ES450723A1 - 3,4-diphenyl-1,2,5,6-tetrahydrobenzoic acid derivatives - Google Patents

3,4-diphenyl-1,2,5,6-tetrahydrobenzoic acid derivatives

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Publication number
ES450723A1
ES450723A1 ES450723A ES450723A ES450723A1 ES 450723 A1 ES450723 A1 ES 450723A1 ES 450723 A ES450723 A ES 450723A ES 450723 A ES450723 A ES 450723A ES 450723 A1 ES450723 A1 ES 450723A1
Authority
ES
Spain
Prior art keywords
alkyl
radical
formula
halogen
alkoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES450723A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1066675A external-priority patent/CH617423A5/en
Priority claimed from CH1066475A external-priority patent/CH617418A5/en
Priority claimed from CH1066575A external-priority patent/CH617421A5/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES450723A1 publication Critical patent/ES450723A1/en
Expired legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30Oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/56Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups bound to carbon atoms of six-membered aromatic rings and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16Unsaturated compounds
    • C07C61/39Unsaturated compounds containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16Unsaturated compounds
    • C07C61/40Unsaturated compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C62/00Compounds having carboxyl groups bound to carbon atoms of rings other than six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C62/30Unsaturated compounds
    • C07C62/34Unsaturated compounds containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40Oxygen atoms
    • C07D211/44Oxygen atoms attached in position 4
    • C07D211/46Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/084Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/088Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12Radicals substituted by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06Radicals substituted by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/08Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D309/10Oxygen atoms
    • C07D309/12Oxygen atoms only hydrogen atoms and one oxygen atom directly attached to ring carbon atoms, e.g. tetrahydropyranyl ethers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/14Radicals substituted by singly bound hetero atoms other than halogen
    • C07D333/16Radicals substituted by singly bound hetero atoms other than halogen by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Procedure for the preparation of a 1,2-diphenyl-cyclohex-l-en-4-carboxylic acid derivative of the formula I **(See formula)** in which U, V, W, X, Y and Z stand for, independently of one another, hydrogen, halogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, NO2, CF3, COOH, CN, OH, S03H, NH2, -NH (< C1-C4 alkyl) or -N (C1-C4 alkyl) 2, although U and X may each additionally signify an unsubstituted phenyl radical, and represents one of the two groups - OR ° or -SR, where R ° means - hydrogen or - the cation of a base **(See formula)** in which M represents an alkaline, alkaline earth cation of Fe, Cu, Zn, Mn or Ni or an ammonium radical **(See formula)** and takes into account, as an integer 1, 2 or 3, the valence of the cation, while R2, R3 and R4 independently of one another they represent hydrogen, benzyl or a radical (optionally substituted by -OH, -NH2 or C1-C4 alkoxy) of C1-C8 alkyl O well - represent; and R means: - a C1-C18 alkyl radical, unsubstituted or possibly substituted by halogen, by nitro, by cyano, by C1-C8 alkoxy, by C2-C8 alkoxyalkyl, by C3-C6 alkenyloxy, by C1- alkylthio C8, by C2-C8 alkanoyl, by C2-C8 acyloxy, by C2-C8 alkoxycarbonyl or by carbamoyl; bis- (C2-C8-alkyl-amino, tris- (C1-C4-alkyl) -ammonium, C3-C8-cycloalkyl, C3-C8-cycloalkenyl or optionally also by a radical (unsubstituted or uni- or pluri-substituted by in turn by halogen, by C1-C4 alkyl or by C1-C4 alkoxy) phenyl, phenoxy or heterocyclic pentagonal or hexagonal with 1 to 3 heteroatoms; - an unsubstituted C3-C18 alkenyl radical, or substituted one to four times by halogen or once by phenyl or methoxycarbonyl; - a C3-C8 alkynyl radical; - a C3-C12 cycloalkyl radical, optionally substituted by halogen or by C1-C4 alkyl; - a C3-C8 cycloalkenyl radical; - a phenyl radical, unsubstituted or substituted by halogen, by C1-C4 alkyl, by C1-C4 alkoxy, by C1-C4 alkylthio, by NO2, by CF3, by COOH, by CN, by OH, by S03H, by NH2, by -NH (C1-C4 alkyl) or by -N (C1-C4 alkyl) 2 one or more times; - or a pentagonal to hexagonal heterocyclic ring with 1 to 3 heteroatoms, which constitutes the active component, for together with appropriate vehicle materials, the formation of agents to influence the growth of plants, characterized in that in their performance a reaction is verified addition of acrylonitrile or an acrylic acid derivative of formula II **(See formula)** in which G has the same meaning as for formula I, to a diene of formula III **(See formula)** optionally formed as an intermediate compound from a diol of formula IIIa **(See formula)** and consecutive transformation, in the usual way, of the nitrile group introduced by using acrylonitrile in the carboxylic group or the ester group -CO-G according to the definition above. (Machine-translation by Google Translate, not legally binding)
ES450723A 1975-08-15 1976-08-14 3,4-diphenyl-1,2,5,6-tetrahydrobenzoic acid derivatives Expired ES450723A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH1066675A CH617423A5 (en) 1975-08-15 1975-08-15 Plant growth regulator.
CH1066475A CH617418A5 (en) 1975-08-15 1975-08-15 Plant growth regulators.
CH1066575A CH617421A5 (en) 1975-08-15 1975-08-15 Plant growth-regulating composition

Publications (1)

Publication Number Publication Date
ES450723A1 true ES450723A1 (en) 1977-12-01

Family

ID=27176486

Family Applications (1)

Application Number Title Priority Date Filing Date
ES450723A Expired ES450723A1 (en) 1975-08-15 1976-08-14 3,4-diphenyl-1,2,5,6-tetrahydrobenzoic acid derivatives

Country Status (19)

Country Link
JP (1) JPS5223050A (en)
AT (1) AT344752B (en)
AU (1) AU507074B2 (en)
BG (1) BG27357A3 (en)
BR (1) BR7605355A (en)
CA (1) CA1069913A (en)
CS (1) CS189595B2 (en)
DD (1) DD127675A5 (en)
DE (1) DE2636389A1 (en)
DK (1) DK367976A (en)
ES (1) ES450723A1 (en)
FR (1) FR2320700A1 (en)
GB (1) GB1539091A (en)
GR (1) GR60796B (en)
IE (1) IE44291B1 (en)
IL (1) IL50231A (en)
LU (1) LU75586A1 (en)
NL (1) NL7609063A (en)
TR (1) TR19118A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5557007A (en) * 1990-09-28 1996-09-17 Union Carbide Chemicals & Plastics Technology Corporation Unsaturated polylactone acrylates and derivatives thereof

Also Published As

Publication number Publication date
LU75586A1 (en) 1977-04-22
JPS5223050A (en) 1977-02-21
CS189595B2 (en) 1979-04-30
IL50231A (en) 1981-02-27
BR7605355A (en) 1977-08-16
GR60796B (en) 1978-08-30
ATA603676A (en) 1977-12-15
BG27357A3 (en) 1979-10-12
DD127675A5 (en) 1977-10-05
AU1683476A (en) 1978-02-16
GB1539091A (en) 1979-01-24
AT344752B (en) 1978-08-10
FR2320700B1 (en) 1979-09-28
DK367976A (en) 1977-02-16
CA1069913A (en) 1980-01-15
IL50231A0 (en) 1976-10-31
TR19118A (en) 1978-07-01
IE44291B1 (en) 1981-10-07
IE44291L (en) 1977-02-15
FR2320700A1 (en) 1977-03-11
AU507074B2 (en) 1980-01-31
NL7609063A (en) 1977-02-17
DE2636389A1 (en) 1977-02-24

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