ES367266A1 - Poly (p-benzamide) dope - Google Patents
Poly (p-benzamide) dopeInfo
- Publication number
- ES367266A1 ES367266A1 ES367266A ES367266A ES367266A1 ES 367266 A1 ES367266 A1 ES 367266A1 ES 367266 A ES367266 A ES 367266A ES 367266 A ES367266 A ES 367266A ES 367266 A1 ES367266 A1 ES 367266A1
- Authority
- ES
- Spain
- Prior art keywords
- dope
- iii
- chloride
- acid
- pentamethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003190 poly( p-benzamide) Polymers 0.000 title 1
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- -1 wool Substances 0.000 abstract 3
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 239000012948 isocyanate Substances 0.000 abstract 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- XXUHCKAAHWJKAT-UHFFFAOYSA-N 3-phenylbenzene-1,2-disulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC(C=2C=CC=CC=2)=C1S(Cl)(=O)=O XXUHCKAAHWJKAT-UHFFFAOYSA-N 0.000 abstract 1
- VSCADKGMBQAGNC-UHFFFAOYSA-N 4-aminobenzoyl chloride;hydrochloride Chemical compound Cl.NC1=CC=C(C(Cl)=O)C=C1 VSCADKGMBQAGNC-UHFFFAOYSA-N 0.000 abstract 1
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 1
- 229910001369 Brass Inorganic materials 0.000 abstract 1
- 101100219382 Caenorhabditis elegans cah-2 gene Proteins 0.000 abstract 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 abstract 1
- 229910018068 Li 2 O Inorganic materials 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012346 acetyl chloride Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 229960004050 aminobenzoic acid Drugs 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 239000010951 brass Substances 0.000 abstract 1
- 239000011449 brick Substances 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 239000004567 concrete Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- WMPOZLHMGVKUEJ-UHFFFAOYSA-N decanedioyl dichloride Chemical compound ClC(=O)CCCCCCCCC(Cl)=O WMPOZLHMGVKUEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229920001291 polyvinyl halide Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
- Laminated Bodies (AREA)
- Artificial Filaments (AREA)
Abstract
Sheets, paper, wires, screens, fibres, fabrics, foams, or solid or microporous objects, made of glass, ceramics, bricks, concrete, Cu, Al, steel, brass, wood, cellulosic materials, wool, polyamide, polyester, polyacrylonitrile, polyolefin, polyvinyl halide, cured epoxy resin, or cured aldehyde-urea resin, are coated with a dope which consists essentially of (I) poly (pbenzamide) containing recurring units (II) LiCl or CaCl 2 , and (III) an amide or urea medium. The dope may be made mixing (I) (II) and (III) or it may be made by polymerizing in situ p-aminobenzoyl chloride hydrochloride at below 60 C, e.g. -15 to +30 C in medium (III), and adding (II) or a substance from which (II) is formed. (III) may be where R is methyl, ethyl or n-propyl, R 1 and R 2 are methyl or ethyl, R 3 is tritetra-, or pentamethylene R 4 is tetra- or pentamethylene and R 5 is di- or trimethylene. The dope contains #4 wt% (I), which is of high MW and is homopolymeric, having inherent viscosity 0.7 and peak height ratio #0.86 and #2 wt% (II), e.g. 8%. (II) may be Li 2 CO 3 , Li 2 O, LiOH, LiOH.H 2 O, LiH, CaO, Ca(OH) 2 and/or CaH 2 , which neutralizes acid by-product. In the polymerization process may be employed chain terminators, e.g. p-aminobenzoic acid, ammonia, monoamines, N, N'-dialkylethylenediamine alcohols, phenol, water, acetyl chloride, acetic, pyromellitic, or phthalic anhydride, isocyanates, di-isocyanates, phthaloyl chlorides, sebacyl chloride, biphenyldisulphonyl chloride, or dihydrazides. (I) preferably has crystallinity index <50 and particle size 1-20Ám. Also present in the dope may be H 2 O, tetrahydrofuran, dioxane, benzene, acetonitrile, acid by-product, dyes, fillers, delustrants U.V. stabilizers, or antioxidants. The dope may contain isotropic and/or anisotropic phases.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72915868A | 1968-05-15 | 1968-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES367266A1 true ES367266A1 (en) | 1971-06-16 |
Family
ID=24929826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES367266A Expired ES367266A1 (en) | 1968-05-15 | 1969-05-14 | Poly (p-benzamide) dope |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5246982B1 (en) |
| BE (1) | BE733061A (en) |
| BR (1) | BR6908824D0 (en) |
| CH (1) | CH527870A (en) |
| DE (1) | DE1924736A1 (en) |
| ES (1) | ES367266A1 (en) |
| FR (1) | FR2008569A1 (en) |
| GB (1) | GB1262002A (en) |
| LU (1) | LU58637A1 (en) |
| NL (1) | NL147460B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1810426B2 (en) * | 1968-06-12 | 1980-08-28 | E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) | Optically anisotropic mass containing aromatic polyamides |
| DE3802470A1 (en) * | 1988-01-28 | 1989-08-03 | Bayer Ag | METHOD FOR PRODUCING POLYBENZAMIDES |
| EP2395397A4 (en) * | 2009-02-03 | 2012-10-03 | Idemitsu Kosan Co | RESIST STRIPPING COMPOSITION AND METHOD OF STRIPPING RESIST USING THE SAME |
-
1969
- 1969-05-13 LU LU58637D patent/LU58637A1/xx unknown
- 1969-05-13 FR FR6915438A patent/FR2008569A1/fr not_active Withdrawn
- 1969-05-14 BE BE733061D patent/BE733061A/xx not_active IP Right Cessation
- 1969-05-14 CH CH738969A patent/CH527870A/en not_active IP Right Cessation
- 1969-05-14 BR BR20882469A patent/BR6908824D0/en unknown
- 1969-05-14 DE DE19691924736 patent/DE1924736A1/en active Pending
- 1969-05-14 JP JP3693669A patent/JPS5246982B1/ja active Pending
- 1969-05-14 ES ES367266A patent/ES367266A1/en not_active Expired
- 1969-05-14 NL NL6907458A patent/NL147460B/en not_active IP Right Cessation
- 1969-05-15 GB GB2472669A patent/GB1262002A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL147460B (en) | 1975-10-15 |
| DE1924736A1 (en) | 1969-12-11 |
| BE733061A (en) | 1969-11-14 |
| NL6907458A (en) | 1969-11-18 |
| FR2008569A1 (en) | 1970-01-23 |
| CH527870A (en) | 1972-09-15 |
| BR6908824D0 (en) | 1973-01-11 |
| LU58637A1 (en) | 1969-08-26 |
| GB1262002A (en) | 1972-02-02 |
| JPS5246982B1 (en) | 1977-11-29 |
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