ES360237A1 - Bromoalkyl-S-Alkyl-or-Aryl-(di) Thiolphosphoric Acid Diester or Ester Amide Chlorides - Google Patents
Bromoalkyl-S-Alkyl-or-Aryl-(di) Thiolphosphoric Acid Diester or Ester Amide ChloridesInfo
- Publication number
- ES360237A1 ES360237A1 ES360237A ES360237A ES360237A1 ES 360237 A1 ES360237 A1 ES 360237A1 ES 360237 A ES360237 A ES 360237A ES 360237 A ES360237 A ES 360237A ES 360237 A1 ES360237 A1 ES 360237A1
- Authority
- ES
- Spain
- Prior art keywords
- aryl
- alkyl
- bromoalkyl
- formula
- acid diester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- -1 Ester Amide Chlorides Chemical class 0.000 title 1
- 150000005690 diesters Chemical class 0.000 title 1
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- RVEZZJVBDQCTEF-UHFFFAOYSA-N sulfenic acid Chemical compound SO RVEZZJVBDQCTEF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/26—Amides of acids of phosphorus containing P-halide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/20—Esters of thiophosphoric acids containing P-halide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Novel thiolphosphoric acid derivatives of the formula where R 1 to R 6 are hydrogen, alkyl, alkoxyalkyl or haloalkyl, R 7 is an optionally substituted aliphatic, aryl or aralkyl radical, X is oxygen or sulphur or an N-alkyl or N-aryl-amino group and n is 0 or 1, are prepared by reacting a compound of the formula with a sulphenic acid bromide of formula R 7 -S-Br, or with the reaction product of an aliphatic or aromatic mercaptan or thiophenol and bromine. The reaction is generally carried out in the presence of a solvent at a temperature between - 20 and +50 C. The products are useful intermediates.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19671668040 DE1668040C3 (en) | 1967-11-14 | 1967-11-14 | Process for the preparation of bromoalkyl-S-alkyl or aryHdi) thiolphosphoric acid diester or ester amide chlorides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES360237A1 true ES360237A1 (en) | 1970-07-01 |
Family
ID=5686047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES360237A Expired ES360237A1 (en) | 1967-11-14 | 1968-11-14 | Bromoalkyl-S-Alkyl-or-Aryl-(di) Thiolphosphoric Acid Diester or Ester Amide Chlorides |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE723771A (en) |
| CH (1) | CH507300A (en) |
| DE (1) | DE1668040B2 (en) |
| ES (1) | ES360237A1 (en) |
| FR (1) | FR1591797A (en) |
| GB (1) | GB1188430A (en) |
| IL (1) | IL30819A (en) |
| NL (1) | NL161158C (en) |
-
1967
- 1967-11-14 DE DE1967F0054029 patent/DE1668040B2/en active Granted
-
1968
- 1968-10-02 CH CH1471468A patent/CH507300A/en not_active IP Right Cessation
- 1968-10-04 IL IL30819A patent/IL30819A/en unknown
- 1968-10-23 GB GB50254/68A patent/GB1188430A/en not_active Expired
- 1968-11-13 BE BE723771D patent/BE723771A/xx unknown
- 1968-11-14 NL NL6816234.A patent/NL161158C/en not_active IP Right Cessation
- 1968-11-14 ES ES360237A patent/ES360237A1/en not_active Expired
- 1968-11-14 FR FR1591797D patent/FR1591797A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1591797A (en) | 1970-05-04 |
| DE1668040B2 (en) | 1976-12-23 |
| GB1188430A (en) | 1970-04-15 |
| BE723771A (en) | 1969-05-13 |
| IL30819A0 (en) | 1968-12-26 |
| NL161158B (en) | 1979-08-15 |
| NL161158C (en) | 1980-01-15 |
| CH507300A (en) | 1971-05-15 |
| NL6816234A (en) | 1969-05-19 |
| IL30819A (en) | 1971-12-29 |
| DE1668040A1 (en) | 1971-07-22 |
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