ES273693A1 - Procedimiento de preparaciën de un catalizador soportado para la polimerizaciën estereoespecifica en fase vaporosa de alfa-olefinas - Google Patents

Procedimiento de preparaciën de un catalizador soportado para la polimerizaciën estereoespecifica en fase vaporosa de alfa-olefinas

Info

Publication number
ES273693A1
ES273693A1 ES0273693A ES273693A ES273693A1 ES 273693 A1 ES273693 A1 ES 273693A1 ES 0273693 A ES0273693 A ES 0273693A ES 273693 A ES273693 A ES 273693A ES 273693 A1 ES273693 A1 ES 273693A1
Authority
ES
Spain
Prior art keywords
transition metal
perhalide
catalyst
group
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0273693A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Publication of ES273693A1 publication Critical patent/ES273693A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/148—Light sensitive titanium compound containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/907—Specified means of reacting components of transition metal catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Procedimiento de preparación de un catalizador soportado para la polimerización estereoespecífica en fase vaporosa de alfa-olefinas, y en particular de propileno, catalizador que comprende un haluro de un metal de transición del grupo IV, V, VI o VIII del Sistema Periódico en que la valencia del metal es inferior a la máxima, en unión con un miembro del grupo de compuestos organometálicos de un metal del grupo II o III del Sistema Periódico, estando dicho haluro del metal de transición a valencia inferior a la máxima preparado a base del correspondiente perhaluro de metal de transición por reducción con aluminio en forma dividida finamente y hallándose el mencionado producto de reducción soportado parcialmente en un soporte inorgánico que es inerte respecto al catalizador y es soluble en agua o soluble en las soluciones de lavado del polímero, la mejora que consiste en efectuar la reducción en ausencia de diluente y prácticamente en ausencia de fase líquida por el empleo del perhaluro de metal de transición en exceso de la cantidad teórica necesaria para reaccionar con la alumina, pero sin exceder la cantidad correspondiente a una absorción completa en el soporte, calentar la mezcla que contiene el perhaluro de metal de transición, polvo de aluminio y soporte en la proporción mencionada y a temperatura entre 100º y 400º C, y luego eliminar el perhaluro en exceso por lavado y/o secado en vacio.
ES0273693A 1960-12-29 1961-12-28 Procedimiento de preparaciën de un catalizador soportado para la polimerizaciën estereoespecifica en fase vaporosa de alfa-olefinas Expired ES273693A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2221860 1960-12-29

Publications (1)

Publication Number Publication Date
ES273693A1 true ES273693A1 (es) 1963-06-16

Family

ID=11193198

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0273693A Expired ES273693A1 (es) 1960-12-29 1961-12-28 Procedimiento de preparaciën de un catalizador soportado para la polimerizaciën estereoespecifica en fase vaporosa de alfa-olefinas

Country Status (8)

Country Link
US (1) US3252959A (es)
DE (1) DE1169673B (es)
ES (1) ES273693A1 (es)
FR (1) FR1308507A (es)
GB (1) GB921955A (es)
IT (1) IT643236A (es)
NL (2) NL272776A (es)
SE (1) SE310487B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3400110A (en) * 1963-08-01 1968-09-03 Solvay Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal
IT951956B (it) * 1971-12-27 1973-07-10 Sir Soc Italiana Resine Spa Procedimento per la polimerizzazio ne di olefine
IT1009869B (it) 1974-04-17 1976-12-20 Snam Progetti Procedimento per la polimerizzazio ne di alfa olefine catalizzatore impiegato in tale processo e meto do per la sua preparazione
IT1081277B (it) * 1977-06-30 1985-05-16 Snam Progetti Composizioni chimiche a base di titanio trialogenuro procedimento per la loro preparazione e loro impieghi

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2981725A (en) * 1955-11-16 1961-04-25 Shell Oil Co Process for polymerizing olefins
BE554242A (es) * 1956-01-18
US2994691A (en) * 1957-12-02 1961-08-01 Union Carbide Corp Influence of oxygen on the polymerization of olefins
US2996459A (en) * 1958-02-03 1961-08-15 Monsanto Chemicals Method for preparing a ziegler polymerization catalyst
US3001951A (en) * 1958-03-07 1961-09-26 Exxon Research Engineering Co Preparation of catalyst with removal of halide
US3010787A (en) * 1958-03-20 1961-11-28 Exxon Research Engineering Co Preparation of crystalline titanium chloride

Also Published As

Publication number Publication date
GB921955A (en) 1963-03-27
SE310487B (es) 1969-05-05
IT643236A (es)
US3252959A (en) 1966-05-24
FR1308507A (fr) 1962-11-03
DE1169673B (de) 1964-05-06
NL125687C (es)
NL272776A (es)

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