ES484811A1 - Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4. - Google Patents

Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4.

Info

Publication number
ES484811A1
ES484811A1 ES484811A ES484811A ES484811A1 ES 484811 A1 ES484811 A1 ES 484811A1 ES 484811 A ES484811 A ES 484811A ES 484811 A ES484811 A ES 484811A ES 484811 A1 ES484811 A1 ES 484811A1
Authority
ES
Spain
Prior art keywords
group
thiazolcarboxylate
preparing
disus
tituated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES484811A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES484811A1 publication Critical patent/ES484811A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions

Landscapes

  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

Un procedimiento para preparar un 5-tiazolcar-boxilato disustituido en las posiciones 2 y 4, de la fórmula: **(Fórmula)** en donde X se selecciona del grupo consistente en cloro, bromo, yodo, flúor, alcoxi inferior, fenoxi y fenoxi sustituido por uno o dos grupos seleccionados independientemente del grupo consistente en alcohilo inferior y halógeno, R se selecciona del grupo consistente en alcohilo de 1 a 9 átomos de carbono, haloalcohilo y trialcoximetilo, y R'' se selecciona del grupo consistente en hidrógeno, cationes aceptables en agricultura, alcohilo de 1 a 10 átomos de carbono, alquinilo inferior, alquinilo inferior, alcoxi inferior-alcohilo inferior, haloalcohilo, bencilo, fenilo y fenilo sustituido por uno o dos miembros seleccionados del grupo consistente en halógeno, alcohilo inferior, trifluorometilo y nitro.
ES484811A 1978-05-15 1979-10-08 Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4. Expired ES484811A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/906,183 US4199506A (en) 1978-05-15 1978-05-15 2,4-Disubstituted-5-thiazolecarboxylic acids and derivatives

Publications (1)

Publication Number Publication Date
ES484811A1 true ES484811A1 (es) 1980-06-16

Family

ID=25422061

Family Applications (2)

Application Number Title Priority Date Filing Date
ES480471A Granted ES480471A0 (es) 1978-05-15 1979-05-11 Un procedimiento para preparar y utilizar acidos 5-tiazol-carboxilicos 2,4-disubstituidos y sus derivados
ES484811A Expired ES484811A1 (es) 1978-05-15 1979-10-08 Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES480471A Granted ES480471A0 (es) 1978-05-15 1979-05-11 Un procedimiento para preparar y utilizar acidos 5-tiazol-carboxilicos 2,4-disubstituidos y sus derivados

Country Status (35)

Country Link
US (1) US4199506A (es)
JP (1) JPS54148785A (es)
AR (2) AR224362A1 (es)
AT (1) AT367973B (es)
AU (1) AU519081B2 (es)
BE (1) BE876245A (es)
BG (1) BG34331A3 (es)
BR (1) BR7902962A (es)
CA (1) CA1126736A (es)
CH (1) CH644371A5 (es)
CS (1) CS219902B2 (es)
DD (1) DD144498A5 (es)
DE (1) DE2919511A1 (es)
DK (1) DK197379A (es)
EG (1) EG14637A (es)
ES (2) ES480471A0 (es)
FR (2) FR2433519A1 (es)
GB (1) GB2020662B (es)
GR (1) GR65368B (es)
HU (1) HU182976B (es)
IL (1) IL57262A (es)
IN (1) IN150913B (es)
IT (1) IT1115220B (es)
KE (1) KE3341A (es)
MX (1) MX5836E (es)
MY (1) MY8400313A (es)
NL (1) NL7903721A (es)
NZ (1) NZ190439A (es)
PH (1) PH18876A (es)
PL (1) PL116363B1 (es)
PT (1) PT69608B (es)
RO (1) RO77554A (es)
TR (1) TR20394A (es)
YU (2) YU41341B (es)
ZA (1) ZA792311B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4400200A (en) * 1977-10-11 1983-08-23 Stauffer Chemical Company Haloacyl and thiohaloacyl aryl-substituted oxazolidines and thiazolidines - herbicidal antidotes
US4602454A (en) * 1978-05-15 1986-07-29 Monsanto Company 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives
US4437876A (en) 1980-04-14 1984-03-20 Monsanto Company 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives
US4437875A (en) 1980-04-14 1984-03-20 Monsanto Company 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives
US4602937A (en) * 1978-05-15 1986-07-29 Monsanto Company 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives
US4308391A (en) * 1979-10-01 1981-12-29 Monsanto Company 2-Amino-4-substituted-thiazolecarboxylic acids and their derivatives
US4303439A (en) * 1979-10-01 1981-12-01 Monsanto Company 2-Substituted-4-alkyl or trihaloalkyl-5-oxazolecarboxylic acids as safening agents
EP0034481B1 (en) * 1980-02-14 1984-05-30 Grigg, Ronald Ernest 2-methyl-5-thiazole-methylamine and carboxamide derivatives
US4640702A (en) * 1980-07-14 1987-02-03 Monsanto Company 2-chloro-4-trifluoromethyl-thiazolecarbothioic acids useful as herbicidal safeners
JPS5772975A (en) * 1980-10-24 1982-05-07 Kureha Chem Ind Co Ltd 2-substituted phenylthiazole derviative, and medicine for peptic ulcer containing said derivative as active component
US4586948A (en) * 1981-04-22 1986-05-06 Monsanto Company 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives
BR8202287A (pt) * 1981-04-22 1983-04-05 Monsanto Co Processo para impedir seletivamente o crescimento de ervas daninhas em presenca de planta de cultura de milho e sorgo sementes de sorgo processo para reduzir os dandos causados por hebicidas as plantas de sorgo e composicao herbicida causadora de menos dano pelo herbicida a plantas de cultura
IT1150707B (it) * 1982-03-19 1986-12-17 Montedison Spa Metodo per la difesa di colture di interesse agrario dall'azione di erbicidi non selettivi
DE3441893A1 (de) * 1984-11-16 1986-05-28 Walter Küsnacht Beck Verfahren und vorrichtung zum absaugen von sekretfluessigkeit aus einer wunde
US5000775A (en) * 1985-12-31 1991-03-19 Monsanto Company 2-amino-4,5-disubstituted-oxazole/thiazole compounds as herbicide antidotes
DE3875750D1 (de) * 1987-01-30 1992-12-17 Ciba Geigy Ag Mikrobizide mittel.
US4992434A (en) * 1987-01-30 1991-02-12 Ciba-Geigy Corporation Microbicidal composition
US5135927A (en) * 1987-01-30 1992-08-04 Ciba-Geigy Corporation Microbicidal composition
US4938796A (en) * 1987-07-06 1990-07-03 Ici Americas Inc. Herbicidal compositions of acylated 1,3-dicarbonyl herbicides and antidotes therefor
EP0335831A1 (de) * 1988-03-15 1989-10-04 Ciba-Geigy Ag Thiazol-5-carbonsäureamide zum Schützen von Kulturpflanzen vor der phytotoxischen Wirkung von stark wirksamen Herbiziden
US5136042A (en) * 1988-06-03 1992-08-04 Mitsui Toatsu Chemicals, Inc. Process for the preparation of thiazolecarboxylic acid chlorides
US5527762A (en) * 1990-12-12 1996-06-18 Zeneca Limited Antidoting herbicidal 3-isoxazolidinone compounds
JP3726306B2 (ja) * 1994-04-27 2005-12-14 日産化学工業株式会社 ピラゾールカルボン酸誘導体および植物病害防除剤
US6071856A (en) * 1997-03-04 2000-06-06 Zeneca Limited Herbicidal compositions for acetochlor in rice
US6737382B1 (en) 2002-10-23 2004-05-18 Nippon Soda Co. Ltd. Insecticidal aminothiazole derivatives
US6617341B1 (en) 2002-12-30 2003-09-09 Nippon Soda Co. Ltd. Insecticidal 2-iminothiazole derivatives

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE658353C (de) 1936-04-22 1938-03-29 Chemische Ind Ges Verfahren zur Herstellung von in 2-Stellung unsubstituierten Thiazolcarbonsaeuren bzw. deren Estern
US2961446A (en) * 1956-03-29 1960-11-22 Monsanto Chemicals 2-[di-(lower alkyl) aminoethylthio]-4-lower alkyl-thiazole-5-carboxylic acid lower alkyl esters
US3155678A (en) * 1961-11-14 1964-11-03 Du Pont Certain isothiazole compounds and their production
DE1187620B (de) * 1963-07-31 1965-02-25 Basf Ag Verfahren zur Herstellung von Carbonsaeurechloriden der Thiazolreihe
US3725427A (en) * 1966-12-07 1973-04-03 Uniroyal Ltd Certain 2,4-dimethyl-5-carboxamido-thiazoles
IL32615A (en) * 1968-07-18 1974-01-14 Roussel Uclaf Derivatives of 5-thiazole carboxylic acid and process of preparation
US3882110A (en) * 1969-06-11 1975-05-06 Roussel Uclaf Novel 2-alkyl-5-thiazole-carboxylic acid derivatives
US3957808A (en) * 1969-09-03 1976-05-18 Rohm And Haas Company 3-alkoxyisothiazoles
US3876652A (en) * 1970-11-09 1975-04-08 Int Flavors & Fragrances Inc Certain 5-alkoxy-4-isobutylthiazoles
DE2213865C3 (de) * 1972-03-22 1981-01-22 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Chlorthiazolen
BR7600775A (pt) * 1975-02-14 1977-05-10 Stauffer Chemical Co Processo para a obtencao de(tio)haloacil-(tia)oxazolidinas arisubstituidas e composicoes herbicidas sinergeticas que as contem
FR2310348A1 (fr) * 1975-05-07 1976-12-03 Ugine Kuhlmann Nouveaux derives heterocycliques antidotes contre herbicides

Also Published As

Publication number Publication date
IT1115220B (it) 1986-02-03
CA1126736A (en) 1982-06-29
GR65368B (en) 1980-08-22
PT69608B (en) 1983-04-26
DK197379A (da) 1979-12-20
MX5836E (es) 1984-08-01
FR2433519A1 (fr) 1980-03-14
NL7903721A (nl) 1979-11-19
TR20394A (tr) 1981-05-18
ATA354779A (de) 1982-01-15
BR7902962A (pt) 1979-12-04
HU182976B (en) 1984-03-28
CH644371A5 (de) 1984-07-31
AU4702979A (en) 1979-11-22
ES8100799A1 (es) 1980-11-01
US4199506A (en) 1980-04-22
YU41341B (en) 1987-02-28
YU12584A (en) 1984-06-30
AR227557A1 (es) 1982-11-15
PL215572A1 (es) 1980-03-10
IL57262A0 (en) 1979-09-30
JPS54148785A (en) 1979-11-21
ZA792311B (en) 1980-08-27
YU41386B (en) 1987-02-28
AU519081B2 (en) 1981-11-05
BG34331A3 (en) 1983-08-15
IN150913B (es) 1983-01-15
PH18876A (en) 1985-10-21
GB2020662B (en) 1982-10-06
FR2433296B1 (es) 1983-07-18
AR224362A1 (es) 1981-11-30
YU113079A (en) 1984-06-30
KE3341A (en) 1983-11-25
EG14637A (en) 1985-03-31
CS219902B2 (en) 1983-03-25
ES480471A0 (es) 1980-11-01
BE876245A (fr) 1979-11-14
PT69608A (en) 1979-06-01
RO77554A (ro) 1982-02-26
PL116363B1 (en) 1981-06-30
FR2433519B1 (es) 1983-10-07
AT367973B (de) 1982-08-25
NZ190439A (en) 1980-11-28
DE2919511A1 (de) 1979-11-29
MY8400313A (en) 1984-12-31
GB2020662A (en) 1979-11-21
FR2433296A1 (fr) 1980-03-14
IT7922663A0 (it) 1979-05-14
IL57262A (en) 1982-08-31
DD144498A5 (de) 1980-10-22

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