ES484811A1 - Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4. - Google Patents
Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4.Info
- Publication number
- ES484811A1 ES484811A1 ES484811A ES484811A ES484811A1 ES 484811 A1 ES484811 A1 ES 484811A1 ES 484811 A ES484811 A ES 484811A ES 484811 A ES484811 A ES 484811A ES 484811 A1 ES484811 A1 ES 484811A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- thiazolcarboxylate
- preparing
- disus
- tituated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
Landscapes
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para preparar un 5-tiazolcar-boxilato disustituido en las posiciones 2 y 4, de la fórmula: **(Fórmula)** en donde X se selecciona del grupo consistente en cloro, bromo, yodo, flúor, alcoxi inferior, fenoxi y fenoxi sustituido por uno o dos grupos seleccionados independientemente del grupo consistente en alcohilo inferior y halógeno, R se selecciona del grupo consistente en alcohilo de 1 a 9 átomos de carbono, haloalcohilo y trialcoximetilo, y R'' se selecciona del grupo consistente en hidrógeno, cationes aceptables en agricultura, alcohilo de 1 a 10 átomos de carbono, alquinilo inferior, alquinilo inferior, alcoxi inferior-alcohilo inferior, haloalcohilo, bencilo, fenilo y fenilo sustituido por uno o dos miembros seleccionados del grupo consistente en halógeno, alcohilo inferior, trifluorometilo y nitro.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/906,183 US4199506A (en) | 1978-05-15 | 1978-05-15 | 2,4-Disubstituted-5-thiazolecarboxylic acids and derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES484811A1 true ES484811A1 (es) | 1980-06-16 |
Family
ID=25422061
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES480471A Expired ES8100799A1 (es) | 1978-05-15 | 1979-05-11 | Un procedimiento para preparar y utilizar acidos 5-tiazol-carboxilicos 2,4-disubstituidos y sus derivados |
| ES484811A Expired ES484811A1 (es) | 1978-05-15 | 1979-10-08 | Un procedimiento para preparar un 5-tiazolcarboxilato disus-tituido en las posiciones 2 y 4. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES480471A Expired ES8100799A1 (es) | 1978-05-15 | 1979-05-11 | Un procedimiento para preparar y utilizar acidos 5-tiazol-carboxilicos 2,4-disubstituidos y sus derivados |
Country Status (35)
| Country | Link |
|---|---|
| US (1) | US4199506A (es) |
| JP (1) | JPS54148785A (es) |
| AR (2) | AR224362A1 (es) |
| AT (1) | AT367973B (es) |
| AU (1) | AU519081B2 (es) |
| BE (1) | BE876245A (es) |
| BG (1) | BG34331A3 (es) |
| BR (1) | BR7902962A (es) |
| CA (1) | CA1126736A (es) |
| CH (1) | CH644371A5 (es) |
| CS (1) | CS219902B2 (es) |
| DD (1) | DD144498A5 (es) |
| DE (1) | DE2919511A1 (es) |
| DK (1) | DK197379A (es) |
| EG (1) | EG14637A (es) |
| ES (2) | ES8100799A1 (es) |
| FR (2) | FR2433519A1 (es) |
| GB (1) | GB2020662B (es) |
| GR (1) | GR65368B (es) |
| HU (1) | HU182976B (es) |
| IL (1) | IL57262A (es) |
| IN (1) | IN150913B (es) |
| IT (1) | IT1115220B (es) |
| KE (1) | KE3341A (es) |
| MX (1) | MX5836E (es) |
| MY (1) | MY8400313A (es) |
| NL (1) | NL7903721A (es) |
| NZ (1) | NZ190439A (es) |
| PH (1) | PH18876A (es) |
| PL (1) | PL116363B1 (es) |
| PT (1) | PT69608B (es) |
| RO (1) | RO77554A (es) |
| TR (1) | TR20394A (es) |
| YU (2) | YU41341B (es) |
| ZA (1) | ZA792311B (es) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400200A (en) * | 1977-10-11 | 1983-08-23 | Stauffer Chemical Company | Haloacyl and thiohaloacyl aryl-substituted oxazolidines and thiazolidines - herbicidal antidotes |
| US4602937A (en) * | 1978-05-15 | 1986-07-29 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
| US4437875A (en) | 1980-04-14 | 1984-03-20 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
| US4602454A (en) * | 1978-05-15 | 1986-07-29 | Monsanto Company | 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives |
| US4437876A (en) | 1980-04-14 | 1984-03-20 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
| US4308391A (en) * | 1979-10-01 | 1981-12-29 | Monsanto Company | 2-Amino-4-substituted-thiazolecarboxylic acids and their derivatives |
| US4303439A (en) * | 1979-10-01 | 1981-12-01 | Monsanto Company | 2-Substituted-4-alkyl or trihaloalkyl-5-oxazolecarboxylic acids as safening agents |
| EP0034481B1 (en) * | 1980-02-14 | 1984-05-30 | Grigg, Ronald Ernest | 2-methyl-5-thiazole-methylamine and carboxamide derivatives |
| US4640702A (en) * | 1980-07-14 | 1987-02-03 | Monsanto Company | 2-chloro-4-trifluoromethyl-thiazolecarbothioic acids useful as herbicidal safeners |
| JPS5772975A (en) * | 1980-10-24 | 1982-05-07 | Kureha Chem Ind Co Ltd | 2-substituted phenylthiazole derviative, and medicine for peptic ulcer containing said derivative as active component |
| RO84370B (ro) * | 1981-04-22 | 1984-09-30 | Monsanto Co | Compozitie erbicida cu antidot |
| US4586948A (en) * | 1981-04-22 | 1986-05-06 | Monsanto Company | 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives |
| IT1150707B (it) * | 1982-03-19 | 1986-12-17 | Montedison Spa | Metodo per la difesa di colture di interesse agrario dall'azione di erbicidi non selettivi |
| DE3441893A1 (de) * | 1984-11-16 | 1986-05-28 | Walter Küsnacht Beck | Verfahren und vorrichtung zum absaugen von sekretfluessigkeit aus einer wunde |
| US5000775A (en) * | 1985-12-31 | 1991-03-19 | Monsanto Company | 2-amino-4,5-disubstituted-oxazole/thiazole compounds as herbicide antidotes |
| US5135927A (en) * | 1987-01-30 | 1992-08-04 | Ciba-Geigy Corporation | Microbicidal composition |
| US4992434A (en) * | 1987-01-30 | 1991-02-12 | Ciba-Geigy Corporation | Microbicidal composition |
| ATE82275T1 (de) * | 1987-01-30 | 1992-11-15 | Ciba Geigy Ag | Mikrobizide mittel. |
| US4938796A (en) * | 1987-07-06 | 1990-07-03 | Ici Americas Inc. | Herbicidal compositions of acylated 1,3-dicarbonyl herbicides and antidotes therefor |
| EP0335831A1 (de) * | 1988-03-15 | 1989-10-04 | Ciba-Geigy Ag | Thiazol-5-carbonsäureamide zum Schützen von Kulturpflanzen vor der phytotoxischen Wirkung von stark wirksamen Herbiziden |
| KR920005826B1 (ko) * | 1988-06-03 | 1992-07-20 | 미츠이 도아츠 가가쿠 가부시기가이샤 | 티아졸카르복실산 클로라이드의 제조방법 |
| US5527762A (en) * | 1990-12-12 | 1996-06-18 | Zeneca Limited | Antidoting herbicidal 3-isoxazolidinone compounds |
| JP3726306B2 (ja) * | 1994-04-27 | 2005-12-14 | 日産化学工業株式会社 | ピラゾールカルボン酸誘導体および植物病害防除剤 |
| US6071856A (en) * | 1997-03-04 | 2000-06-06 | Zeneca Limited | Herbicidal compositions for acetochlor in rice |
| US6737382B1 (en) | 2002-10-23 | 2004-05-18 | Nippon Soda Co. Ltd. | Insecticidal aminothiazole derivatives |
| US6617341B1 (en) | 2002-12-30 | 2003-09-09 | Nippon Soda Co. Ltd. | Insecticidal 2-iminothiazole derivatives |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE658353C (de) | 1936-04-22 | 1938-03-29 | Chemische Ind Ges | Verfahren zur Herstellung von in 2-Stellung unsubstituierten Thiazolcarbonsaeuren bzw. deren Estern |
| US2961446A (en) * | 1956-03-29 | 1960-11-22 | Monsanto Chemicals | 2-[di-(lower alkyl) aminoethylthio]-4-lower alkyl-thiazole-5-carboxylic acid lower alkyl esters |
| US3155678A (en) * | 1961-11-14 | 1964-11-03 | Du Pont | Certain isothiazole compounds and their production |
| DE1187620B (de) | 1963-07-31 | 1965-02-25 | Basf Ag | Verfahren zur Herstellung von Carbonsaeurechloriden der Thiazolreihe |
| US3725427A (en) * | 1966-12-07 | 1973-04-03 | Uniroyal Ltd | Certain 2,4-dimethyl-5-carboxamido-thiazoles |
| IL32615A (en) * | 1968-07-18 | 1974-01-14 | Roussel Uclaf | Derivatives of 5-thiazole carboxylic acid and process of preparation |
| US3882110A (en) * | 1969-06-11 | 1975-05-06 | Roussel Uclaf | Novel 2-alkyl-5-thiazole-carboxylic acid derivatives |
| US3957808A (en) * | 1969-09-03 | 1976-05-18 | Rohm And Haas Company | 3-alkoxyisothiazoles |
| US3876652A (en) * | 1970-11-09 | 1975-04-08 | Int Flavors & Fragrances Inc | Certain 5-alkoxy-4-isobutylthiazoles |
| DE2213865C3 (de) * | 1972-03-22 | 1981-01-22 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Chlorthiazolen |
| BR7600775A (pt) * | 1975-02-14 | 1977-05-10 | Stauffer Chemical Co | Processo para a obtencao de(tio)haloacil-(tia)oxazolidinas arisubstituidas e composicoes herbicidas sinergeticas que as contem |
| FR2310348A1 (fr) * | 1975-05-07 | 1976-12-03 | Ugine Kuhlmann | Nouveaux derives heterocycliques antidotes contre herbicides |
-
1978
- 1978-05-15 US US05/906,183 patent/US4199506A/en not_active Expired - Lifetime
-
1979
- 1979-05-04 TR TR20394A patent/TR20394A/xx unknown
- 1979-05-11 IN IN488/CAL/79A patent/IN150913B/en unknown
- 1979-05-11 ES ES480471A patent/ES8100799A1/es not_active Expired
- 1979-05-11 NL NL7903721A patent/NL7903721A/xx not_active Application Discontinuation
- 1979-05-14 AU AU47029/79A patent/AU519081B2/en not_active Expired
- 1979-05-14 CA CA327,554A patent/CA1126736A/en not_active Expired
- 1979-05-14 CH CH448779A patent/CH644371A5/de not_active IP Right Cessation
- 1979-05-14 RO RO7997512A patent/RO77554A/ro unknown
- 1979-05-14 BG BG043570A patent/BG34331A3/xx unknown
- 1979-05-14 DK DK197379A patent/DK197379A/da not_active Application Discontinuation
- 1979-05-14 GB GB7916615A patent/GB2020662B/en not_active Expired
- 1979-05-14 EG EG79284A patent/EG14637A/xx active
- 1979-05-14 HU HU79MO1044A patent/HU182976B/hu unknown
- 1979-05-14 IT IT22663/79A patent/IT1115220B/it active
- 1979-05-14 MX MX797976U patent/MX5836E/es unknown
- 1979-05-14 BE BE0/195158A patent/BE876245A/xx not_active IP Right Cessation
- 1979-05-14 IL IL57262A patent/IL57262A/xx unknown
- 1979-05-14 PH PH22483A patent/PH18876A/en unknown
- 1979-05-14 JP JP6023279A patent/JPS54148785A/ja active Pending
- 1979-05-14 FR FR7912182A patent/FR2433519A1/fr active Granted
- 1979-05-14 DD DD79212868A patent/DD144498A5/de unknown
- 1979-05-14 AT AT0354779A patent/AT367973B/de not_active IP Right Cessation
- 1979-05-14 CS CS793290A patent/CS219902B2/cs unknown
- 1979-05-14 BR BR7902962A patent/BR7902962A/pt unknown
- 1979-05-14 ZA ZA792311A patent/ZA792311B/xx unknown
- 1979-05-14 PT PT69608A patent/PT69608B/pt unknown
- 1979-05-14 YU YU1130/79A patent/YU41341B/xx unknown
- 1979-05-14 NZ NZ190439A patent/NZ190439A/xx unknown
- 1979-05-14 AR AR276497A patent/AR224362A1/es active
- 1979-05-14 PL PL1979215572A patent/PL116363B1/pl unknown
- 1979-05-14 GR GR59078A patent/GR65368B/el unknown
- 1979-05-15 DE DE19792919511 patent/DE2919511A1/de not_active Ceased
- 1979-10-08 ES ES484811A patent/ES484811A1/es not_active Expired
- 1979-11-07 FR FR7927431A patent/FR2433296A1/fr active Granted
-
1981
- 1981-09-01 AR AR286609A patent/AR227557A1/es active
-
1983
- 1983-10-27 KE KE3341A patent/KE3341A/xx unknown
-
1984
- 1984-01-24 YU YU125/84A patent/YU41386B/xx unknown
- 1984-12-30 MY MY313/84A patent/MY8400313A/xx unknown
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