ES292122A1 - Process for modifying the characteristics of structures containing keratin fibres and product thereof - Google Patents
Process for modifying the characteristics of structures containing keratin fibres and product thereofInfo
- Publication number
- ES292122A1 ES292122A1 ES0292122A ES292122A ES292122A1 ES 292122 A1 ES292122 A1 ES 292122A1 ES 0292122 A ES0292122 A ES 0292122A ES 292122 A ES292122 A ES 292122A ES 292122 A1 ES292122 A1 ES 292122A1
- Authority
- ES
- Spain
- Prior art keywords
- fibres
- isocyanate
- fabric
- groups
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 102000011782 Keratins Human genes 0.000 title abstract 3
- 108010076876 Keratins Proteins 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 6
- 239000004744 fabric Substances 0.000 abstract 6
- 239000012948 isocyanate Substances 0.000 abstract 6
- -1 isocyanate compound Chemical class 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000005470 impregnation Methods 0.000 abstract 2
- 150000002513 isocyanates Chemical class 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 229920002647 polyamide Polymers 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- JRMAQQQTXDJDNC-UHFFFAOYSA-M 2-ethoxy-2-oxoacetate Chemical compound CCOC(=O)C([O-])=O JRMAQQQTXDJDNC-UHFFFAOYSA-M 0.000 abstract 1
- 235000002198 Annona diversifolia Nutrition 0.000 abstract 1
- 241000282836 Camelus dromedarius Species 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 abstract 1
- 241000282842 Lama glama Species 0.000 abstract 1
- 241000282852 Lama guanicoe Species 0.000 abstract 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 abstract 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- 241001416177 Vicugna pacos Species 0.000 abstract 1
- 241000282840 Vicugna vicugna Species 0.000 abstract 1
- 239000000980 acid dye Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 238000003490 calendering Methods 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 210000000085 cashmere Anatomy 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000002788 crimping Methods 0.000 abstract 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical class OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 150000003949 imides Chemical class 0.000 abstract 1
- ZBKFYXZXZJPWNQ-UHFFFAOYSA-N isothiocyanate group Chemical group [N-]=C=S ZBKFYXZXZJPWNQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002540 isothiocyanates Chemical class 0.000 abstract 1
- 238000009940 knitting Methods 0.000 abstract 1
- 150000003951 lactams Chemical class 0.000 abstract 1
- 210000000050 mohair Anatomy 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 150000003336 secondary aromatic amines Chemical class 0.000 abstract 1
- 229920002050 silicone resin Polymers 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 150000003509 tertiary alcohols Chemical class 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polyurethanes Or Polyureas (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Structures containing keratin fibres are shrinkproofed and permanent configurations and mechanical effects, e.g. pleating, crimping and calendering, are set therein by reacting them with a polyfunctional isocyanate compound containing at least two groups which are isocyanate or isothiocyanate groups and a polymeric polyfunctional compound which is a polyester, polyamide, polyepoxide, a reaction product of a phenol and an alkylene oxide, a formaldehyde resin, a hydrogenation product of an olefin-carbon monoxide copolymer or a polyepihalohydrin. The isocyanate compound and the polymeric polyfunctional compound may be reacted together to an extent below which a gel is produced which is insoluble in a non-reactive organic solvent to form a prepolymer and the prepolymer then applied to the fibres. The isocyanate compound may be an aryl, alicyclic or alkylene diisocyanate or diisothiocyanate. The isocyanate compound and the polymeric polyfunctional compound may be applied to the fibres as a solution in a non-reactive organic solvent, e.g. a halogenated hydrocarbon, an aromatic hydrocarbon, n-butyl acetate, ether or phosphate, p-dioxane, ethyl oxalate, methyl isobutyl ketone, pyridine, quinoline, N,N-dimethyl-formamide or acetamide or 2,2,4-trimethyl pentane by padding, immersing, spraying or applicator rolls or as aqueous emulsions or dispersions when the isocyanate groups are blocked by reaction with tertiary alcohols, secondary aromatic amines which contain only one group having a hydrogen atom reactive with an isocyanate group, mercaptans, lactams, imides, monohydric phenols or compounds containing enolizable hydrogen. The treating solution may also contain a catalyst, a silicone resin and a coreactant containing at least two -OH1-NH2-NRH,-COOH or-SH groups or the coreactant may be applied from a separate solution. Numerous examples of suitable isocyanates, isothiocyanates, polymeric polyfunctional compounds, catalysts, coreactants and isocyanate group blocking compounds are given. After impregnation the fibres may be dried and cured by heating to 200 DEG -260 DEG F., aged for 12 - 24 hours, scoured and dyed with premetallized or acid dyes. During impregnation the fibres and solutions are preferably maintained at a pH of 3-9. Fabrics comprising wool alone or in admixture with synthetic polyamide, polyester, acrylic, cellulose acetate, viscose rayon or cotton fibres may be treated. Other suitable keratin fibres are mohair, alpaca, cashmere, vicuna, guanaco, camel hair or llama may be treated. In inserting a desired configuration, e.g. pleat, in a fabric, the fabric may be impregnated, arranged in the configuration and cured. Alternatively the fabric may be impregnated, dried, made into garments, pressed to the desired configuration and cured. Reference is also made to crimped yarns and crimped stretch fabrics. Crimped yarns may be obtained by knitting yarn, impregnating, curing and unravelling the knitted fabric.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23073162A | 1962-10-15 | 1962-10-15 | |
| US29276963A | 1963-07-03 | 1963-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES292122A1 true ES292122A1 (en) | 1964-03-01 |
Family
ID=26924495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0292122A Expired ES292122A1 (en) | 1962-10-15 | 1963-09-20 | Process for modifying the characteristics of structures containing keratin fibres and product thereof |
Country Status (11)
| Country | Link |
|---|---|
| BE (1) | BE638673A (en) |
| CH (1) | CH462099A (en) |
| DE (1) | DE1444047C3 (en) |
| DK (1) | DK116792B (en) |
| ES (1) | ES292122A1 (en) |
| FI (1) | FI43728C (en) |
| FR (1) | FR1377613A (en) |
| GB (1) | GB1064982A (en) |
| LU (1) | LU44605A1 (en) |
| NL (2) | NL144005B (en) |
| SE (1) | SE339285B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL123321A (en) * | 1997-03-04 | 2001-01-11 | Ciba Sc Pfersee Gmbh | Process for treating wool-comprising fabrics |
| WO2014120100A1 (en) * | 2013-01-29 | 2014-08-07 | Güven Boya Apre Ve Dokuma Fabri̇kalari Anoni̇m Şi̇rketi̇ | Production method providing size stability of wool and wool blend fabrics |
-
0
- BE BE638673D patent/BE638673A/xx unknown
- NL NL299245D patent/NL299245A/xx unknown
-
1963
- 1963-09-12 GB GB3599763A patent/GB1064982A/en not_active Expired
- 1963-09-20 ES ES0292122A patent/ES292122A1/en not_active Expired
- 1963-10-09 FR FR950021A patent/FR1377613A/en not_active Expired
- 1963-10-10 LU LU44605D patent/LU44605A1/xx unknown
- 1963-10-14 SE SE1125863A patent/SE339285B/xx unknown
- 1963-10-14 DK DK483663A patent/DK116792B/en unknown
- 1963-10-15 FI FI199263A patent/FI43728C/en active
- 1963-10-15 NL NL299245A patent/NL144005B/en unknown
- 1963-10-15 CH CH1264563A patent/CH462099A/en unknown
- 1963-10-15 DE DE19631444047 patent/DE1444047C3/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1444047A1 (en) | 1970-02-19 |
| NL144005B (en) | 1974-11-15 |
| DK116792B (en) | 1970-02-16 |
| CH462099A (en) | 1968-04-11 |
| NL299245A (en) | |
| LU44605A1 (en) | 1963-12-10 |
| GB1064982A (en) | 1967-04-12 |
| BE638673A (en) | |
| DE1444047C3 (en) | 1974-10-17 |
| FR1377613A (en) | 1964-11-06 |
| FI43728B (en) | 1971-03-01 |
| FI43728C (en) | 1971-06-10 |
| SE339285B (en) | 1971-10-04 |
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