 | 一种环苯草酮和氯氟吡氧乙酸除草组合物 |
| WO2022175808A1 (en) * | 2021-02-16 | 2022-08-25 | Parijat Industries (India) Private Limited | Synergistic herbicidal compositions of metamifop |
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| ES2058983T3 (es) * | 1990-05-09 | 1994-11-01 | Basf Ag | Ciclohexenonoximeteres, procedimiento para su obtencion y su empleo como herbicidas. |
| ES2196176T3 (es) * | 1995-09-20 | 2003-12-16 | Basf Ag | Mezclas herbicidas sinergicas que contienen eteres de ciclohexenon-oxima. |
| KR100314776B1 (ko) * | 1998-07-25 | 2001-11-17 | 우종일 | 제초성 페녹시프로피온산 ｎ-알킬-ｎ-2-플루오로페닐 아미드화합물 |
| CA2466554A1 (en) * | 2001-12-03 | 2003-06-12 | Syngenta Participations Ag | Herbicidal composition |
| DE102004041529A1 (de) * | 2004-08-27 | 2006-03-02 | Bayer Cropscience Gmbh | Herbizid-Kombinationen mit speziellen Ketoenolen |
| CN101019537A (zh) * | 2007-03-22 | 2007-08-22 | 陈德胜 | 精噁唑禾草灵和氯氟吡氧乙酸复配除草剂 |
| CN101530104B (zh) * | 2009-04-21 | 2013-07-31 | 上虞颖泰精细化工有限公司 | 一种含有磺酰脲类、吡啶类、氰氟草酯的除草剂组合物及其应用 |
| CN101595875A (zh) * | 2009-07-10 | 2009-12-09 | 赵邦斌 | 氟草烟·氰氟草酯复配除草剂 |
| CN101999357A (zh) | 2010-12-17 | 2011-04-06 | 上海生农生化制品有限公司 | 一种除草剂组合物及其用途 |
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