ES471398A1 - Substituted 3-(2'-nitro phenoxy)-alpha-phenoxy alcanoic acids and their derivatives, their preparation and their use as herbicides. - Google Patents
Substituted 3-(2'-nitro phenoxy)-alpha-phenoxy alcanoic acids and their derivatives, their preparation and their use as herbicides.Info
- Publication number
- ES471398A1 ES471398A1 ES471398A ES471398A ES471398A1 ES 471398 A1 ES471398 A1 ES 471398A1 ES 471398 A ES471398 A ES 471398A ES 471398 A ES471398 A ES 471398A ES 471398 A1 ES471398 A1 ES 471398A1
- Authority
- ES
- Spain
- Prior art keywords
- radical
- substituted
- halogen
- cyano
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 150000007513 acids Chemical class 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- -1 alkaline earth metal cation Chemical class 0.000 abstract 12
- 229910052736 halogen Inorganic materials 0.000 abstract 9
- 125000005843 halogen group Chemical group 0.000 abstract 9
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 8
- 239000001257 hydrogen Substances 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 4
- 239000001301 oxygen Substances 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 239000005864 Sulphur Substances 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- 150000002431 hydrogen Chemical group 0.000 abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 3
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000005277 alkyl imino group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000001841 imino group Chemical group [H]N=* 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 150000003254 radicals Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/39—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by esterified hydroxy groups
- C07C205/42—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by esterified hydroxy groups having nitro groups or esterified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C205/43—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by esterified hydroxy groups having nitro groups or esterified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
- C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
- C07C205/38—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. nitrodiphenyl ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C327/00—Thiocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1. A 3-(2'-nitrophenoxy)-alpha-phenoxyalkanecarboxylic acid derivative of the general formula I see diagramm : EP0000474,P15,F3 wherein R1 represents hydrogen, C1 -C4 alkyl or C2 -C8 alkoxyalkyl, R2 represents hydrogen or C1 -C4 alkyl, R3 represents halogen, cyano or nitro, R4 represents halogen, cyano or trifluoromethyl, A represents cyano or the group -COB, B represents a radical OR5 , SR6 or NR7 R8 , R5 represents hydrogen or the cation of a base 1/n M**n (anion), wherein M represents an alkali metal or alkaline earth metal cation or an ammonium radical see diagramm : EP0000474,P15,F4 n as integer 1, 2 or 3 corresponds to the valency of the cation, whilst Ra , Rb , Rc and Rd , each independently of the other, represent hydrogen, benzyl or an alkyl radical which is unsubstituted or substituted by -OH, -NH2 or C1 -C4 alkoxy and R5 further represents, a C1 -C8 alkyl radical which can be unsubstituted or substituted by halogen, cyano, nitro, hydroxyl or a 5- to 6-membered nitrogen-containing heterocyclic ring system, and a C2 -C8 alkyl radical which can be interrupted by oxygen, sulphur, nitrogen, carbonyl or carbonyloxy, a C3 -C6 cycloalkyl radical, a C3 -C6 alkenyl or alkynyl radical which can be substituted by halogen, a phenyl or benzyl radical which can be substituted by halogen, cyano, nitro, C1 -C4 alkyl, C1 -C4 alkoxy or trifluoromethyl, R6 represents a C1 -C8 alkyl radical which can be substituted by halogen, cyano, nitro or hydroxyl or interrupted by oxygen, sulphur, nitrogen, carbonyl or carbonyloxy, a C3 -C6 cycloalkyl radical, a C3 -C6 alkenyl or alkynyl radical which can be substituted by halogen, a phenyl or benzyl radical which can be substituted by halogen, cyano, nitro, C1 -C4 alkyl, C1 -C4 alkoxy or trifluoromethyl, R7 represents hydrogen, a C1 -C8 alkyl radical which can be substituted by halogen, cyano or hydroxyl, and a C2 -C8 alkyl radical which can be interrupted by oxygen, R8 represents a C1 -C4 alkyl radical or a C3 -C4 alkyl radical, and R7 and R8 , together with the nitrogen atom to which they are attached, also represent a 5- to 6-membered heterocyclic radical which can be interrupted by oxygen, sulphur, an imino, C1 -C4 alkylimino or phenylimino group.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH806877 | 1977-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES471398A1 true ES471398A1 (en) | 1979-02-01 |
Family
ID=4334639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES471398A Expired ES471398A1 (en) | 1977-06-30 | 1978-06-29 | Substituted 3-(2'-nitro phenoxy)-alpha-phenoxy alcanoic acids and their derivatives, their preparation and their use as herbicides. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0000474B1 (en) |
| JP (1) | JPS5416436A (en) |
| CA (1) | CA1090367A (en) |
| DE (1) | DE2860339D1 (en) |
| ES (1) | ES471398A1 (en) |
| IL (1) | IL55029A (en) |
| IT (1) | IT7825138A0 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2850902A1 (en) * | 1978-11-24 | 1980-06-12 | Hoechst Ag | NEW PHENOXY-PHENOXI-PROPIONIC ACID AMIDES AND THEIR USE AS HERBICIDES |
| US4309210A (en) * | 1978-12-01 | 1982-01-05 | Ciba-Geigy Corporation | Preemergence method of selectively controlling weeds in crops of cereals and composition therefor |
| EP0078536A3 (en) * | 1981-11-02 | 1983-07-27 | Sandoz Ag | Phosphinates and phosphonates and their use in the control of weeds |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1560416A (en) * | 1975-09-03 | 1980-02-06 | Rohm & Haas | Trifluoromethylphenyl derivatives |
| NZ181994A (en) * | 1975-09-27 | 1978-09-20 | Ishihara Sangyo Kaisha | (2-chloro-4-trifluorom-ethylphenoxy)-phenoxy acids,esters,ethers,amides and nitriles and herbicidal compositions |
| GB1565972A (en) * | 1976-04-15 | 1980-04-23 | Sori Soc Rech Ind | M-substituted phenoxypropionic acid dervatives |
| DE2632581C2 (en) * | 1976-07-20 | 1982-07-15 | Hoechst Ag, 6000 Frankfurt | Substituted nitrodiphenyl ethers, processes for their preparation and herbicidal compositions containing them |
| AU2716177A (en) * | 1976-07-21 | 1979-01-25 | Ciba Geigy Ag | Herbicides |
-
1978
- 1978-06-22 EP EP78100218A patent/EP0000474B1/en not_active Expired
- 1978-06-22 DE DE7878100218T patent/DE2860339D1/en not_active Expired
- 1978-06-28 IL IL55029A patent/IL55029A/en unknown
- 1978-06-28 CA CA306,425A patent/CA1090367A/en not_active Expired
- 1978-06-29 IT IT7825138A patent/IT7825138A0/en unknown
- 1978-06-29 ES ES471398A patent/ES471398A1/en not_active Expired
- 1978-06-30 JP JP8044678A patent/JPS5416436A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IT7825138A0 (en) | 1978-06-29 |
| JPS5416436A (en) | 1979-02-07 |
| IL55029A0 (en) | 1978-08-31 |
| DE2860339D1 (en) | 1981-02-12 |
| EP0000474B1 (en) | 1980-11-26 |
| EP0000474A1 (en) | 1979-02-07 |
| IL55029A (en) | 1982-09-30 |
| CA1090367A (en) | 1980-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19991102 |