ES8105272A1 - Un procedimiento para la preparacion de aminoacetonitrilos hidroxiimino sustituidos - Google Patents

Un procedimiento para la preparacion de aminoacetonitrilos hidroxiimino sustituidos

Info

Publication number
ES8105272A1
ES8105272A1 ES490286A ES490286A ES8105272A1 ES 8105272 A1 ES8105272 A1 ES 8105272A1 ES 490286 A ES490286 A ES 490286A ES 490286 A ES490286 A ES 490286A ES 8105272 A1 ES8105272 A1 ES 8105272A1
Authority
ES
Spain
Prior art keywords
elevated
alkyl
hydroxyimino
intermediates
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES490286A
Other languages
English (en)
Other versions
ES490286A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eli Lilly and Co
Original Assignee
Eli Lilly and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eli Lilly and Co filed Critical Eli Lilly and Co
Publication of ES8105272A1 publication Critical patent/ES8105272A1/es
Publication of ES490286A0 publication Critical patent/ES490286A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/20—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/40—Halogenated unsaturated alcohols
    • C07C33/46—Halogenated unsaturated alcohols containing only six-membered aromatic rings as cyclic parts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/18—Oxygen or sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

PROCEDIMIENTO DE OBTENCION DE AMINOACETONITRILOS HIDROXIIMINO-SUSTITUIDOS. CONSISTE EN HACER REACCIONAR UN AMINOACETONITRILO DE FORMULA GENERAL (I) CON UNA -HALO-OXINA II EN UN DISOLVENTE TAL COMO EL CLOROFORMO O CLORURO DE METILENO. LA REACCION SE EFECTUA EN PRESENCIA DE UN ACEPTOR DE ACIDO. LA TEMPERATURA DE REACCION OSCILA ENTRE -5 Y 25GC. SE OBTIENE UN COMPUESTO DE FORMULA GENERAL III, DONDE R ELEVADO A 1 ES HIDROGENO O ALQUILO DE 1 A 4 ATOMOS DE CARBONO; R ELEVADO A 2 ES HIDROGENO, HALOGENO, ALQUILO O TRIFLUORMETILO; <<N>> ES 0,1 O 2; R ELEVADO A 3 ES ALQUILO DE 1 A 4 ATOMOS DE CARBONO Y <<X>> ES CLORO O BROMO. *FORMULA* INTERMEDIARIOS PARA OBTENCION DE INSECTICIDAS. 3
ES490286A 1979-04-06 1980-04-02 Un procedimiento para la preparacion de aminoacetonitrilos hidroxiimino sustituidos Granted ES490286A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/027,627 US4199525A (en) 1979-04-06 1979-04-06 Hydroxyimino-substituted aminoacetonitriles

Publications (2)

Publication Number Publication Date
ES8105272A1 true ES8105272A1 (es) 1981-05-16
ES490286A0 ES490286A0 (es) 1981-05-16

Family

ID=21838822

Family Applications (1)

Application Number Title Priority Date Filing Date
ES490286A Granted ES490286A0 (es) 1979-04-06 1980-04-02 Un procedimiento para la preparacion de aminoacetonitrilos hidroxiimino sustituidos

Country Status (30)

Country Link
US (1) US4199525A (es)
EP (1) EP0017494A3 (es)
JP (1) JPS55141459A (es)
KR (1) KR830002679A (es)
AT (1) AT365168B (es)
AU (1) AU5710380A (es)
BE (1) BE882607A (es)
BR (1) BR8002078A (es)
CA (1) CA1118788A (es)
CS (1) CS215054B2 (es)
DD (1) DD150053A5 (es)
DK (1) DK143780A (es)
ES (1) ES490286A0 (es)
FI (1) FI801057A7 (es)
FR (1) FR2453144A1 (es)
GB (1) GB2046752A (es)
GR (1) GR68095B (es)
HU (1) HU178852B (es)
IL (1) IL59762A0 (es)
IT (1) IT1147344B (es)
LU (1) LU82341A1 (es)
NZ (1) NZ193346A (es)
OA (1) OA07371A (es)
PH (1) PH15423A (es)
PL (1) PL123696B1 (es)
PT (1) PT71055A (es)
RO (1) RO79499A (es)
TR (1) TR20651A (es)
YU (1) YU90680A (es)
ZA (1) ZA802002B (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USD647235S1 (en) 2010-03-08 2011-10-18 Hubbell Incorporated Lighting fixture having struts
USD689646S1 (en) 2012-01-25 2013-09-10 Hubbell Incorporated Wall mounted light fixture having struts

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3144485A (en) * 1960-01-20 1964-08-11 Boots Pure Drug Co Ltd Alpha-(nu-aryl, aralkyl) acetamidoxiones

Also Published As

Publication number Publication date
EP0017494A2 (en) 1980-10-15
GB2046752A (en) 1980-11-19
YU90680A (en) 1983-02-28
ZA802002B (en) 1981-11-25
CS215054B2 (en) 1982-07-30
NZ193346A (en) 1982-11-23
RO79499A (ro) 1982-07-06
GR68095B (es) 1981-10-30
AU5710380A (en) 1980-10-09
AT365168B (de) 1981-12-28
KR830002679A (ko) 1983-05-30
IT8021230A0 (it) 1980-04-04
IL59762A0 (en) 1980-06-30
BE882607A (fr) 1980-10-03
PL123696B1 (en) 1982-11-30
CA1118788A (en) 1982-02-23
EP0017494A3 (en) 1981-06-10
DD150053A5 (de) 1981-08-12
OA07371A (fr) 1984-06-30
BR8002078A (pt) 1980-11-25
JPS55141459A (en) 1980-11-05
LU82341A1 (fr) 1980-07-02
ATA184580A (de) 1981-05-15
PT71055A (en) 1980-05-01
PL223265A1 (es) 1981-01-30
IT1147344B (it) 1986-11-19
HU178852B (en) 1982-07-28
TR20651A (tr) 1982-03-24
FR2453144A1 (fr) 1980-10-31
FI801057A7 (fi) 1981-01-01
DK143780A (da) 1980-10-07
US4199525A (en) 1980-04-22
PH15423A (en) 1983-01-07
ES490286A0 (es) 1981-05-16

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