ES314604A1 - A procedure for the preparation of a granular material of non-pigmentary titanium dioxide. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure for the preparation of a granular material of non-pigmentary titanium dioxide. (Machine-translation by Google Translate, not legally binding)

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Publication number
ES314604A1
ES314604A1 ES0314604A ES314604A ES314604A1 ES 314604 A1 ES314604 A1 ES 314604A1 ES 0314604 A ES0314604 A ES 0314604A ES 314604 A ES314604 A ES 314604A ES 314604 A1 ES314604 A1 ES 314604A1
Authority
ES
Spain
Prior art keywords
microns
titanium
tio2
titanium dioxide
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0314604A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Titan GmbH
Original Assignee
Titan GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US378044A external-priority patent/US3403977A/en
Application filed by Titan GmbH filed Critical Titan GmbH
Publication of ES314604A1 publication Critical patent/ES314604A1/en
Expired legal-status Critical Current

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  • Detergent Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

A process for the preparation of a non-pigmentary granular titanium dioxide material capable of rapidly melting in a molten glass charge without releasing dust or settling, the granular material having a grain size range between less than 1680 microns and more than 37 microns, with at least 75% of more than 37 microns, and consisting essentially of agglomerated particles of titanium dioxide with an individual size range between 0.05 and 0.15 microns, the material having a bulk density that falls within from the margin of 0.8 to 1.7g per cm3 and which is freely flowing and capable of being handled without releasing dust, by digestion of a titaniferous material in concentrated sulfuric acid to form a digestion cake, dissolving the cake in aqueous media, reducing the amounts of iron in the solution to the ferrous state, and clarifying the solution characterized by that at least 75% of the clarified solution of sulfate of titanium-sulphate of iron, with a concentration within the range of 100 to 180 g of titanium per liter, calculated as TiO2, and a proportion of H2SO4/TiO2 of 1.7 to 2.3 and heated to 40-80º C, is added to heated water at least 80º with stirring for a period of 15-50 minutes, the volume of water used being 10% to 100% of the amount of solution used, keeping the temperature of the mixture between 60 and 80º C during the addition period, heating the mixture to the boiling temperature for a period between 15 and 75 minutes, boiling the mixture for at least one hour to hydrolyze the amounts of titanium and form an insoluble titanium hydrate, filtering, washing and whitening the titanium hydrate, calcining the titanium hydrate bleached at 800-1000º C, and subdividing the nodules of agglomerated particles of TiO2, formed during the calcination, into TiO2 granules of such size, which pass through a sieve of 1680 microns but which are retained. os on a sieve of 37 microns. (Machine-translation by Google Translate, not legally binding)
ES0314604A 1964-06-25 1965-06-24 A procedure for the preparation of a granular material of non-pigmentary titanium dioxide. (Machine-translation by Google Translate, not legally binding) Expired ES314604A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US378044A US3403977A (en) 1964-06-25 1964-06-25 Method for production of titanium dioxide granules

Publications (1)

Publication Number Publication Date
ES314604A1 true ES314604A1 (en) 1965-10-01

Family

ID=59091787

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0314604A Expired ES314604A1 (en) 1964-06-25 1965-06-24 A procedure for the preparation of a granular material of non-pigmentary titanium dioxide. (Machine-translation by Google Translate, not legally binding)

Country Status (1)

Country Link
ES (1) ES314604A1 (en)

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