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CHIMICO FARMACEUTICO DR P BLAS
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CHIMICO FARMACEUTICO DR P BLAS
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Application filed by CHIMICO FARMACEUTICO DR P BLASfiledCriticalCHIMICO FARMACEUTICO DR P BLAS
Publication of ES408403A1publicationCriticalpatent/ES408403A1/en
Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems
(AREA)
Plural Heterocyclic Compounds
(AREA)
Quinoline Compounds
(AREA)
Abstract
Procedure for the preparation of oxolinic acid of the structural formula: **(See formula)** characterized by reacting a compound of structure (III) **(See formula)** where R = R1 = H or R and R1, together, represent the group -O-CH2-O-, with hot diethyl malonate, to obtain a compound of structure (IV) **(See formula)** which cyclizes by rapid heating to 250-260ºC, becoming a respective quinoline derivative of the structure (V) **(See formula)** which, by alkylation on the heterocyclic nitrogen with a compound taken from the group consisting of ethyl halide and an ethyl ester of an ethyl donor inorganic acid, in the presence or absence of a polar or apolar solvent, gives the respective compound of the structure (VI) **(See formula)** where R and R1 have the same meaning as before, and this compound (VI), by ambient or alkaline hydrolysis, gives the end the oxolinic acid. (Machine-translation by Google Translate, not legally binding)
ES408403A1972-07-261972-11-09Procedure for the preparation of oxolynic acid. (Machine-translation by Google Translate, not legally binding)
ExpiredES408403A1
(en)
Procedure for the preparation of 6-aminopenicilanico or 7-aminodexacetoxicefalosporanico ácidos derivados. (Machine-translation by Google Translate, not legally binding)