ES481113A1 - Un procedimiento para electrodepositar rodio sobre una pin- za. - Google Patents
Un procedimiento para electrodepositar rodio sobre una pin- za.Info
- Publication number
- ES481113A1 ES481113A1 ES481113A ES481113A ES481113A1 ES 481113 A1 ES481113 A1 ES 481113A1 ES 481113 A ES481113 A ES 481113A ES 481113 A ES481113 A ES 481113A ES 481113 A1 ES481113 A1 ES 481113A1
- Authority
- ES
- Spain
- Prior art keywords
- rhodium
- bath
- polycarboxylic
- worked
- amino group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052703 rhodium Inorganic materials 0.000 title abstract 5
- 239000010948 rhodium Substances 0.000 title abstract 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 5
- 238000007747 plating Methods 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 239000011260 aqueous acid Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- YWFDDXXMOPZFFM-UHFFFAOYSA-H rhodium(3+);trisulfate Chemical compound [Rh+3].[Rh+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YWFDDXXMOPZFFM-UHFFFAOYSA-H 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
Un procedimiento para electrodepositar rodio sobre una pieza que se trata de trabajar, que posee por lo menos una superficie conductora, que comprende: a) preparar un baño galvánico ácido acuoso de rodio que comprende de 0,1 a 30 g/l de iones de rodio; de 0,1 a 20 g/l de un ácido carboxílico policarboxílico-orgánico contentivo de por lo menos un grupo amino, y 10 a 100 g/l de radicales de ortofosfato, teniendo dicho baño un valor pH de 0 a 2,0 por disolución en agua de una composición para baño galvánico de rodio consistente esencialmente en sulfato de rodio, un ácido carboxílico policarboxílico-orgánico que tiene por lo menos un grupo amino y ácido fosfórico; b) mantener el baño a una temperatura de 20 a 85ºC; c) sumergir en el baño la pieza que se trate de trabajar y que posea por lo menos una superficie conductora; y d) aplicar un voltaje regulado para proporcionar una densidad de corriente de 0,5 a 30 amperios por 929,03 cm2 en la superficie de la pieza, a través de dicha pieza y de unánodo insoluble, para provocar la correspondiente reacción electrolítica sobre la superficie metálica.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2390378A GB1594418A (en) | 1978-05-30 | 1978-05-30 | Rhodium plating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES481113A1 true ES481113A1 (es) | 1980-08-16 |
Family
ID=10203180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES481113A Expired ES481113A1 (es) | 1978-05-30 | 1979-05-30 | Un procedimiento para electrodepositar rodio sobre una pin- za. |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS54158340A (es) |
| AR (1) | AR225612A1 (es) |
| AT (1) | AT362209B (es) |
| BR (1) | BR7903371A (es) |
| CA (1) | CA1132939A (es) |
| ES (1) | ES481113A1 (es) |
| FR (1) | FR2427404A1 (es) |
| GB (1) | GB1594418A (es) |
| MX (1) | MX152325A (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0048929B1 (en) * | 1980-09-25 | 1987-12-09 | Nippon Mining Company Limited | Rhodium-plated article with black or blue color, process for making the same and bath therefor |
| CN103755738B (zh) * | 2014-01-13 | 2016-06-01 | 孙松华 | 一种络合剂及其制备方法和用途 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1981820A (en) * | 1931-08-27 | 1934-11-20 | Baker & Co Inc | Process of electrodepositing rhodium, bath and method of preparing the same |
-
1978
- 1978-05-30 GB GB2390378A patent/GB1594418A/en not_active Expired
-
1979
- 1979-04-27 FR FR7910941A patent/FR2427404A1/fr active Granted
- 1979-05-23 AR AR27664179A patent/AR225612A1/es active
- 1979-05-23 JP JP6377979A patent/JPS54158340A/ja active Pending
- 1979-05-28 AT AT387579A patent/AT362209B/de not_active IP Right Cessation
- 1979-05-29 BR BR7903371A patent/BR7903371A/pt unknown
- 1979-05-29 CA CA328,747A patent/CA1132939A/en not_active Expired
- 1979-05-29 MX MX17785879A patent/MX152325A/es unknown
- 1979-05-30 ES ES481113A patent/ES481113A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AR225612A1 (es) | 1982-04-15 |
| FR2427404A1 (fr) | 1979-12-28 |
| MX152325A (es) | 1985-06-27 |
| AT362209B (de) | 1981-04-27 |
| JPS54158340A (en) | 1979-12-14 |
| CA1132939A (en) | 1982-10-05 |
| FR2427404B1 (es) | 1982-12-10 |
| GB1594418A (en) | 1981-07-30 |
| ATA387579A (de) | 1980-09-15 |
| BR7903371A (pt) | 1979-12-11 |
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