ES2862578T3 - Método para mejorar las materias primas petrolíferas utilizando una membrana conductora de metales alcalinos - Google Patents

Método para mejorar las materias primas petrolíferas utilizando una membrana conductora de metales alcalinos Download PDF

Info

Publication number: ES2862578T3
Authority: ES; Spain
Prior art keywords: alkali metal; petroleum feedstock; feedstock; chamber; petroleum
Prior art date: 2011-11-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES12849838T

Other languages

English (en)

Spanish (es)

Other versions

ES2862578T8 (es

Inventor

John Howard Gordon

Javier Alvare

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Enlighten Innovations Inc

Original Assignee

Enlighten Innovations Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-11-16

Filing date

2012-11-16

Publication date

2021-10-07

2012-11-16 Application filed by Enlighten Innovations Inc filed Critical Enlighten Innovations Inc

2021-10-07 Application granted granted Critical

2021-10-07 Publication of ES2862578T3 publication Critical patent/ES2862578T3/es

2022-01-10 Publication of ES2862578T8 publication Critical patent/ES2862578T8/es

Status Active legal-status Critical Current

2032-11-16 Anticipated expiration legal-status Critical

Links

239000003208 petroleum Substances 0.000 title claims abstract description 214
229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 177
150000001340 alkali metals Chemical class 0.000 title claims abstract description 176
238000000034 method Methods 0.000 title claims abstract description 66
239000012528 membrane Substances 0.000 title description 8
239000011734 sodium Substances 0.000 claims abstract description 38
229910052708 sodium Inorganic materials 0.000 claims abstract description 31
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 28
125000005608 naphthenic acid group Chemical group 0.000 claims abstract description 22
229910052744 lithium Inorganic materials 0.000 claims abstract description 19
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 13
229910045601 alloy Inorganic materials 0.000 claims abstract description 4
239000000956 alloy Substances 0.000 claims abstract description 4
238000006243 chemical reaction Methods 0.000 claims description 81
229910001385 heavy metal Inorganic materials 0.000 claims description 56
239000002994 raw material Substances 0.000 claims description 50
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 46
125000005842 heteroatom Chemical group 0.000 claims description 46
150000002430 hydrocarbons Chemical class 0.000 claims description 42
229930195733 hydrocarbon Natural products 0.000 claims description 41
239000004215 Carbon black (E152) Substances 0.000 claims description 36
229910052799 carbon Inorganic materials 0.000 claims description 24
229910052751 metal Inorganic materials 0.000 claims description 24
239000002184 metal Substances 0.000 claims description 24
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 23
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
229910001413 alkali metal ion Inorganic materials 0.000 claims description 18
150000002500 ions Chemical class 0.000 claims description 17
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 12
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 9
238000011065 in-situ storage Methods 0.000 claims description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
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238000002844 melting Methods 0.000 claims description 5
230000008018 melting Effects 0.000 claims description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 3
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239000001273 butane Substances 0.000 claims description 3
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150000001993 dienes Chemical class 0.000 claims description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
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239000001294 propane Substances 0.000 claims description 3
239000000047 product Substances 0.000 description 72
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 55
229910052717 sulfur Inorganic materials 0.000 description 42
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 37
239000011593 sulfur Substances 0.000 description 36
229910052757 nitrogen Inorganic materials 0.000 description 35
230000008569 process Effects 0.000 description 32
239000000463 material Substances 0.000 description 29
239000001257 hydrogen Substances 0.000 description 28
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239000002253 acid Substances 0.000 description 25
150000007513 acids Chemical class 0.000 description 16
238000000926 separation method Methods 0.000 description 16
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
239000003921 oil Substances 0.000 description 14
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239000007789 gas Substances 0.000 description 12
150000003839 salts Chemical class 0.000 description 12
238000006722 reduction reaction Methods 0.000 description 11
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230000009467 reduction Effects 0.000 description 9
239000003079 shale oil Substances 0.000 description 9
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230000015572 biosynthetic process Effects 0.000 description 8
239000000446 fuel Substances 0.000 description 8
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229910010272 inorganic material Inorganic materials 0.000 description 7
239000007788 liquid Substances 0.000 description 7
238000005868 electrolysis reaction Methods 0.000 description 6
108091006110 nucleoid-associated proteins Proteins 0.000 description 6
239000007787 solid Substances 0.000 description 6
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125000004432 carbon atom Chemical group C* 0.000 description 5
239000001569 carbon dioxide Substances 0.000 description 5
229910002092 carbon dioxide Inorganic materials 0.000 description 5
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239000011147 inorganic material Substances 0.000 description 5
239000003345 natural gas Substances 0.000 description 5
238000012545 processing Methods 0.000 description 5
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GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 5
238000001991 steam methane reforming Methods 0.000 description 5
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239000010426 asphalt Substances 0.000 description 4
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239000000295 fuel oil Substances 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
150000007522 mineralic acids Chemical class 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
239000012074 organic phase Substances 0.000 description 4
235000011121 sodium hydroxide Nutrition 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000003513 alkali Substances 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000002585 base Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
230000004907 flux Effects 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
229920000620 organic polymer Polymers 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000012071 phase Substances 0.000 description 3
239000002574 poison Substances 0.000 description 3
231100000614 poison Toxicity 0.000 description 3
239000002904 solvent Substances 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
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HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 2
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RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
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150000001875 compounds Chemical class 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
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239000010779 crude oil Substances 0.000 description 2
229960001760 dimethyl sulfoxide Drugs 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
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RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
150000002484 inorganic compounds Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
229910001416 lithium ion Inorganic materials 0.000 description 2
229910003002 lithium salt Inorganic materials 0.000 description 2
159000000002 lithium salts Chemical class 0.000 description 2
VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 description 2
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
239000003209 petroleum derivative Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
238000007348 radical reaction Methods 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
238000007670 refining Methods 0.000 description 2
229910001415 sodium ion Inorganic materials 0.000 description 2
150000004763 sulfides Chemical class 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
229920000049 Carbon (fiber) Polymers 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
229910018091 Li 2 S Inorganic materials 0.000 description 1
229910000733 Li alloy Inorganic materials 0.000 description 1
229910001216 Li2S Inorganic materials 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 1
229910000528 Na alloy Inorganic materials 0.000 description 1
229910003296 Ni-Mo Inorganic materials 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
229910001514 alkali metal chloride Inorganic materials 0.000 description 1
229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910001423 beryllium ion Inorganic materials 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
239000004917 carbon fiber Substances 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
238000004939 coking Methods 0.000 description 1
238000004891 communication Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
RLMGYIOTPQVQJR-UHFFFAOYSA-N cyclohexane-1,3-diol Chemical compound OC1CCCC(O)C1 RLMGYIOTPQVQJR-UHFFFAOYSA-N 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
238000006114 decarboxylation reaction Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
GUVUOGQBMYCBQP-UHFFFAOYSA-N dmpu Chemical compound CN1CCCN(C)C1=O GUVUOGQBMYCBQP-UHFFFAOYSA-N 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
229940031098 ethanolamine Drugs 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000002608 ionic liquid Substances 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
239000001989 lithium alloy Substances 0.000 description 1
GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
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125000004433 nitrogen atom Chemical group N* 0.000 description 1
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
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235000013772 propylene glycol Nutrition 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
239000002594 sorbent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
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238000012549 training Methods 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
- C10G32/02—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/04—Metals, or metals deposited on a carrier
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
- C10G75/02—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
- C10G2300/203—Naphthenic acids, TAN

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Microbiology (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Electrolytic Production Of Metals (AREA)

ES12849838T 2011-11-16 2012-11-16 Método para mejorar las materias primas petrolíferas utilizando una membrana conductora de metales alcalinos Active ES2862578T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US201161560653P	2011-11-16	2011-11-16
PCT/US2012/065670 WO2013075021A1 (fr)	2011-11-16	2012-11-16	Dispositif et procédé pour valoriser des charges d'alimentation pétrolières à l'aide d'une membrane conductrice à base de métal alcalin

Publications (2)

Publication Number	Publication Date
ES2862578T3 true ES2862578T3 (es)	2021-10-07
ES2862578T8 ES2862578T8 (es)	2022-01-10

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EP (1)	EP2780434B1 (fr)
JP (1)	JP6162711B2 (fr)
KR (1)	KR101909773B1 (fr)
CA (2)	CA2997472C (fr)
ES (1)	ES2862578T3 (fr)
HK (1)	HK1202572A1 (fr)
IN (1)	IN2014CN04302A (fr)
SG (1)	SG11201402307SA (fr)
WO (1)	WO2013075021A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20150144503A1 (en) *	2013-11-26	2015-05-28	Ceramatec, Inc.	Methods and systems for treating petroleum feedstock containing organic acids and sulfur

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ES2217323T3 (es) *	1995-08-25	2004-11-01	Exxonmobil Research And Engineering Company	Proceso para reducir la corrosividad y acidez de los crudos de petroleo.
GB9912842D0 (en) *	1999-06-02	1999-08-04	Bp Exploration Operating	Process for reducing the acidity of oil
GB0113645D0 (en) *	2001-06-05	2001-07-25	Bp Exploration Operating	Process
JP3516446B2 (ja)	2002-04-26	2004-04-05	東京応化工業株式会社	ホトレジスト剥離方法
BRPI0405724A (pt)	2003-12-19	2005-10-04	Shell Int Research	Produto de petróleo bruto e método de produzir combustìvel de transporte, combustìvel de aquecimento, lubrificantes ou substâncias quìmicas
US7897028B2 (en)	2004-01-26	2011-03-01	Ceramatec, Inc.	Process for the recovery of materials from a desulfurization reaction
US20060054538A1 (en) *	2004-09-14	2006-03-16	Exxonmobil Research And Engineering Company	Emulsion neutralization of high total acid number (TAN) crude oil
CA2705270C (fr) *	2007-11-27	2016-07-26	Ceramatec, Inc.	Procede pour recuperer des metaux alcalins et du soufre a partir de sulfures et de polysulfures de metaux alcalins
US8486251B2 (en) *	2008-08-05	2013-07-16	Exxonmobil Research And Engineering Company	Process for regenerating alkali metal hydroxides by electrochemical means
US8338038B2 (en) *	2008-09-12	2012-12-25	Ceramatec, Inc	Electrochemical cell comprising ionically conductive membrane and porous multiphase electrode
US20100087124A1 (en)	2008-10-07	2010-04-08	Farzad Saghian	Cd repair apparatus
KR101736753B1 (ko) *	2009-11-02	2017-05-17	필드 업그레이딩 리미티드	알칼리 금속과 탄화수소를 사용하여 석유 공급원료를 업그레이드시키는 방법
US8608952B2 (en) *	2009-12-30	2013-12-17	Uop Llc	Process for de-acidifying hydrocarbons

2012
- 2012-11-16 JP JP2014542519A patent/JP6162711B2/ja active Active
- 2012-11-16 HK HK15103026.5A patent/HK1202572A1/xx unknown
- 2012-11-16 KR KR1020147015890A patent/KR101909773B1/ko active Active
- 2012-11-16 EP EP12849838.3A patent/EP2780434B1/fr active Active
- 2012-11-16 WO PCT/US2012/065670 patent/WO2013075021A1/fr not_active Ceased
- 2012-11-16 CA CA2997472A patent/CA2997472C/fr active Active
- 2012-11-16 CA CA2855966A patent/CA2855966C/fr active Active
- 2012-11-16 SG SG11201402307SA patent/SG11201402307SA/en unknown
- 2012-11-16 IN IN4302CHN2014 patent/IN2014CN04302A/en unknown
- 2012-11-16 ES ES12849838T patent/ES2862578T3/es active Active

Also Published As

Publication number	Publication date
KR20140096119A (ko)	2014-08-04
EP2780434B1 (fr)	2021-03-03
SG11201402307SA (en)	2014-09-26
KR101909773B1 (ko)	2018-10-18
HK1202572A1 (en)	2015-10-02
JP2015501860A (ja)	2015-01-19
EP2780434A4 (fr)	2015-07-15
WO2013075021A1 (fr)	2013-05-23
JP6162711B2 (ja)	2017-07-12
IN2014CN04302A (fr)	2015-09-04
ES2862578T8 (es)	2022-01-10
CA2997472C (fr)	2020-02-25
CA2855966C (fr)	2018-05-01
CA2855966A1 (fr)	2013-05-23
EP2780434A1 (fr)	2014-09-24
CA2997472A1 (fr)	2013-05-23

Publication	Publication Date	Title
ES2656073T3 (es)	2018-02-23	Mejoramiento de materias primas de petróleo que usan metales alcalinos e hidrocarburos
EP2732010B1 (fr)	2018-10-10	Plateforme de valorisation utilisant des métaux alcalins
US20160369176A9 (en)	2016-12-22	Method of preventing corrosion of oil pipelines, storage structures and piping
Tang et al.	2015	Deep desulfurization of condensate gasoline by electrochemical oxidation and solvent extraction
KR20150127640A (ko)	2015-11-17	알칼리 금속 설파이드 및 폴리설파이드로부터 알칼리 금속 및 황을 회수하는 방법
ES2862578T3 (es)	2021-10-07	Método para mejorar las materias primas petrolíferas utilizando una membrana conductora de metales alcalinos
ES2650952T3 (es)	2018-01-23	Proceso para desulfurar materias primas de petróleo
US9441170B2 (en)	2016-09-13	Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
US8444843B2 (en)	2013-05-21	Electrocatalytic dissociation of water for hydrodesulfurization of hydrocarbon feedstock