ES471694A1 - Process for the recovery of gallium from very basic solutions by liquid/liquid extraction. - Google Patents
Process for the recovery of gallium from very basic solutions by liquid/liquid extraction.Info
- Publication number
- ES471694A1 ES471694A1 ES471694A ES471694A ES471694A1 ES 471694 A1 ES471694 A1 ES 471694A1 ES 471694 A ES471694 A ES 471694A ES 471694 A ES471694 A ES 471694A ES 471694 A1 ES471694 A1 ES 471694A1
- Authority
- ES
- Spain
- Prior art keywords
- liquid
- gallium
- recovery
- basic solutions
- liquid extraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 title abstract 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000605 extraction Methods 0.000 title abstract 2
- 229910052733 gallium Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003637 basic solution Substances 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- 239000007864 aqueous solution Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical class C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1. Process for the liquid/liquid extraction of gallium contained in basic aqueous solutions, by bringing the aqueous solution into contact with an organic phase mainly containing an organic solvent and at least one substituted hydroxyquinoline having the formula see diagramm : EP0000457,P9,F2 in which R1 , R2 , R3 , R4 , R5 and R6 , which are identical or different, are chosen from amongst the group comprising hydrogen and alkyl, alkenyl, cycloaliphatic and aromatic radicals, it being impossible for R1 , R2 , R3 , R4 , R5 and R6 to represent H simultaneously, characterised in that the reaction is carried out under an inert atmosphere.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7721607A FR2397464A2 (en) | 1977-07-13 | 1977-07-13 | PROCESS FOR RECOVERING GALLIUM FROM VERY BASIC SOLUTIONS BY LIQUID / LIQUID EXTRACTION |
| KR7803585A KR810001297B1 (en) | 1977-07-13 | 1978-12-07 | Gallium Extraction Method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES471694A1 true ES471694A1 (en) | 1979-10-01 |
Family
ID=26220127
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES471694A Expired ES471694A1 (en) | 1977-07-13 | 1978-07-13 | Process for the recovery of gallium from very basic solutions by liquid/liquid extraction. |
| ES479022A Expired ES479022A1 (en) | 1977-07-13 | 1979-03-28 | PROCEDURE FOR THE RECOVERY OF THE VERY BASIC AQUO-SAS SOLUTIONS GALIUM BY LIQUID-LIQUID EXTRACTION. |
| ES479023A Expired ES479023A1 (en) | 1977-07-13 | 1979-03-28 | PROCEDURE FOR THE RECOVERY OF THE VERY BASIC AQUO-SAS SOLUTIONS GALIUM BY LIQUID-LIQUID EXTRACTION. |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES479022A Expired ES479022A1 (en) | 1977-07-13 | 1979-03-28 | PROCEDURE FOR THE RECOVERY OF THE VERY BASIC AQUO-SAS SOLUTIONS GALIUM BY LIQUID-LIQUID EXTRACTION. |
| ES479023A Expired ES479023A1 (en) | 1977-07-13 | 1979-03-28 | PROCEDURE FOR THE RECOVERY OF THE VERY BASIC AQUO-SAS SOLUTIONS GALIUM BY LIQUID-LIQUID EXTRACTION. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0000457B1 (en) |
| JP (1) | JPS5440212A (en) |
| KR (1) | KR810001297B1 (en) |
| AU (1) | AU517726B2 (en) |
| CA (1) | CA1117767A (en) |
| ES (3) | ES471694A1 (en) |
| FI (1) | FI68087C (en) |
| FR (1) | FR2397464A2 (en) |
| GR (1) | GR66020B (en) |
| IT (1) | IT1105093B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2460276A1 (en) * | 1979-07-03 | 1981-01-23 | Rhone Poulenc Ind | PROCESS FOR TREATING RARE EARTH OXIDES AND GALLIUM MIXTURES |
| FR2532296B1 (en) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | PROCESS FOR THE EXTRACTION OF GALLIUM USING SUBSTITUTED HYDROXYQUINOLEINS AND ORGANOPHOSPHORUS COMPOUNDS |
| SE8206378L (en) * | 1982-11-10 | 1984-05-11 | Sverker Hogberg | NEW CHELATING CINOLIC SOCIETY COMPOUNDS |
| SE8206377A0 (en) * | 1982-11-10 | 1984-05-11 | Madan Khorshed | New chelating biskinoline compounds |
| CH655710A5 (en) * | 1983-11-17 | 1986-05-15 | Sulzer Ag | METHOD FOR LIQUID-LIQUID EXTRACTION OF GALLIUM FROM SODIUM ALUMINATE SOLUTION WITH THE AID OF AN ORGANIC EXTRACTION AGENT. |
| CH656643A5 (en) * | 1983-11-29 | 1986-07-15 | Sulzer Ag | METHOD FOR THE LIQUID-LIQUID EXTRACTION OF GALLIUM FROM BASIC, AQUEOUS SOLUTIONS BY MEANS OF AN ORGANIC EXTRACTION AGENT. |
| DE3508041A1 (en) * | 1985-03-07 | 1986-09-11 | Preussag Ag Metall, 3380 Goslar | METHOD FOR LIQUID-LIQUID EXTRACTION OF GALLIUM, GERMANIUM OR INDIUM FROM AQUEOUS SOLUTIONS |
| NO158028C (en) * | 1985-12-16 | 1988-06-29 | Elkem As | GALLIUM EXTRACTION. |
| JPH01117370U (en) * | 1988-01-29 | 1989-08-08 | ||
| US5016092A (en) * | 1989-11-17 | 1991-05-14 | Rca Licensing Corporation | Control circuitry for an adaptive multistandard video comb filter |
| FR2670803B1 (en) * | 1990-12-19 | 1993-03-19 | Rhone Poulenc Chimie | PROCESS FOR THE EXTRACTION OF GALLIUM WITH SUBSTITUTED HYDROXYQUINOLEIN. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR952976A (en) * | 1947-08-25 | 1949-11-28 | Alais & Froges & Camarque Cie | Process for extracting gallin from aluminous products |
| US3214239A (en) * | 1962-07-02 | 1965-10-26 | Kerr Mc Gee Oil Ind Inc | Recovery of metal values from aqueous solution by solvent extraction with an organo phosphorus extractant |
| US3971843A (en) * | 1974-07-12 | 1976-07-27 | Rhone-Poulenc Industries | Process for liquid/liquid extraction of gallium |
-
1977
- 1977-07-13 FR FR7721607A patent/FR2397464A2/en active Granted
-
1978
- 1978-06-27 EP EP78400035A patent/EP0000457B1/en not_active Expired
- 1978-07-10 JP JP8389378A patent/JPS5440212A/en active Granted
- 1978-07-11 GR GR56752A patent/GR66020B/el unknown
- 1978-07-11 FI FI782222A patent/FI68087C/en not_active IP Right Cessation
- 1978-07-12 IT IT50271/78A patent/IT1105093B/en active
- 1978-07-12 CA CA000307275A patent/CA1117767A/en not_active Expired
- 1978-07-12 AU AU37963/78A patent/AU517726B2/en not_active Expired
- 1978-07-13 ES ES471694A patent/ES471694A1/en not_active Expired
- 1978-12-07 KR KR7803585A patent/KR810001297B1/en not_active Expired
-
1979
- 1979-03-28 ES ES479022A patent/ES479022A1/en not_active Expired
- 1979-03-28 ES ES479023A patent/ES479023A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0000457B1 (en) | 1982-06-02 |
| AU3796378A (en) | 1980-01-17 |
| CA1117767A (en) | 1982-02-09 |
| JPS5440212A (en) | 1979-03-29 |
| ES479023A1 (en) | 1979-07-01 |
| JPS6242851B2 (en) | 1987-09-10 |
| FI68087B (en) | 1985-03-29 |
| KR810001297B1 (en) | 1981-10-13 |
| IT1105093B (en) | 1985-10-28 |
| AU517726B2 (en) | 1981-08-20 |
| IT7850271A0 (en) | 1978-07-12 |
| FI68087C (en) | 1985-07-10 |
| FR2397464A2 (en) | 1979-02-09 |
| FR2397464B2 (en) | 1980-01-18 |
| EP0000457A1 (en) | 1979-01-24 |
| GR66020B (en) | 1981-01-13 |
| FI782222A7 (en) | 1979-01-14 |
| ES479022A1 (en) | 1979-07-01 |
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