ES465738A1 - Un procedimiento para la produccion de alquilbencenos nucle-ares clorados. - Google Patents
Un procedimiento para la produccion de alquilbencenos nucle-ares clorados.Info
- Publication number
- ES465738A1 ES465738A1 ES465738A ES465738A ES465738A1 ES 465738 A1 ES465738 A1 ES 465738A1 ES 465738 A ES465738 A ES 465738A ES 465738 A ES465738 A ES 465738A ES 465738 A1 ES465738 A1 ES 465738A1
- Authority
- ES
- Spain
- Prior art keywords
- electron
- donating
- substituents
- present
- substituent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004996 alkyl benzenes Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000005660 chlorination reaction Methods 0.000 title 1
- 125000001424 substituent group Chemical group 0.000 abstract 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000011968 lewis acid catalyst Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 thianthrene compound Chemical class 0.000 abstract 1
- 150000005029 thianthrenes Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
- C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para la producción de alquilbencenos clorados en el núcleo que consiste en hacer reaccionar, en fase líquida, un alquilbenceno con cloro, en presencia de un catalizador ácido de Lewis y de un cocatalizador constituido por un compuesto de tiantreno o una mezcla de compuestos de tiantreno, caracterizados por la fórmula: **(Fórmula)** donde n es 0 o 1, y- es un sustituyente aceptor de electrones o un sustituyente donador de electrones y cada símbolo x es hidrógeno, un sustituyente aceptor de electrones o un sustituyente donador de electrones; el número total de sustituyentes aceptores de electrones presente en las posiciones x- e y- es como mínimo 1 y como máximo 7; el número total de sustituyentes donadores de electrones es como mínimo 1 y como máximo 4; no hay más de 3 sustituyentes donadores de electrones en las posiciones peri y con la condición de que cuando los sustituyentes aceptores de electrones se encuentran en cada una de las posiciones peri, los sustituyentes donadores de electrones están en cada una de las posiciones 2, 3, 7 y 8.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/756,449 US4069263A (en) | 1977-01-03 | 1977-01-03 | Process for directed chlorination of alkylbenzenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES465738A1 true ES465738A1 (es) | 1979-05-01 |
Family
ID=25043537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES465738A Expired ES465738A1 (es) | 1977-01-03 | 1978-01-03 | Un procedimiento para la produccion de alquilbencenos nucle-ares clorados. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4069263A (es) |
| JP (1) | JPS5387323A (es) |
| BE (1) | BE862360A (es) |
| BR (1) | BR7708666A (es) |
| CA (1) | CA1109081A (es) |
| DE (1) | DE2800175C3 (es) |
| ES (1) | ES465738A1 (es) |
| FR (1) | FR2376104A1 (es) |
| GB (1) | GB1576572A (es) |
| IL (1) | IL53655A0 (es) |
| IT (1) | IT1143795B (es) |
| NL (1) | NL7714627A (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4190609A (en) * | 1976-10-04 | 1980-02-26 | Hooker Chemicals & Plastics Corp. | Process for the directed chlorination of xylenes |
| US4289916A (en) * | 1979-06-28 | 1981-09-15 | Ihara Chemical Industry Co., Ltd. | Process for producing p-chloroalkylbenzene |
| US4250122A (en) * | 1979-09-07 | 1981-02-10 | Hooker Chemicals & Plastics Corp. | Process and catalyst mixture for the para-directed chlorination of alkylbenzenes |
| US4495036A (en) * | 1983-07-11 | 1985-01-22 | The Dow Chemical Company | Electrochemical chlorination process |
| DE3432095A1 (de) * | 1984-08-31 | 1986-03-06 | Hoechst Ag, 6230 Frankfurt | Verfahren zur kernchlorierung von toluol |
| DE3718060A1 (de) * | 1987-05-28 | 1988-12-08 | Bayer Ag | Verfahren zur kernchlorierung von aromatischen kohlenwasserstoffen |
| DE3916664A1 (de) * | 1989-05-23 | 1991-01-03 | Bayer Ag | Verfahren zur herstellung von 2-chlor-4-nitro-alkylbenzol |
| US5621153A (en) * | 1995-04-21 | 1997-04-15 | Occidental Chemical Corporation | Process for the preparation of chloro-alkylbenzenes and novel cocatalysts therefor |
| CN104844587B (zh) * | 2015-04-29 | 2018-06-01 | 深圳市华星光电技术有限公司 | 含有吩恶噻结构的共轭化合物及其制备方法与有机电致发光二极管器件 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1741305A (en) * | 1926-02-04 | 1929-12-31 | Selden Co | Purification of aromatic hydrocarbons |
| US1946040A (en) * | 1931-10-01 | 1934-02-06 | Dow Chemical Co | Catalyst for the nuclear chlorination of benzene compounds and method of using same |
| US3226447A (en) * | 1960-12-22 | 1965-12-28 | Union Carbide Australia | Directed nuclear substitution-chlorination of aromatic hydrocarbons and halogenated aromatic hydrocarbons |
| US3920757A (en) * | 1971-08-25 | 1975-11-18 | Dow Chemical Co | Chlorination with sulfuryl chloride |
| US4024198A (en) * | 1975-08-01 | 1977-05-17 | Hooker Chemicals & Plastics Corporation | Process for the chlorination of toluene |
| US4031142A (en) * | 1975-08-01 | 1977-06-21 | Hooker Chemicals & Plastics Corporation | Process for the directed chlorination of alkylbenzenes |
| US4031147A (en) * | 1975-08-01 | 1977-06-21 | Hooker Chemicals & Plastics Corporation | Process for directed chlorination of alkylbenzenes |
| US4013147A (en) * | 1975-09-02 | 1977-03-22 | The Bendix Corporation | Segmented friction disc for brakes |
| US4013142A (en) * | 1975-10-07 | 1977-03-22 | Westinghouse Electric Corporation | Elevator system having a drive sheave with rigid but circumferentially compliant cable grooves |
| US4069264A (en) * | 1976-10-04 | 1978-01-17 | Hooker Chemicals & Plastics Corporation | Process for directed chlorination of alkylbenzenes |
-
1977
- 1977-01-03 US US05/756,449 patent/US4069263A/en not_active Expired - Lifetime
- 1977-12-20 IL IL53655A patent/IL53655A0/xx not_active IP Right Cessation
- 1977-12-23 FR FR7738986A patent/FR2376104A1/fr active Granted
- 1977-12-27 BE BE183879A patent/BE862360A/xx not_active IP Right Cessation
- 1977-12-27 BR BR7708666A patent/BR7708666A/pt unknown
- 1977-12-28 JP JP16097577A patent/JPS5387323A/ja active Granted
- 1977-12-29 IT IT31390/77A patent/IT1143795B/it active
- 1977-12-31 NL NL7714627A patent/NL7714627A/xx not_active Application Discontinuation
-
1978
- 1978-01-03 CA CA294,264A patent/CA1109081A/en not_active Expired
- 1978-01-03 DE DE2800175A patent/DE2800175C3/de not_active Expired
- 1978-01-03 GB GB64/78A patent/GB1576572A/en not_active Expired
- 1978-01-03 ES ES465738A patent/ES465738A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7714627A (nl) | 1978-07-05 |
| JPS5387323A (en) | 1978-08-01 |
| DE2800175B2 (de) | 1980-07-24 |
| FR2376104A1 (fr) | 1978-07-28 |
| CA1109081A (en) | 1981-09-15 |
| US4069263A (en) | 1978-01-17 |
| IT1143795B (it) | 1986-10-22 |
| DE2800175A1 (de) | 1978-07-20 |
| BE862360A (fr) | 1978-06-27 |
| JPS6236014B2 (es) | 1987-08-05 |
| FR2376104B1 (es) | 1984-01-20 |
| IL53655A0 (en) | 1978-03-10 |
| DE2800175C3 (de) | 1981-12-17 |
| BR7708666A (pt) | 1978-08-29 |
| GB1576572A (en) | 1980-10-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19980202 |