ES340685A1 - Process for making a modified carbohydrate material for smoking mixtures and the material made thereby - Google Patents
Process for making a modified carbohydrate material for smoking mixtures and the material made therebyInfo
- Publication number
- ES340685A1 ES340685A1 ES340685A ES340685A ES340685A1 ES 340685 A1 ES340685 A1 ES 340685A1 ES 340685 A ES340685 A ES 340685A ES 340685 A ES340685 A ES 340685A ES 340685 A1 ES340685 A1 ES 340685A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- product
- gum
- ammonium
- degraded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
Landscapes
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Paper (AREA)
- Manufacture Of Tobacco Products (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicinal Preparation (AREA)
- Confectionery (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
Polysaccharides are subjected to a catalysed degradation at 100-250 DEG C. until the weight of the degraded material is less than 90% of the starting material. Specified catalysts are sulphamic acid, ammonium sulphamate, phosphoric acid, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, sulphuric acid, hydrochloric acid, ferric chloride, sodium hydroxide or sodium carbonate. The polysaccharide may be a -cellulose, methyl cellulose, starch, alginic acid, pectin, gum tragacanth, gum arabic or locust bean gum. The treated product may be further treated with nitric acid, hydrogen peroxide or ammonia to improve the colour. The product is useful in compounding smoking mixtures (see Division A2), but must be washed free of NaOH or sodium carbonate if these catalyst were used.ALSO:A smoking mixture comprises a carbohydrate which has been catalytically degraded at 100-250 DEG C. to less than 90% of its original weight. Specified carbohydrates are a -cellulose, methyl cellulose, glucose, sucrose, starch, alginic acid, pectin, gum tragacanth, gum arabic or locust bean gum. The degraded product may have been further treated with nitric acid, hydrogen peroxide or ammonia to improve colour. Other adjuvants include glow-promoting catalysts, e.g. alkali metal compounds ash improvers, e.g. ammonium, alkaline earth or alkali metal salts flavours, e.g. tobacco extract, organic esters, essential oils, menthol, touka bean or vanillin humectants, e.g. glycols or glycerol and combustion improvers, e.g. carbonates. Any alkali catalyst, and, desirably any acid catalyst remaining in the treated material is neutralized before use. The product, together with the other ingredients, may be conditioned to 5-15% water content in a humid atmosphere. The product may be in sheet form, which can be shredded, optionally with film-forming agents such as methyl cellulose, sodium CMC, PVA, starch, pectin, gum or mucilage.ALSO:Wood-pulp or a -cellolose optionally in the form of sheets is catalytically degraded at 100-250 DEG C until the product is less than 90% of the weight of the starting material. Specified catalysts are sulphamic acid, ammonium sulphamate, phosphoric acid, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, sulphuric acid, ammonium sulphate, hydrochloric acid, ferric chloride, sodium hydroxide and sodium carbonate. The degraded product may be further treated with nitric acid, hydrogen peroxide or ammonia to improve the colour. The sheets may be held together with such binders as methyl cellulose, sodium CMC, PVA, starch, pectin, gum or mucilage. Optionally, sheets may be formed of the final treated product, using binders as specified above. The product, e.g. in the form of shredded sheets, is useful in making smoking mixtures (see Div. A2), but must first be washed free of any alkaline degradation catalyst used.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB22270/66A GB1113979A (en) | 1966-05-19 | 1966-05-19 | Modified carbohydrate material for smoking mixtures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES340685A1 true ES340685A1 (en) | 1968-09-16 |
Family
ID=10176655
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES340685A Expired ES340685A1 (en) | 1966-05-19 | 1967-05-18 | Process for making a modified carbohydrate material for smoking mixtures and the material made thereby |
| ES344777A Expired ES344777A1 (en) | 1966-05-19 | 1967-09-06 | PROCEDURE FOR PREPARING SMOKING MIXTURES. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES344777A Expired ES344777A1 (en) | 1966-05-19 | 1967-09-06 | PROCEDURE FOR PREPARING SMOKING MIXTURES. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3545448A (en) |
| BE (1) | BE698359A (en) |
| CH (1) | CH529175A (en) |
| DE (2) | DE1692921C3 (en) |
| DK (1) | DK127671B (en) |
| ES (2) | ES340685A1 (en) |
| GB (1) | GB1113979A (en) |
| LU (1) | LU53689A1 (en) |
| NL (1) | NL141770B (en) |
| NO (1) | NO116233B (en) |
| SE (1) | SE383891B (en) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3738374A (en) * | 1970-03-05 | 1973-06-12 | B Lab | Cigar or cigarette having substitute filler |
| US4008723A (en) * | 1970-03-23 | 1977-02-22 | Imperial Chemical Industries Limited | Smoking mixture |
| GB1312483A (en) * | 1970-03-23 | 1973-04-04 | Ici Ltd | Smoking mixture |
| GB1317584A (en) * | 1970-03-23 | 1973-05-23 | Ici Ltd | Smoking mixture |
| GB1299296A (en) * | 1970-03-23 | 1972-12-13 | Ici Ltd | Improved smoking mixture |
| US4005718A (en) * | 1970-07-11 | 1977-02-01 | Carreras Rothmans Limited | Smoking materials |
| US3951155A (en) * | 1970-07-11 | 1976-04-20 | Carreras Rothmans Limited | Smoking materials |
| GB1332503A (en) * | 1970-10-15 | 1973-10-03 | British American Tobacco Co | Smoking compositions |
| BE788198A (en) * | 1971-09-08 | 1973-02-28 | Ici Ltd | IMPROVED SMOKING MIX |
| GB1364103A (en) * | 1971-12-15 | 1974-08-21 | Ici Ltd | Smoking mixtures |
| US3892244A (en) * | 1971-12-15 | 1975-07-01 | Ici Ltd | Smoking mixtures |
| US4319591A (en) * | 1972-02-09 | 1982-03-16 | Celanese Corporation | Smoking compositions |
| US3812864A (en) * | 1972-02-09 | 1974-05-28 | Celanese Corp | Tobacco replacement material |
| NL7301732A (en) * | 1972-02-10 | 1973-08-14 | ||
| US3831609A (en) * | 1972-02-14 | 1974-08-27 | Sutton Res Corp | Smokable substitute material and smoking products thereof |
| US3934594A (en) * | 1972-03-02 | 1976-01-27 | Tamag Basel Ag | Process for the manufacture of tobacco substitute |
| US4002176A (en) * | 1972-03-02 | 1977-01-11 | Imperial Chemical Industries Limited | Tobacco based smoking material |
| GB1362613A (en) * | 1972-03-16 | 1974-08-07 | Ici Ltd | Smoking mixtures |
| US4044777A (en) * | 1972-04-20 | 1977-08-30 | Gallaher Limited | Synthetic smoking product |
| IE37524B1 (en) * | 1972-04-20 | 1977-08-17 | Gallaher Ltd | Synthetic smoking product |
| US3782393A (en) * | 1972-08-02 | 1974-01-01 | American Safety Equip | Method of making a cigarette of reduced biological damage capability |
| US4014349A (en) * | 1972-08-31 | 1977-03-29 | Imperial Chemical Industries Limited | Smoking material |
| GB1385754A (en) * | 1972-08-31 | 1975-02-26 | Ici Ltd | Manufacture of a smoking material |
| GB1398177A (en) * | 1972-12-04 | 1975-06-18 | Ici Ltd | Smoking mixtures |
| US3861401A (en) * | 1973-03-08 | 1975-01-21 | Theodore S Briskin | Smokable tobacco substitute material and method |
| FR2224099A1 (en) * | 1973-04-09 | 1974-10-31 | Gallaher Ltd | Base for synthetic tobacco - composed of carbon-contg. flexible and coherent fine fibres |
| US4019521A (en) * | 1973-06-06 | 1977-04-26 | Philip Morris Incorporated | Smokable material and method for preparing same |
| GB1445124A (en) * | 1973-07-09 | 1976-08-04 | Ici Ltd | Smoking mixtures |
| GB1445111A (en) * | 1973-07-09 | 1976-08-04 | Ici Ltd | Smoking mixture |
| US3861402A (en) * | 1973-10-23 | 1975-01-21 | Sutton Res Corp | Smokable material and method for preparation of same |
| US3964494A (en) * | 1974-10-21 | 1976-06-22 | R. J. Reynolds Tobacco Company | Compositions for smoking |
| US4111211A (en) * | 1974-05-02 | 1978-09-05 | Imperial Chemical Industries Limited | Smoking mixtures |
| US4147172A (en) * | 1974-07-16 | 1979-04-03 | Imperial Chemical Industries Limited | Smoking mixtures |
| US3978866A (en) * | 1974-09-03 | 1976-09-07 | R. J. Reynolds Tobacco Company | Smoking compositions |
| US4133317A (en) * | 1975-03-27 | 1979-01-09 | Philip Morris Incorporated | Smokable material and method for preparing same |
| US4034764A (en) * | 1975-08-15 | 1977-07-12 | Philip Morris Incorporated | Smoking material and method for its preparation |
| AU1871276A (en) * | 1975-11-11 | 1978-04-20 | Brown & Williamson Tobacco Corp | Tobacco |
| US4256126A (en) * | 1978-08-02 | 1981-03-17 | Philip Morris Incorporated | Smokable material and its method of preparation |
| GB2064296B (en) * | 1979-11-16 | 1983-06-22 | Imp Group Ltd | Cigarette or cigarette-like device which produces aerosol in smoke |
| US4474191A (en) * | 1982-09-30 | 1984-10-02 | Steiner Pierre G | Tar-free smoking devices |
| US5060676A (en) * | 1982-12-16 | 1991-10-29 | Philip Morris Incorporated | Process for making a carbon heat source and smoking article including the heat source and a flavor generator |
| DE3321960A1 (en) * | 1983-06-18 | 1984-12-20 | Maizena Gmbh, 2000 Hamburg | FLAME RESISTANT STRENGTH PRODUCT, METHOD FOR PRODUCING IT AND ITS USE |
| IE65637B1 (en) * | 1984-09-14 | 1995-11-01 | Reynolds Tobacco Co R | Smoking article |
| US4793365A (en) * | 1984-09-14 | 1988-12-27 | R. J. Reynolds Tobacco Company | Smoking article |
| US5076297A (en) * | 1986-03-14 | 1991-12-31 | R. J. Reynolds Tobacco Company | Method for preparing carbon fuel for smoking articles and product produced thereby |
| US4893639A (en) * | 1986-07-22 | 1990-01-16 | R. J. Reynolds Tobacco Company | Densified particulate materials for smoking products and process for preparing the same |
| US6637439B2 (en) | 2001-08-31 | 2003-10-28 | Philip Morris Incorporated | Tobacco smoking mixture for smoking articles such as cigarettes |
| US6817365B2 (en) * | 2001-11-15 | 2004-11-16 | Philip Morris Usa Inc. | Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles |
| US6769437B2 (en) | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
| WO2012078597A1 (en) | 2010-12-07 | 2012-06-14 | Freeman Steven R | Vegetable based tobacco alternatives and articles comprising same |
| CN203388263U (en) * | 2013-06-26 | 2014-01-15 | 刘秋明 | Electronic cigarette, electronic cigarette atomizer and electronic cigarette tip |
| GB201312501D0 (en) | 2013-07-12 | 2013-08-28 | British American Tobacco Co | Material for inclusion in a smoking article |
| HUE069731T2 (en) | 2016-12-30 | 2025-04-28 | Philip Morris Products Sa | Method of making a nicotine containing sheet |
| US11490653B2 (en) | 2017-06-23 | 2022-11-08 | Altria Client Services Llc | Smoking article |
| US10765143B2 (en) | 2017-09-14 | 2020-09-08 | Altria Client Services Llc | Smoking article with reduced tobacco |
| US12342851B2 (en) | 2017-12-08 | 2025-07-01 | Altria Client Services Llc | Smoking article with reduced tobacco |
| WO2023163715A1 (en) * | 2022-02-26 | 2023-08-31 | Big 5 Properties Inc. | Smoking product and methods of manufacture |
-
1966
- 1966-05-19 GB GB22270/66A patent/GB1113979A/en not_active Expired
-
1967
- 1967-05-10 DE DE1692921A patent/DE1692921C3/en not_active Expired
- 1967-05-10 DE DE1792740A patent/DE1792740C3/en not_active Expired
- 1967-05-11 BE BE698359D patent/BE698359A/xx unknown
- 1967-05-17 LU LU53689D patent/LU53689A1/xx unknown
- 1967-05-18 SE SE6706978A patent/SE383891B/en unknown
- 1967-05-18 NO NO168199A patent/NO116233B/no unknown
- 1967-05-18 ES ES340685A patent/ES340685A1/en not_active Expired
- 1967-05-19 NL NL676706991A patent/NL141770B/en not_active IP Right Cessation
- 1967-05-19 DK DK262567AA patent/DK127671B/en unknown
- 1967-05-19 CH CH704667A patent/CH529175A/en not_active IP Right Cessation
- 1967-09-06 ES ES344777A patent/ES344777A1/en not_active Expired
-
1969
- 1969-12-01 US US876219A patent/US3545448A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3545448A (en) | 1970-12-08 |
| NL141770B (en) | 1974-04-16 |
| DE1692921C3 (en) | 1975-03-13 |
| LU53689A1 (en) | 1967-07-17 |
| GB1113979A (en) | 1968-05-15 |
| BE698359A (en) | 1967-11-13 |
| DE1792740B2 (en) | 1974-08-22 |
| DE1692921A1 (en) | 1972-06-15 |
| CH529175A (en) | 1972-10-15 |
| DE1792740A1 (en) | 1973-05-30 |
| SE383891B (en) | 1976-04-05 |
| NL6706991A (en) | 1967-11-20 |
| NO116233B (en) | 1969-02-17 |
| DK127671B (en) | 1973-12-17 |
| ES344777A1 (en) | 1968-11-01 |
| DE1792740C3 (en) | 1975-04-10 |
| DE1692921B2 (en) | 1974-07-25 |
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