ES2915829T3 - Método de producción de una dispersión acuosa de pigmento - Google Patents
Método de producción de una dispersión acuosa de pigmento Download PDFInfo
- Publication number
- ES2915829T3 ES2915829T3 ES18828747T ES18828747T ES2915829T3 ES 2915829 T3 ES2915829 T3 ES 2915829T3 ES 18828747 T ES18828747 T ES 18828747T ES 18828747 T ES18828747 T ES 18828747T ES 2915829 T3 ES2915829 T3 ES 2915829T3
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- polymer
- water
- pigment dispersion
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- 239000000049 pigment Substances 0.000 title claims abstract description 287
- 239000006185 dispersion Substances 0.000 title claims abstract description 206
- 238000004519 manufacturing process Methods 0.000 title description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 237
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- 239000000178 monomer Substances 0.000 claims abstract description 126
- 125000003010 ionic group Chemical group 0.000 claims abstract description 94
- 238000000034 method Methods 0.000 claims abstract description 78
- 150000001875 compounds Chemical class 0.000 claims abstract description 63
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 238000004132 cross linking Methods 0.000 claims abstract description 41
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 30
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 30
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 25
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 239000012736 aqueous medium Substances 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims description 61
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical group [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 50
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- -1 glycidyl ether compound Chemical class 0.000 claims description 25
- 125000000524 functional group Chemical group 0.000 claims description 22
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 125000000129 anionic group Chemical group 0.000 description 14
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- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 11
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
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- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 239000003431 cross linking reagent Substances 0.000 description 6
- 229910001873 dinitrogen Inorganic materials 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
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- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 6
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
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- 229920001451 polypropylene glycol Polymers 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 4
- 229940081735 acetylcellulose Drugs 0.000 description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
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- 239000003086 colorant Substances 0.000 description 4
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- 150000002148 esters Chemical class 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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- 239000004743 Polypropylene Substances 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
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- 239000002270 dispersing agent Substances 0.000 description 3
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- 238000002474 experimental method Methods 0.000 description 3
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- 150000002576 ketones Chemical class 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000003495 polar organic solvent Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
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- NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 3
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- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 2
- DAVVKEZTUOGEAK-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound COCCOCCOC(=O)C(C)=C DAVVKEZTUOGEAK-UHFFFAOYSA-N 0.000 description 2
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- CIXWVSNANHWSNT-UHFFFAOYSA-N 3-[[2-[[1-(2-carboxyethylamino)-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanoyl]amino]propanoic acid Chemical compound OC(=O)CCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCC(O)=O CIXWVSNANHWSNT-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
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- 239000004606 Fillers/Extenders Substances 0.000 description 2
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
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- NXBXJOWBDCQIHF-UHFFFAOYSA-N 2-[hydroxy-[2-(2-methylprop-2-enoyloxy)ethoxy]phosphoryl]oxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(=O)OCCOC(=O)C(C)=C NXBXJOWBDCQIHF-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
- C09D11/326—Inkjet printing inks characterised by colouring agents containing carbon black characterised by the pigment dispersant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Duplication Or Marking (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017130674 | 2017-07-03 | ||
| PCT/JP2018/024520 WO2019009170A1 (fr) | 2017-07-03 | 2018-06-28 | Procédé de production d'une dispersion aqueuse de pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2915829T3 true ES2915829T3 (es) | 2022-06-27 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES18828747T Active ES2915829T3 (es) | 2017-07-03 | 2018-06-28 | Método de producción de una dispersión acuosa de pigmento |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11447578B2 (fr) |
| EP (1) | EP3650510B1 (fr) |
| JP (1) | JP6452881B1 (fr) |
| CN (1) | CN110832042B (fr) |
| ES (1) | ES2915829T3 (fr) |
| WO (1) | WO2019009170A1 (fr) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6965703B2 (ja) * | 2016-11-28 | 2021-11-10 | 東洋インキScホールディングス株式会社 | (メタ)アクリル系重合体、(メタ)アクリル系ブロック共重合体、顔料分散体、感光性着色組成物、カラーフィルタ、インキ組成物、複合ブロック共重合体、顔料分散剤。 |
| JP7340444B2 (ja) * | 2019-12-24 | 2023-09-07 | 花王株式会社 | 顔料水分散体 |
| JP7667648B2 (ja) * | 2020-10-26 | 2025-04-23 | 花王株式会社 | 水系顔料分散体の製造方法 |
| CN112552746A (zh) * | 2020-11-30 | 2021-03-26 | 珠海天威新材料股份有限公司 | 一种水性颜料色浆及其制备方法 |
| WO2022145425A1 (fr) * | 2020-12-28 | 2022-07-07 | 花王株式会社 | Dispersion aqueuse de pigment |
| EP4286485A4 (fr) * | 2021-04-15 | 2024-07-03 | Dic Corporation | Dispersion aqueuse de pigment, encre d'impression par jet d'encre et procédé de production de matériau imprimé |
| JP7770175B2 (ja) * | 2021-12-14 | 2025-11-14 | 東ソー・ファインケム株式会社 | 上限臨界溶液温度型の温度応答性を有するカルボン酸系ポリマー及びその用途 |
| WO2024069154A1 (fr) | 2022-09-26 | 2024-04-04 | Fujifilm Speciality Ink Systems Limited | Encre d'impression |
| JP2024050438A (ja) | 2022-09-29 | 2024-04-10 | 日信化学工業株式会社 | 分散剤、分散体及びインク組成物、並びにこれらの製造方法 |
| GB202404181D0 (en) | 2024-03-22 | 2024-05-08 | Fujifilm Speciality Ink Systems Ltd | Printing ink |
| GB202404182D0 (en) | 2024-03-22 | 2024-05-08 | Fujifilm Speciality Ink Systems Ltd | Printing ink |
| JP2025148119A (ja) * | 2024-03-25 | 2025-10-07 | 富士フイルム株式会社 | 顔料分散物の製造方法、インクジェットインクの製造方法、及び画像記録方法 |
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| US6107397A (en) * | 1997-03-24 | 2000-08-22 | Basf Aktiengesellschaft | Aqueous copolymer dispersions of water-soluble monomers with N-vinyl groups and hydrophobic monomers |
| CN1206013A (zh) * | 1997-03-24 | 1999-01-27 | Basf公司 | 含n-乙烯基的水溶性单体与疏水性单体的水性共聚物分散体 |
| EP1652897B1 (fr) | 2002-06-25 | 2010-06-30 | Kao Corporation | Encre à base d'eau |
| JP3907191B2 (ja) | 2002-12-27 | 2007-04-18 | 花王株式会社 | 水系インク |
| JP3919093B2 (ja) * | 2002-06-25 | 2007-05-23 | 花王株式会社 | 水系インク |
| US20040102568A1 (en) * | 2002-11-22 | 2004-05-27 | Bridgewater Brian Michael | Aqueous coating composition |
| JP3790537B2 (ja) * | 2004-10-29 | 2006-06-28 | 花王株式会社 | インクジェット記録用水系インク |
| JP4759262B2 (ja) * | 2004-12-22 | 2011-08-31 | 花王株式会社 | インクジェット記録用水系インク |
| JP2006274141A (ja) * | 2005-03-30 | 2006-10-12 | Dainippon Ink & Chem Inc | インクジェット記録用水性インク調製のための水分散体及びインクジェット記録用水性インク |
| WO2007126145A2 (fr) | 2006-04-28 | 2007-11-08 | Kao Corporation | Encres à base d'eau pour impression par jet d'encre |
| JP4077021B2 (ja) | 2006-04-28 | 2008-04-16 | 花王株式会社 | インクジェット記録用水系インク |
| KR102194356B1 (ko) * | 2013-06-06 | 2020-12-23 | 카오카부시키가이샤 | 잉크젯 기록용 수계 잉크 |
| JP5624656B2 (ja) * | 2013-08-01 | 2014-11-12 | 花王株式会社 | サーマルインクジェット記録用水系インク |
| EP3165575B1 (fr) | 2014-07-04 | 2020-09-30 | Kao Corporation | Procédé de fabrication de dispersion de microparticules colorées |
| JP2016160331A (ja) * | 2015-02-27 | 2016-09-05 | 富士フイルム株式会社 | 水性顔料分散物及び水性インク組成物 |
| GB201513018D0 (en) * | 2015-07-23 | 2015-09-09 | Fujifilm Imaging Colorants Ltd | Process, dispersions and use |
| JP6652272B2 (ja) | 2015-12-25 | 2020-02-19 | 花王株式会社 | 顔料水分散体 |
| JP6391721B2 (ja) * | 2016-01-16 | 2018-09-19 | キヤノン株式会社 | 水性インクの製造方法、及びインクジェット記録方法 |
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- 2018-06-28 US US16/626,185 patent/US11447578B2/en active Active
- 2018-06-28 CN CN201880043065.0A patent/CN110832042B/zh active Active
- 2018-06-28 ES ES18828747T patent/ES2915829T3/es active Active
- 2018-06-28 WO PCT/JP2018/024520 patent/WO2019009170A1/fr not_active Ceased
- 2018-06-28 EP EP18828747.8A patent/EP3650510B1/fr active Active
- 2018-06-28 JP JP2018122815A patent/JP6452881B1/ja active Active
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| Publication number | Publication date |
|---|---|
| CN110832042B (zh) | 2022-10-14 |
| CN110832042A (zh) | 2020-02-21 |
| US20200216580A1 (en) | 2020-07-09 |
| WO2019009170A1 (fr) | 2019-01-10 |
| EP3650510B1 (fr) | 2022-05-04 |
| US11447578B2 (en) | 2022-09-20 |
| EP3650510A4 (fr) | 2021-03-17 |
| EP3650510A1 (fr) | 2020-05-13 |
| JP2019014879A (ja) | 2019-01-31 |
| JP6452881B1 (ja) | 2019-01-16 |
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