ES373311A1 - A procedure for dying cellulose materials. (Machine-translation by Google Translate, not legally binding) - Google Patents
A procedure for dying cellulose materials. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES373311A1 ES373311A1 ES373311A ES373311A ES373311A1 ES 373311 A1 ES373311 A1 ES 373311A1 ES 373311 A ES373311 A ES 373311A ES 373311 A ES373311 A ES 373311A ES 373311 A1 ES373311 A1 ES 373311A1
- Authority
- ES
- Spain
- Prior art keywords
- water
- dye
- cellulosic material
- solvent
- see formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 10
- 239000001913 cellulose Substances 0.000 title abstract 4
- 229920002678 cellulose Polymers 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 4
- 239000000243 solution Substances 0.000 abstract 4
- 239000002904 solvent Substances 0.000 abstract 4
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 3
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 3
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 238000002835 absorbance Methods 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- 125000006713 (C5-C10) cycloalkyl group Chemical group 0.000 abstract 1
- JZCZNTBTAPXSPB-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethanol;hydrate Chemical compound O.OCCOCCOCCO JZCZNTBTAPXSPB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003125 aqueous solvent Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000007385 chemical modification Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 238000005108 dry cleaning Methods 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 230000009467 reduction Effects 0.000 abstract 1
- 238000006722 reduction reaction Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000012047 saturated solution Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 229920002994 synthetic fiber Polymers 0.000 abstract 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B31/00—Disazo and polyazo dyes of the type A->B->C, A->B->C->D, or the like, prepared by diazotising and coupling
- C09B31/02—Disazo dyes
- C09B31/06—Disazo dyes from a coupling component "C" containing a directive hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B31/00—Disazo and polyazo dyes of the type A->B->C, A->B->C->D, or the like, prepared by diazotising and coupling
- C09B31/02—Disazo dyes
- C09B31/04—Disazo dyes from a coupling component "C" containing a directive amino group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/908—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof using specified dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
- D06P1/922—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents hydrocarbons
- D06P1/924—Halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6033—Natural or regenerated cellulose using dispersed dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6033—Natural or regenerated cellulose using dispersed dyes
- D06P3/6041—Natural or regenerated cellulose using dispersed dyes using specified dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
- D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
- D06P3/8233—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye using dispersed dyes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Paper (AREA)
Abstract
A procedure for dyeing water-swellable cellulosic materials and combinations or mixtures thereof with synthetic materials, in which the size and flexibility of the cellulose material are increased by exposure to water, for a high use of the dye, characterized in that it consists of in: A. Contacting the water-swellable cellulosic material, or its mixtures or combinations, in any order, even simultaneously, at a temperature of 0-225ºC, with (1) water in sufficient quantity to swell the cellulosic material; (2) a colored preformed dye that does not require oxidation, reduction, hydrolysis, or other chemical modification for fixation or color development, in sufficient quantity to color the cellulosic material, a saturated boiling solution of which dye in 0.1 aqueous solution M of sodium carbonate has an optical absorbance of not more than 30, calculated from the optical absorbance determined spectrophotometrically in the solution obtained by diluting the saturated solution 10 times with a 90/10 by volume mixture of triethylene glycol dimethyl ether and water and then cooling at room temperature; and (3) a solvent in an amount sufficient to maintain the swelling of the cellulose if the water is separated and that: (a) has a solubility of at least 2.5% by weight in water at 25ºC, (b) boils above about 150ºC at atmospheric pressure, (c) is a solvent for the dye at some temperature within the range of about 0º to 225ºC and (d) respond to the formula (see formula) or **(See formula)** where n is 0 or 1; m is a positive integer; R is H, C1-8 alkyl, aralkyl or C7-15 alkaryl, (see formula), R2SO2 or **(See formula)** where R2 is C1-8 alkyl, C5-10 cycloalkyl, C7-10 aralkyl or alkaryl, C6 aryl, C10 aryl or furfuryl; R1 is -OH, -OR2, -SR2, -NHR2, -NR2 (C1-8 alkyl), -NR2 (aralkyl or C7-15 alkaryl), (see formula), -OSO2R2, - (see formula), -NH (phenyl) or -NH (naphthyl); X is the number of unmet valencies in A; and A is ROCH2CHORCH2-, -CH2CHORCH2, -CH2CHCH2-CH2C (CH2OR) 3, (-CH2) 2C (CH2OR) 2, (-CH2) 5CCH2OR, (-CH2) 4C, -CH2 (CHOR) andCH2OR, -CH2 (CHOR) yCH2- or -CH2 (CHOR) yz (-CH) zCH2-, where y is 2 is 3 or 4 and z is 0, 1, 2, 3 or 4 but not greater than u; with the proviso that at some stage during the process, the interior of the swollen cellulose is in contact with a solution of the dye in an aqueous solvent or another solvent. B. while maintaining the cellulosic material of step (A) in a swollen state, bringing it into full contact with a solution of the preformed dye with solvent or solvent-water; C. fixing said preformed dye within the cellulosic material by precipitation thereof; and D. recover the cellulosic material or its mixture or combination, in which the cellulosic material is uniformly dyed and is solid to aqueous washing and dry cleaning with organic solvents. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77880968A | 1968-11-25 | 1968-11-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES373311A1 true ES373311A1 (en) | 1972-01-01 |
Family
ID=25114445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES373311A Expired ES373311A1 (en) | 1968-11-25 | 1969-11-07 | A procedure for dying cellulose materials. (Machine-translation by Google Translate, not legally binding) |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE736946A (en) |
| BR (1) | BR7004476D0 (en) |
| CH (2) | CH586319B5 (en) |
| DE (1) | DE1811796C3 (en) |
| ES (1) | ES373311A1 (en) |
| FR (1) | FR2027549A1 (en) |
| IL (1) | IL32746A (en) |
| NL (1) | NL138764B (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2044927B2 (en) * | 1970-09-11 | 1974-10-24 | Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt | Process for fixing dyes on predominantly synthetic fibers |
| AT373930B (en) | 1975-10-29 | 1984-03-12 | Basf Ag | DYE PREPARATIONS FOR DYEING AND PRINTING CELLULOSE AND CELLULOSE-CONTAINING TEXTILE MATERIAL |
| AT350998B (en) * | 1976-03-18 | 1979-06-25 | Basf Ag | DYE PREPARATIONS FOR CELLULOSE AND CELLULOSE-CONTAINING TEXTILE MATERIAL |
| DE2618032A1 (en) * | 1976-04-24 | 1977-11-10 | Basf Ag | DYE PREPARATIONS FOR CELLULOSE OR CELLULOSIC FIBER MATERIAL |
| DE2635650C2 (en) * | 1976-08-07 | 1982-12-16 | Hoechst Ag, 6000 Frankfurt | Method and means for coloring mixed fiber textile materials made from cellulose fibers and synthetic fibers |
| DE2712969A1 (en) | 1977-03-24 | 1978-10-05 | Basf Ag | AZO DYES |
| DE2718636A1 (en) | 1977-04-27 | 1978-11-09 | Basf Ag | AZO DYES |
| DE2816505C2 (en) | 1978-04-15 | 1987-01-15 | Basf Ag, 6700 Ludwigshafen | Azo dyes with thiazole residues, their preparation and use |
| DE2752805A1 (en) | 1977-11-26 | 1979-05-31 | Basf Ag | AZO DYES |
| DE2817201A1 (en) | 1978-04-20 | 1979-10-31 | Basf Ag | AZO DYES |
| DE2831673A1 (en) | 1978-07-19 | 1980-02-07 | Basf Ag | HETEROCYCLIC COMPOUNDS |
| DE2837500A1 (en) * | 1978-08-28 | 1980-03-20 | Basf Ag | METHOD FOR COLORING CELLULOSE-CONTAINING TEXTILE MATERIAL AND NEW DYES |
| DE2842186A1 (en) | 1978-09-28 | 1980-04-10 | Basf Ag | AZO DYES |
| DE2855188A1 (en) * | 1978-12-21 | 1980-07-10 | Basf Ag | METHOD FOR COLORING AND PRINTING TEXTILES WITH DISPERSION DYES |
| DE2912428A1 (en) * | 1979-03-29 | 1980-10-09 | Basf Ag | NEW DISPERSION DYES, THEIR PRODUCTION AND USE |
| DE2929763A1 (en) | 1979-07-23 | 1981-02-19 | Basf Ag | METHOD FOR COLORING AND PRINTING CELLULOSE-CONTAINING TEXTILE MATERIAL |
| DE2930334A1 (en) | 1979-07-26 | 1981-02-19 | Basf Ag | DISAZO DYES WITH HETEROCYCLIC CLUTCH COMPONENTS |
| DE2930919A1 (en) | 1979-07-30 | 1981-02-26 | Basf Ag | METHOD FOR COLORING AND PRINTING CELLULOSE-CONTAINING TEXTILE MATERIAL |
| DE2948456A1 (en) | 1979-12-01 | 1981-06-11 | Basf Ag, 6700 Ludwigshafen | DISAZO DYES |
| DE3140521A1 (en) * | 1980-10-14 | 1982-05-27 | Basf Ag, 6700 Ludwigshafen | Liquid aqueous preparations |
| EP0099333B1 (en) | 1982-07-12 | 1986-09-24 | Sicpa Holding S.A. | Transfer sheets for the thermal dry-printing of cellulosic fibres |
| DE3325083A1 (en) * | 1983-07-12 | 1985-01-24 | Hoechst Ag, 6230 Frankfurt | STORAGE-STABLE, CARRIER-ACTIVE THICKENER DISPERSIONS |
| KR20060090805A (en) * | 2003-09-08 | 2006-08-16 | 시바 스페셜티 케미칼스 홀딩 인크. | Printing or dyeing of cellulose / polyester blend fibers |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1927144A (en) * | 1928-06-11 | 1933-09-19 | Celanese Corp | Dyeing of textile materials |
| GB482324A (en) * | 1936-03-31 | 1938-03-28 | Onderzoekings Inst Res | Improvements in or relating to the dyeing of artificial silk in the form of wound packages |
| GB760041A (en) * | 1953-12-01 | 1956-10-31 | Fontaine Converting Works Inc | Improved method of dyeing textile materials and dyed textile materials so produced |
| CH351689A (en) * | 1956-03-05 | 1961-01-31 | Ciba Geigy | Process for the preparation of solutions of azo dyes |
| FR1536737A (en) * | 1966-09-15 | 1968-08-16 | Sandoz Sa | Sparingly soluble azo dyes in water, their manufacturing process and applications |
-
1968
- 1968-11-29 CH CH1785468A patent/CH586319B5/xx not_active IP Right Cessation
- 1968-11-29 DE DE1811796A patent/DE1811796C3/en not_active Expired
- 1968-11-29 CH CH1785468D patent/CH1785468A4/xx unknown
-
1969
- 1969-07-30 IL IL32746A patent/IL32746A/en unknown
- 1969-08-01 BE BE736946D patent/BE736946A/xx not_active IP Right Cessation
- 1969-11-07 ES ES373311A patent/ES373311A1/en not_active Expired
- 1969-11-25 FR FR6940650A patent/FR2027549A1/en active Granted
- 1969-11-25 NL NL696917733A patent/NL138764B/en unknown
-
1970
- 1970-10-29 BR BR204476/70A patent/BR7004476D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6917733A (en) | 1970-05-27 |
| FR2027549A1 (en) | 1970-10-02 |
| CH586319B5 (en) | 1977-03-31 |
| IL32746A0 (en) | 1969-09-25 |
| NL138764B (en) | 1973-05-15 |
| DE1811796C3 (en) | 1974-01-03 |
| IL32746A (en) | 1972-08-30 |
| BE736946A (en) | 1970-02-02 |
| CH1785468A4 (en) | 1976-09-15 |
| DE1811796A1 (en) | 1970-08-06 |
| DE1811796B2 (en) | 1973-05-30 |
| FR2027549B1 (en) | 1973-04-06 |
| BR7004476D0 (en) | 1973-01-16 |
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