ES367572A1 - New procedure for the manufacture of foam surfaces of weak power. (Machine-translation by Google Translate, not legally binding) - Google Patents
New procedure for the manufacture of foam surfaces of weak power. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES367572A1 ES367572A1 ES367572A ES367572A ES367572A1 ES 367572 A1 ES367572 A1 ES 367572A1 ES 367572 A ES367572 A ES 367572A ES 367572 A ES367572 A ES 367572A ES 367572 A1 ES367572 A1 ES 367572A1
- Authority
- ES
- Spain
- Prior art keywords
- see formula
- oxide
- amine
- translation
- manufacture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000006260 foam Substances 0.000 title 1
- 150000001412 amines Chemical class 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 238000007792 addition Methods 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 238000005187 foaming Methods 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000573 alkali metal alloy Inorganic materials 0.000 abstract 1
- 238000005262 decarbonization Methods 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Landscapes
- Catalysts (AREA)
Abstract
New procedure for the manufacture of surfactants with low foaming power corresponding to the general formulas: to) **(See formula)** b) **(See formula)** c) **(See formula)** d) **(See formula)** where: "A" indicates an ethylene group;-CH2 CH2 "B" indicates a substituted ethylene group: **(See formula)** "R" can be a methyl or ethyl group. "m" is an integer greater than 10 and less than 200. "n" is an integer greater than 20 and less than 600. Procedure characterized by the following sequence of operations: A) The starting amine undergoes a decarbonization and dehydration process based on: 1º Treatment of the amine with solid potassium hydroxide. 2nd. Settling of the aqueous layer. 3rd Distillation of the dry amine in an inert atmosphere and eventually under vacuum. Always working in an inert atmosphere and closed systems. B) On a mole of the starting amine, at a temperature between 60º-80ºC and at 0.2-2 atmospheres, as many moles of propylene or butylene oxide as there are active hydrogens are added. C) Add 0.01 - 0.2% of a catalyst consisting of a liquid alloy of alkali metals, generally sodium-potassium, and then propylene oxide, or butylene oxide or a mixture of both in proportions of 5/95 to 95/5 at temperatures between 90 and 130ºC, the addition of oxide is carried out in a unique way and eventually in a staggered way with intermediate additions of the same catalyst. D) After a further addition of the same catalyst, ethylene oxide is added under the same conditions as propylene oxide. E) The final product, nonionic with weak foaming power, is neutralized with phosphoric or nitric acids so that a 10% solution or dispersion has a pH of 7 - 7.5. (Machine-translation by Google Translate, not legally binding)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES367572A ES367572A1 (en) | 1969-05-09 | 1969-05-09 | New procedure for the manufacture of foam surfaces of weak power. (Machine-translation by Google Translate, not legally binding) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES367572A ES367572A1 (en) | 1969-05-09 | 1969-05-09 | New procedure for the manufacture of foam surfaces of weak power. (Machine-translation by Google Translate, not legally binding) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES367572A1 true ES367572A1 (en) | 1971-04-01 |
Family
ID=8452833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES367572A Expired ES367572A1 (en) | 1969-05-09 | 1969-05-09 | New procedure for the manufacture of foam surfaces of weak power. (Machine-translation by Google Translate, not legally binding) |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES367572A1 (en) |
-
1969
- 1969-05-09 ES ES367572A patent/ES367572A1/en not_active Expired
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19900228 |