ES485645A1 - Un procedimiento mejorado para preparar n-fenil-n'-alcohil- fenilendiamina - Google Patents
Un procedimiento mejorado para preparar n-fenil-n'-alcohil- fenilendiaminaInfo
- Publication number
- ES485645A1 ES485645A1 ES485645A ES485645A ES485645A1 ES 485645 A1 ES485645 A1 ES 485645A1 ES 485645 A ES485645 A ES 485645A ES 485645 A ES485645 A ES 485645A ES 485645 A1 ES485645 A1 ES 485645A1
- Authority
- ES
- Spain
- Prior art keywords
- alkylphenylenediamines
- phenyl
- preparation
- dihydric alcohol
- diether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- -1 ether compound Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 238000005932 reductive alkylation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento mejorado para preparar N-fenil-N''- alcohilfenilendiamina que comprende la alcohilación reductora de un compuesto que contiene nitrógeno seleccionado del grupo que consta de nitrodifenilaminas, nitrosodifenilaminas, y aminodifenilaminas, y una cetona, en presencia de hidrógeno y un catalizador de hidrogenación, en condiciones de reacción, y la recuperación de la N-feni-N''-alcohilfenilendiamina resultante, en el que la mejora consiste en efectuar dicho procedimiento en presencia de un disolvente orgánico que comprende un éter seleccionado del grupo que consta de monoéteres de alcoholes dihidroxilados, diéteres de alcoholes dihidroxilados y éteres cíclicos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/957,263 US4304939A (en) | 1978-11-02 | 1978-11-02 | Preparation of N-phenyl-N-alkylphenylenediamines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES485645A1 true ES485645A1 (es) | 1980-07-01 |
Family
ID=25499316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES485645A Expired ES485645A1 (es) | 1978-11-02 | 1979-11-02 | Un procedimiento mejorado para preparar n-fenil-n'-alcohil- fenilendiamina |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4304939A (es) |
| JP (1) | JPS55108840A (es) |
| BR (1) | BR7907134A (es) |
| CA (1) | CA1133517A (es) |
| DE (1) | DE2944240C2 (es) |
| ES (1) | ES485645A1 (es) |
| FR (1) | FR2440938A1 (es) |
| GB (1) | GB2037747B (es) |
| IT (1) | IT1125604B (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706216B1 (en) * | 2000-04-19 | 2004-03-16 | Uniroyal Chemical Company, Inc. | Liquid antiozonants and rubber compositions containing same |
| US8563489B2 (en) * | 2007-12-12 | 2013-10-22 | Chemtura Corporation | Alkylated 1,3-benzenediamine compounds and methods for producing same |
| US20090156441A1 (en) * | 2007-12-12 | 2009-06-18 | Rowland Robert G | Cycloalkyl phenylenediamines as deposit control agents for lubricants |
| CN102060714A (zh) * | 2010-06-25 | 2011-05-18 | 天津市有机化工一厂 | 一种制备4-氨基二苯胺的方法 |
| RU2502725C1 (ru) * | 2012-10-22 | 2013-12-27 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Способ получения n-алкил-n'-фенил-пара-фенилендиаминов |
| JP6852238B2 (ja) * | 2017-07-13 | 2021-03-31 | 日本特殊化学工業株式会社 | エーテル組成物の製造方法 |
| RU2670975C1 (ru) * | 2018-07-20 | 2018-10-26 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Способ получения n-изопропил-n'-фенил-п-фенилендиамина |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1172211A (fr) * | 1956-02-06 | 1959-02-06 | Gen Aniline & Film Corp | Procédé d'hydrogénation catalytique de composés aromatiques dinitrés |
| US2809994A (en) * | 1956-06-14 | 1957-10-15 | Metal Hydrides Inc | Method for alkylating aromatic amines |
| DE1543635A1 (de) * | 1966-02-08 | 1969-07-31 | Gnii Orch Poluprodktov I Krasi | Verfahren zur Herstellung von N-sekundaeren Alkylaminodiphenylaminen |
| FR2113312A5 (en) * | 1970-10-31 | 1972-06-23 | Eszakmagyar Vegyimuevek | N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether |
| US4140718A (en) * | 1976-10-14 | 1979-02-20 | Uop Inc. | Preparation of N,N'-dialkylphenylenediamines |
| US4155936A (en) * | 1978-03-08 | 1979-05-22 | The Goodyear Tire & Rubber Company | Para-nitrodiphenylamines synthesis using Polyethers and macrocyclic esters as solubilizing agents |
-
1978
- 1978-11-02 US US05/957,263 patent/US4304939A/en not_active Expired - Lifetime
-
1979
- 1979-11-01 CA CA338,967A patent/CA1133517A/en not_active Expired
- 1979-11-01 BR BR7907134A patent/BR7907134A/pt unknown
- 1979-11-02 ES ES485645A patent/ES485645A1/es not_active Expired
- 1979-11-02 FR FR7927115A patent/FR2440938A1/fr active Granted
- 1979-11-02 DE DE2944240A patent/DE2944240C2/de not_active Expired
- 1979-11-02 GB GB7937990A patent/GB2037747B/en not_active Expired
- 1979-11-02 IT IT27024/79A patent/IT1125604B/it active
- 1979-11-02 JP JP14270979A patent/JPS55108840A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5721259B2 (es) | 1982-05-06 |
| IT1125604B (it) | 1986-05-14 |
| FR2440938B1 (es) | 1981-12-11 |
| US4304939A (en) | 1981-12-08 |
| CA1133517A (en) | 1982-10-12 |
| DE2944240A1 (de) | 1980-05-14 |
| GB2037747A (en) | 1980-07-16 |
| GB2037747B (en) | 1983-04-13 |
| IT7927024A0 (it) | 1979-11-02 |
| DE2944240C2 (de) | 1982-10-14 |
| FR2440938A1 (fr) | 1980-06-06 |
| JPS55108840A (en) | 1980-08-21 |
| BR7907134A (pt) | 1980-08-26 |
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