ES408731A1 - A procedure for the preparation of acids 7-acilamido7-metoxi-3-cefem-4-carboxilicos and their steres. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure for the preparation of acids 7-acilamido7-metoxi-3-cefem-4-carboxilicos and their steres. (Machine-translation by Google Translate, not legally binding)

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Publication number
ES408731A1
ES408731A1 ES408731A ES408731A ES408731A1 ES 408731 A1 ES408731 A1 ES 408731A1 ES 408731 A ES408731 A ES 408731A ES 408731 A ES408731 A ES 408731A ES 408731 A1 ES408731 A1 ES 408731A1
Authority
ES
Spain
Prior art keywords
hydrogen
translation
formula
preparation
legally binding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES408731A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck and Co Inc
Original Assignee
Merck and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck and Co Inc filed Critical Merck and Co Inc
Publication of ES408731A1 publication Critical patent/ES408731A1/en
Expired legal-status Critical Current

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  • Cephalosporin Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

A process for the preparation of 7-acylamido-7-methoxy-3-cephem-4-carboxylic acids and their esters, of the formula: **(See formula)** where A is hydrogen, hydroxy, azido, halogen, carbamoyloxy, N-lower alkylcarbamoyloxy, N, N-dialkyl lower) -carbamoyloxy, a tertiary amine, lower alkoxy, acyloxy or heterocyclotium; R1 is hydrogen or trichlorethyl, tert-butyl, benzoylmethyl, p-methoxybenzyl, benzyl, benzohydryl, trimethylsilyl or methoxymethyl; R2 is hydrogen, halogen, amino, guanidino, phosphono, hydroxy, tetrazolyl, carboxy, sulfo or sulfamino and R3 is phenyl, substituted phenyl, a 5- or 6-membered monocyclic heterocycle containing one or more oxygen, sulfur or nitrogen atoms in the ring, substituted heterocycles, phenylthio, heterocycle or substituted heterocyclium or cyano, the method of which is to treat a compound of the formula: **(See formula)** where A, R1, R2 and R3 are as defined above, with an alumina base or silica gel as the isomerizing agent, and optionally, separating the ester group. (Machine-translation by Google Translate, not legally binding)
ES408731A 1971-11-19 1972-11-17 A procedure for the preparation of acids 7-acilamido7-metoxi-3-cefem-4-carboxilicos and their steres. (Machine-translation by Google Translate, not legally binding) Expired ES408731A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20058771A 1971-11-19 1971-11-19

Publications (1)

Publication Number Publication Date
ES408731A1 true ES408731A1 (en) 1976-03-16

Family

ID=22742338

Family Applications (1)

Application Number Title Priority Date Filing Date
ES408731A Expired ES408731A1 (en) 1971-11-19 1972-11-17 A procedure for the preparation of acids 7-acilamido7-metoxi-3-cefem-4-carboxilicos and their steres. (Machine-translation by Google Translate, not legally binding)

Country Status (7)

Country Link
JP (1) JPS4857992A (en)
AT (1) AT321463B (en)
CS (1) CS187364B2 (en)
ES (1) ES408731A1 (en)
HU (1) HU165581B (en)
PL (1) PL84057B1 (en)
SU (1) SU450413A3 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5417755B2 (en) * 1973-11-26 1979-07-02
JPS5442999B2 (en) * 1973-12-18 1979-12-17

Also Published As

Publication number Publication date
PL84057B1 (en) 1976-02-28
JPS4857992A (en) 1973-08-14
AT321463B (en) 1975-04-10
HU165581B (en) 1974-09-28
SU450413A3 (en) 1974-11-15
CS187364B2 (en) 1979-01-31

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