ES8207111A1 - Process for the preparation of cyclohexanol and/or cyclohexanone. - Google Patents

Process for the preparation of cyclohexanol and/or cyclohexanone.

Info

Publication number
ES8207111A1
ES8207111A1 ES507669A ES507669A ES8207111A1 ES 8207111 A1 ES8207111 A1 ES 8207111A1 ES 507669 A ES507669 A ES 507669A ES 507669 A ES507669 A ES 507669A ES 8207111 A1 ES8207111 A1 ES 8207111A1
Authority
ES
Spain
Prior art keywords
cyclohexanol
cyclohexanone
cyclohexene
cyclohexane
mpa
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES507669A
Other languages
Spanish (es)
Other versions
ES507669A0 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stamicarbon BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of ES507669A0 publication Critical patent/ES507669A0/en
Publication of ES8207111A1 publication Critical patent/ES8207111A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
    • C07C29/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis the acid being sulfuric acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCEDIMIENTO PARA LA PREARACION DE CICLOHEXANOL Y-O CICLOHEXANONA A PARTIR DE CICLOHEXANO. CONSISTE EN DESHIDROGENAR EL CICLOHEXANO A CICLOHEXENO A UNA TEMPERATURA DE 200 A 700 GRADOS CENTIGRADOS Y UNA PRE SION DE 0,01 A 10 MPA. A CONTINUACION EL CICLOHEXENO SE HIDRATA A CICLOHEXANO A UNA TEMPERATURA DE -50 A 150 GRADOS CENTIGRADOS Y APRESION DE 0,01 A 200 MPA, SE SEPARA EL CICLOHEXANOL Y-O CICLOHEXENO SIN CONVERTIR SE DEVUELVEN A LA ETAPA DE DESHIDROGENACION. LA HIDROGENACION TIENE LUGAR EN FASE GASEOSA A UNA TEMPERATURA DE 150 A 400 GRADOS CENTIGRADOS Y PESION DE 0,01 A MPA, EMPLEANDOSE PLATINO COMO CATALIZADOR.PROCEDURE FOR THE PREPARATION OF CYCLOHEXANOL AND-OR CYCLOHEXANONE FROM CYCLOHEXANE. IT CONSISTS OF DEHYDROGENING CYCLOHEXANE TO CYCLOHEXENE AT A TEMPERATURE OF 200 TO 700 DEGREES CENTIGRADE AND A PRESSURE OF 0.01 TO 10 MPA. THEN THE CYCLOHEXENE IS HYDRATED TO CYCLOHEXANE AT A TEMPERATURE OF -50 TO 150 DEGREES CENTIGRADE AND PRESSURE OF 0.01 TO 200 MPA, THE CYCLOHEXANOL AND-OR CYCLOHEXENE IS SEPARATED WITHOUT CONVERTING THEY RETURN TO THE DEHYDROGEN STAGE. HYDROGENATION TAKES PLACE IN THE GASEOUS PHASE AT A TEMPERATURE OF 150 TO 400 DEGREES CENTIGRADE AND PESSION OF 0.01 A MPA, USING PLATINUM AS A CATALYST.

ES507669A 1980-12-04 1981-12-03 Process for the preparation of cyclohexanol and/or cyclohexanone. Expired ES8207111A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8006602A NL8006602A (en) 1980-12-04 1980-12-04 PROCESS FOR PREPARING CYCLOHEXANOL AND / OR CYCLOHEXANONE.

Publications (2)

Publication Number Publication Date
ES507669A0 ES507669A0 (en) 1982-09-01
ES8207111A1 true ES8207111A1 (en) 1982-09-01

Family

ID=19836280

Family Applications (1)

Application Number Title Priority Date Filing Date
ES507669A Expired ES8207111A1 (en) 1980-12-04 1981-12-03 Process for the preparation of cyclohexanol and/or cyclohexanone.

Country Status (10)

Country Link
EP (1) EP0053847A1 (en)
JP (1) JPS57120538A (en)
KR (1) KR830007481A (en)
BR (1) BR8107857A (en)
CS (1) CS224636B2 (en)
DD (1) DD202526A5 (en)
ES (1) ES8207111A1 (en)
NL (1) NL8006602A (en)
PL (1) PL234078A1 (en)
YU (1) YU280181A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5233095A (en) * 1986-03-18 1993-08-03 Catalytica, Inc. Process for manufacture of resorcinol
NL8801036A (en) * 1988-04-21 1989-11-16 Stamicarbon PROCESS FOR THE PREPARATION OF CYCLOHEXANOL AND / OR CYCLOHEXANONE.
CN115838325A (en) * 2021-09-18 2023-03-24 中国石油化工股份有限公司 A kind of method that cyclohexene and cyclohexane coupling prepare cyclohexanone
CN115838324B (en) * 2021-09-18 2024-05-28 中国石油化工股份有限公司 A method for preparing cyclohexanone by combined hydration and oxidation dehydrogenation

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1087595B (en) * 1959-01-15 1960-08-25 Ruhrchemie Ag Circular process for the production of cyclohexanone
LU40055A1 (en) * 1960-04-26 1961-06-24
DE2437472A1 (en) * 1974-08-03 1976-04-22 Bayer Antwerpen Nv PROCESS FOR OXIDATION OF HYDROCARBONS
JPS51118743A (en) * 1975-04-08 1976-10-18 Ube Ind Ltd Process for preparation of cyclohexene from high boiling point mixed o il
JPS5390242A (en) * 1977-01-18 1978-08-08 Toray Ind Inc Preparation of cyclohexanol
NL7804667A (en) * 1978-04-29 1979-10-31 Stamicarbon METHOD OF PREPARING CYCLOHEXANONE.
FR2442835A1 (en) * 1978-11-30 1980-06-27 Inst Francais Du Petrole NOVEL PEROXIDE PLATINUM AND PALLADIUM COMPLEXES, PROCESS FOR THEIR MANUFACTURE AND THEIR USE AS SELECTIVE OXIDATION AND OXIDANT DEHYDROGENATION REAGENTS
NL7905781A (en) * 1979-07-26 1981-01-28 Stamicarbon PROCESS FOR PREPARING CYCLOHEXANOL.

Also Published As

Publication number Publication date
EP0053847A1 (en) 1982-06-16
DD202526A5 (en) 1983-09-21
BR8107857A (en) 1982-09-08
YU280181A (en) 1983-02-28
CS224636B2 (en) 1984-01-16
PL234078A1 (en) 1982-07-05
JPS57120538A (en) 1982-07-27
NL8006602A (en) 1982-07-01
ES507669A0 (en) 1982-09-01
KR830007481A (en) 1983-10-21

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