ES2922545T3 - Método ecológico para el blanqueo local y reproducible de tejidos con ozono - Google Patents

Método ecológico para el blanqueo local y reproducible de tejidos con ozono Download PDF

Info

Publication number: ES2922545T3
Authority: ES; Spain
Prior art keywords: ozone; hygroscopic substance; bleaching; dyed material; dyed
Prior art date: 2016-10-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES17784899T

Other languages

English (en)

Spanish (es)

Other versions

ES2922545T8 (es

Inventor

Christian Bruno Schimper

Paul Sebastian Pachschwöll

Hubert Hettegger

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Acticell GmbH

Jeanologia SL

Original Assignee

Acticell GmbH

Jeanologia SL

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2016-10-03

Filing date

2017-10-03

Publication date

2022-09-16

2017-10-03 Application filed by Acticell GmbH, Jeanologia SL filed Critical Acticell GmbH

2022-09-16 Application granted granted Critical

2022-09-16 Publication of ES2922545T3 publication Critical patent/ES2922545T3/es

2024-01-19 Publication of ES2922545T8 publication Critical patent/ES2922545T8/es

Status Active legal-status Critical Current

2037-10-03 Anticipated expiration legal-status Critical

Links

CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 113
238000000034 method Methods 0.000 title claims abstract description 52
238000004061 bleaching Methods 0.000 title abstract description 65
239000004744 fabric Substances 0.000 title abstract description 47
239000000126 substance Substances 0.000 claims abstract description 84
230000000694 effects Effects 0.000 claims abstract description 32
239000000463 material Substances 0.000 claims description 59
238000011282 treatment Methods 0.000 claims description 42
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 27
239000000203 mixture Substances 0.000 claims description 24
230000008859 change Effects 0.000 claims description 17
150000001875 compounds Chemical class 0.000 claims description 13
-1 tachyhydrite Chemical compound 0.000 claims description 11
239000002562 thickening agent Substances 0.000 claims description 11
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
150000003839 salts Chemical class 0.000 claims description 10
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
239000000080 wetting agent Substances 0.000 claims description 9
239000002904 solvent Substances 0.000 claims description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
239000007788 liquid Substances 0.000 claims description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
235000019341 magnesium sulphate Nutrition 0.000 claims description 5
229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
235000011152 sodium sulphate Nutrition 0.000 claims description 5
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 4
HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 4
IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 4
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 4
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 4
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 4
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
150000001298 alcohols Chemical class 0.000 claims description 3
239000001110 calcium chloride Substances 0.000 claims description 3
229910001628 calcium chloride Inorganic materials 0.000 claims description 3
235000011187 glycerol Nutrition 0.000 claims description 3
229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
239000003550 marker Substances 0.000 claims description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 2
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 2
JTNCEQNHURODLX-UHFFFAOYSA-N 2-phenylethanimidamide Chemical compound NC(=N)CC1=CC=CC=C1 JTNCEQNHURODLX-UHFFFAOYSA-N 0.000 claims description 2
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
229940061720 alpha hydroxy acid Drugs 0.000 claims description 2
150000001280 alpha hydroxy acids Chemical class 0.000 claims description 2
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 2
229910001622 calcium bromide Inorganic materials 0.000 claims description 2
WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims description 2
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
150000002334 glycols Chemical class 0.000 claims description 2
235000014655 lactic acid Nutrition 0.000 claims description 2
239000004310 lactic acid Substances 0.000 claims description 2
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 2
OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 2
229910001623 magnesium bromide Inorganic materials 0.000 claims description 2
PALNZFJYSCMLBK-UHFFFAOYSA-K magnesium;potassium;trichloride;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-].[Cl-].[K+] PALNZFJYSCMLBK-UHFFFAOYSA-K 0.000 claims description 2
VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 2
235000010449 maltitol Nutrition 0.000 claims description 2
239000000845 maltitol Substances 0.000 claims description 2
229940035436 maltitol Drugs 0.000 claims description 2
229940099596 manganese sulfate Drugs 0.000 claims description 2
239000011702 manganese sulphate Substances 0.000 claims description 2
235000007079 manganese sulphate Nutrition 0.000 claims description 2
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 2
150000002894 organic compounds Chemical class 0.000 claims description 2
235000006408 oxalic acid Nutrition 0.000 claims description 2
229920005862 polyol Polymers 0.000 claims description 2
150000003077 polyols Chemical class 0.000 claims description 2
229910000343 potassium bisulfate Inorganic materials 0.000 claims description 2
239000001103 potassium chloride Substances 0.000 claims description 2
235000011164 potassium chloride Nutrition 0.000 claims description 2
235000010333 potassium nitrate Nutrition 0.000 claims description 2
239000004323 potassium nitrate Substances 0.000 claims description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
235000011151 potassium sulphates Nutrition 0.000 claims description 2
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 2
229910000342 sodium bisulfate Inorganic materials 0.000 claims description 2
239000011780 sodium chloride Substances 0.000 claims description 2
235000010344 sodium nitrate Nutrition 0.000 claims description 2
239000004317 sodium nitrate Substances 0.000 claims description 2
239000000600 sorbitol Substances 0.000 claims description 2
235000010356 sorbitol Nutrition 0.000 claims description 2
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 2
FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 claims description 2
239000000811 xylitol Substances 0.000 claims description 2
235000010447 xylitol Nutrition 0.000 claims description 2
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 2
229960002675 xylitol Drugs 0.000 claims description 2
239000011592 zinc chloride Substances 0.000 claims description 2
235000005074 zinc chloride Nutrition 0.000 claims description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
239000007864 aqueous solution Substances 0.000 description 39
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 38
239000004753 textile Substances 0.000 description 32
238000006385 ozonation reaction Methods 0.000 description 23
239000000975 dye Substances 0.000 description 18
239000003795 chemical substances by application Substances 0.000 description 16
239000003086 colorant Substances 0.000 description 13
239000000835 fiber Substances 0.000 description 12
238000001035 drying Methods 0.000 description 11
239000007789 gas Substances 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 11
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239000003623 enhancer Substances 0.000 description 10
COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 10
230000008569 process Effects 0.000 description 9
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108090000790 Enzymes Proteins 0.000 description 6
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ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
239000000654 additive Substances 0.000 description 5
239000012080 ambient air Substances 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
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239000000843 powder Substances 0.000 description 5
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WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 4
230000009471 action Effects 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
239000007844 bleaching agent Substances 0.000 description 4
238000000576 coating method Methods 0.000 description 4
239000002270 dispersing agent Substances 0.000 description 4
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239000008103 glucose Substances 0.000 description 4
229910001385 heavy metal Inorganic materials 0.000 description 4
238000007654 immersion Methods 0.000 description 4
COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 description 4
238000013532 laser treatment Methods 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
239000007832 Na2SO4 Substances 0.000 description 2
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NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
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RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
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FDSDTBUPSURDBL-LOFNIBRQSA-N canthaxanthin Chemical compound CC=1C(=O)CCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)C(=O)CCC1(C)C FDSDTBUPSURDBL-LOFNIBRQSA-N 0.000 description 2
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IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 2
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JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
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HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
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235000012756 tartrazine Nutrition 0.000 description 1
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UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
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VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 1
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YJCJAUSWVUZMSY-UHFFFAOYSA-K trisodium;4-[(2,4-diamino-5-methylphenyl)diazenyl]benzenesulfonate;4-[[2,4-diamino-5-[(4-sulfonatophenyl)diazenyl]phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].[Na+].C1=C(N)C(C)=CC(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)=C1N.NC1=CC(N)=C(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)C=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 YJCJAUSWVUZMSY-UHFFFAOYSA-K 0.000 description 1
SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
239000002699 waste material Substances 0.000 description 1
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235000010493 xanthan gum Nutrition 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
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239000001018 xanthene dye Substances 0.000 description 1
FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
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UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/153—Locally discharging the dyes with oxidants

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Coloring (AREA)
Detergent Compositions (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)
Paper (AREA)

ES17784899T 2016-10-03 2017-10-03 Método ecológico para el blanqueo local y reproducible de tejidos con ozono Active ES2922545T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP16192076		2016-10-03
PCT/EP2017/075037 WO2018065388A1 (en)	2016-10-03	2017-10-03	Environmentally friendly method for local and reproducible bleaching of fabric with ozone

Publications (2)

Publication Number	Publication Date
ES2922545T3 true ES2922545T3 (es)	2022-09-16
ES2922545T8 ES2922545T8 (es)	2024-01-19

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EP (1)	EP3519623B8 (de)
CN (1)	CN110073054B (de)
ES (1)	ES2922545T3 (de)
PT (1)	PT3519623T (de)
WO (1)	WO2018065388A1 (de)

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CN108442151B (zh) *	2018-04-17	2020-06-26	广东溢达纺织有限公司	纯棉染色织物渐变剥色方法
CN109338706A (zh) *	2018-11-07	2019-02-15	青岛奥洛思新材料有限公司	一种退浆脱色复合酶及其怀旧风格的牛仔面料水洗工艺
JP7392995B2 (ja) *	2020-06-10	2023-12-06	豊和株式会社	ユーズド加工を施した物品の製造方法
ES2953291T3 (es) *	2020-07-01	2023-11-10	Jeanologia Sl	Método y aparato para el tratamiento de un tejido textil
US11608588B2 (en) *	2020-08-07	2023-03-21	Fast Retailing Co., Ltd.	Damage processing method and manufacturing method for textile product
CN113073461B (zh) *	2021-03-03	2022-09-06	江南大学	一种有色涤纶织物的回收方法
IT202100007712A1 (it) *	2021-03-29	2022-09-29	Soko Chimica S R L	Metodo di decolorazione di tessuti
JP2023057374A (ja) *	2021-10-11	2023-04-21	豊和株式会社	デニム製品の製造方法

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US5118322A (en) *	1990-07-31	1992-06-02	Eric Wasinger	Ozone decolorization of garments
JPH0737715B2 (ja) *	1990-08-08	1995-04-26	豊和株式会社	繊維染色物の脱色模様の形成方法
JPH0781238B2 (ja) *	1992-06-26	1995-08-30	日東製網株式会社	デニム製品のオゾン水による脱色加工時に於ける発色助剤添加による発色加工方法とその製品
WO1995013415A1 (en) *	1993-11-10	1995-05-18	Ecolab Inc.	Decolorizing fabrics and garments with a liquid treating agent containing ozone
JP4022436B2 (ja)	2002-06-20	2007-12-19	豊和株式会社	脱色模様形成方法
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US20120276821A1 (en) *	2011-04-28	2012-11-01	Richardiere Gilbert	Method and system enabling premature use of a textile garment made of denim fabric
CN102787486B (zh) *	2012-08-15	2014-10-01	广东省均安牛仔服装研究院	一种应用于牛仔面料的无水洗水工艺
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WO2015164577A1 (en) *	2014-04-24	2015-10-29	Allen Thomas R	Methods and systems for bleaching textiles

2017
- 2017-10-03 EP EP17784899.1A patent/EP3519623B8/de active Active
- 2017-10-03 CN CN201780074860.1A patent/CN110073054B/zh active Active
- 2017-10-03 ES ES17784899T patent/ES2922545T3/es active Active
- 2017-10-03 WO PCT/EP2017/075037 patent/WO2018065388A1/en not_active Ceased
- 2017-10-03 PT PT177848991T patent/PT3519623T/pt unknown

Also Published As

Publication number	Publication date
EP3519623A1 (de)	2019-08-07
EP3519623B1 (de)	2022-06-01
CN110073054A (zh)	2019-07-30
EP3519623B8 (de)	2022-07-13
CN110073054B (zh)	2023-05-30
ES2922545T8 (es)	2024-01-19
WO2018065388A1 (en)	2018-04-12
PT3519623T (pt)	2022-07-29

Publication	Publication Date	Title
ES2922545T3 (es)	2022-09-16	Método ecológico para el blanqueo local y reproducible de tejidos con ozono
CN109722837B (zh)	2021-05-25	纺织品的损伤方法
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JP2770437B2 (ja)	1998-07-02	ロープ染色法及びロープ染色物
EP3412826A1 (de)	2018-12-12	Behandlung von gefärbtem material
KR102477862B1 (ko)	2022-12-15	친환경적인 청바지의 탈색방법
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JP7392995B2 (ja)	2023-12-06	ユーズド加工を施した物品の製造方法
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ITRE20060011A1 (it)	2007-08-02	Procedimento per tingere in modo non uniforme prodotti tessili
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