ES438341A1 - Procedure for the obtaining of masses of thermoplastic molds. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for the obtaining of masses of thermoplastic molds. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES438341A1 ES438341A1 ES438341A ES438341A ES438341A1 ES 438341 A1 ES438341 A1 ES 438341A1 ES 438341 A ES438341 A ES 438341A ES 438341 A ES438341 A ES 438341A ES 438341 A1 ES438341 A1 ES 438341A1
- Authority
- ES
- Spain
- Prior art keywords
- weight
- rubber latex
- mixtures
- rubber
- translation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229920001169 thermoplastic Polymers 0.000 title 1
- 239000004416 thermosoftening plastic Substances 0.000 title 1
- 229920000126 latex Polymers 0.000 abstract 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 239000002245 particle Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- 238000005054 agglomeration Methods 0.000 abstract 2
- 230000002776 aggregation Effects 0.000 abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- -1 acryl ester Chemical class 0.000 abstract 1
- 229920006222 acrylic ester polymer Polymers 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000009757 thermoplastic moulding Methods 0.000 abstract 1
- 238000004017 vitrification Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Process for obtaining impact-resistant thermoplastic molding compositions based on polymers in the form of rubber with a vitrification temperature of less than -20º c, comprising the following steps A) polymerization of butadiene, of an acryl ester, their mixtures with one another or with up to 30% by weight of other monomers, in aqueous emulsion to a rubber latex with an average particle size (d50 value of the mass distribution) integral) less than 0.15 μ m, B) agglomerating the rubber latex and increasing the size of a part of the rubber particles so that the rubber latex has an average particle size of 0.16 to 0.45 μm (d50 value of the distribution of integral masses). C) polymerization of 20 to 90 parts by weight of styrene, acrylonitrile, methyl methacrylate or mixtures thereof, in aqueous emulsion, in the presence of 80 to 10 parts by weight of the agglomerated rubber latex, based on the solids and, in case dice, D) mixing from 10 to 60% by weight of this graft polymer with 90 to 40% by weight of a hard polymer of styrene, α-methylstyrene, methylmethacrylate, acrylonitrile, methacrylonitrile, vinyl chloride or mixtures of these monomers, Characterized in that the agglomeration is carried out at 20-90ºC by addition of an agglomeration agent based on a dispersion of acrylic ester polymer to the rubber latex. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742427960 DE2427960B1 (en) | 1974-06-10 | 1974-06-10 | Process for the production of impact-resistant thermoplastic molding compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES438341A1 true ES438341A1 (en) | 1977-01-16 |
Family
ID=5917777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES438341A Expired ES438341A1 (en) | 1974-06-10 | 1975-06-09 | Procedure for the obtaining of masses of thermoplastic molds. (Machine-translation by Google Translate, not legally binding) |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE829810A (en) |
| CA (1) | CA1056975A (en) |
| DE (1) | DE2427960B1 (en) |
| ES (1) | ES438341A1 (en) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2927572A1 (en) * | 1979-07-07 | 1981-01-22 | Basf Ag | THEMOPLASTIC MOLDS |
| DE3114875A1 (en) * | 1981-04-13 | 1982-11-04 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING IMPACT-RESISTANT THERMOPLASTIC MOLDING MATERIALS |
| DE3202370A1 (en) * | 1982-01-26 | 1983-08-04 | Basf Ag, 6700 Ludwigshafen | Thermoplastic moulding compositions |
| DE3629581A1 (en) * | 1986-08-30 | 1988-03-03 | Basf Ag | AQUEOUS BINDER DISPERSIONS FOR THE PRODUCTION OF PAINT AND COATING AGENTS |
| JPH02252766A (en) * | 1989-03-28 | 1990-10-11 | Mitsubishi Rayon Co Ltd | Thermoplastic resin composition |
| US5336720A (en) * | 1991-06-05 | 1994-08-09 | Rohm And Haas Company | Impact resistant polymers |
| DE4402394B4 (en) * | 1994-01-27 | 2005-02-10 | Basf Ag | Process for dewatering water-moist graft rubber |
| DE19802121A1 (en) | 1998-01-21 | 1999-07-22 | Basf Ag | Simple and cost-effective method for preparing polymer microsuspension, useful for the modification of molding compositions |
| DE19951648A1 (en) | 1999-10-27 | 2001-05-03 | Basf Ag | Process to reduce cold stress whitening |
| DE19960855A1 (en) * | 1999-12-16 | 2001-06-28 | Basf Ag | Process for the production of thermoplastic molding compositions |
| AU2001258252A1 (en) | 2000-03-10 | 2001-09-24 | Bayer Aktiengesellschaft | Method for agglomerating finely divided polybutadiene latices |
| DE10021565A1 (en) * | 2000-05-03 | 2001-11-22 | Basf Ag | Thermoplastic molding compounds with improved impact strength |
| DE102004006193A1 (en) * | 2004-02-06 | 2005-08-25 | Basf Ag | Thermoplastic molding compounds with improved mechanical and optical properties |
| DE102005022635B4 (en) | 2005-05-11 | 2018-05-30 | Ineos Styrolution Europe Gmbh | Thermoplastic molding compounds with improved dyeability |
| DE102005022632B4 (en) | 2005-05-11 | 2022-05-25 | Ineos Styrolution Europe Gmbh | Particulate rubber, process for its production and use, and graft copolymer, thermoplastic molding material and process for its production |
| DE102005027485A1 (en) | 2005-06-14 | 2006-12-28 | Basf Ag | Reinforced thermoplastic molding compounds |
| EP1752478A1 (en) | 2005-08-08 | 2007-02-14 | Basf Aktiengesellschaft | A process for the production of a graft copolymer having a bimodal particle distribution. |
| EP2949699A1 (en) * | 2006-08-18 | 2015-12-02 | Styrolution Europe GmbH | Process to prepare thermoplastic molding compositions based on acrylonitrile, styrene, and butadiene, comprising a thermoplastic copolymer and a grafted copolymer |
| MX2009011656A (en) | 2007-05-07 | 2009-11-10 | Basf Se | Thermoplastic molding compound with processing-independent viscosity. |
| DE102008009735A1 (en) | 2008-02-19 | 2009-08-20 | Basf Se | Device for extruding molding compounds |
| US8501868B2 (en) | 2010-03-26 | 2013-08-06 | Styrolution GmbH | Thermoplastic molding compositions with improved optical properties |
| KR102179363B1 (en) | 2013-04-18 | 2020-11-18 | 이네오스 스티롤루션 그룹 게엠베하 | Thermoplastic moulding materials based on acrylonitrile, styrene and butadiene |
| US9624333B2 (en) | 2013-04-18 | 2017-04-18 | Ineos Styrolution Group Gmbh | Thermoplastic moulding materials based on acrylonitrile, styrene and butadiene |
| ES2713635T3 (en) * | 2013-07-02 | 2019-05-23 | Ineos Styrolution Group Gmbh | Process for the manufacture of ABS molding compositions |
| WO2015004112A1 (en) | 2013-07-11 | 2015-01-15 | Styrolution Group Gmbh | Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto |
| RU2017100916A (en) | 2014-06-13 | 2018-07-16 | ЮЭмДжи ЭйБиЭс, ЛТД. | COMPOSITION OF THERMOPLASTIC RESIN AND FORMED PRODUCT FROM IT |
| EP3265496B1 (en) | 2015-03-05 | 2022-02-16 | INEOS Styrolution Group GmbH | Efficient copolymers having an agglomerating effect |
| KR102840793B1 (en) | 2018-05-18 | 2025-07-31 | 이네오스 스티롤루션 그룹 게엠베하 | Extrusion method for producing a thermoplastic molding compound, and apparatus for performing such method |
| KR102490390B1 (en) | 2019-04-29 | 2023-01-19 | 주식회사 엘지화학 | Polymer Coagulant and Graft Copolymer Comprising the Same |
| MX2023009262A (en) | 2021-02-16 | 2023-10-16 | Ineos Styrolution Group Gmbh | Process for producing a thermoplastic moulding compound comprising a thermoplastic copolymer a and a graft copolymer b. |
| CN117715976A (en) | 2021-04-30 | 2024-03-15 | 英力士苯领集团股份公司 | Improved process for producing thermoplastic ABS moulding compositions |
| KR20240006565A (en) | 2021-04-30 | 2024-01-15 | 이네오스 스티롤루션 그룹 게엠베하 | Improved process for producing thermoplastic ABS molding compositions |
| CN118525054A (en) | 2021-11-12 | 2024-08-20 | 英力士苯领集团股份公司 | Thermoplastic ABS molding compositions with improved surface properties |
| WO2023222674A1 (en) | 2022-05-18 | 2023-11-23 | Ineos Styrolution Group Gmbh | Method to improve surface gloss stability of acrylonitrile-butadiene-styrene copolymer compositions |
| WO2025215148A1 (en) | 2024-04-11 | 2025-10-16 | Ineos Styrolution Group Gmbh | Process for the preparation of abs graft copolymers and abs molding compositions therefrom with improved gloss stability |
-
1974
- 1974-06-10 DE DE19742427960 patent/DE2427960B1/en not_active Ceased
-
1975
- 1975-05-15 CA CA227,020A patent/CA1056975A/en not_active Expired
- 1975-06-03 BE BE156978A patent/BE829810A/en not_active IP Right Cessation
- 1975-06-09 ES ES438341A patent/ES438341A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE829810A (en) | 1975-12-03 |
| DE2427960B1 (en) | 1975-06-19 |
| CA1056975A (en) | 1979-06-19 |
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