ES8304583A1 - Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio. - Google Patents

Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio.

Info

Publication number
ES8304583A1
ES8304583A1 ES508413A ES508413A ES8304583A1 ES 8304583 A1 ES8304583 A1 ES 8304583A1 ES 508413 A ES508413 A ES 508413A ES 508413 A ES508413 A ES 508413A ES 8304583 A1 ES8304583 A1 ES 8304583A1
Authority
ES
Spain
Prior art keywords
preparation
complex compounds
rhodium complex
triorganophosphorus
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES508413A
Other languages
English (en)
Other versions
ES508413A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES8304583A1 publication Critical patent/ES8304583A1/es
Publication of ES508413A0 publication Critical patent/ES508413A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

_(PROCEDIMIENTO PARA PREPARAR UN COMPUESTO DE HALOCARBONILBIS (TRIORGANOFOSFORO)RODIO . CONSISTE EN HACER REACCIONAR A UNA TEMPERATURA DE 20 A 200 C UNA SOLUCION DE REACCION ORGANICA HOMOGENEA CONSISTENTE EN: A) UN CONCENTRADO DE COMPLEJO DE RODIO; B) UNA FUENTE DEL ION HALURO; C) GAS MONOXIDO DE CARBONO; D) LIGANDO DE TRIORGANOFOSFORO LIBRE. EL CONCENTRADO HA SIDO OXIDADO A UNA TEMPERATURA DE 90 A 175 C; EL AGENTE OXIDANTE EMPLEADO ES AIRE. LA FUENTE DE ION HALURO ES UN ACIDO HIDROHALICO TAL COMO EL CLORHIDRICO. COMO FUENTE DE MONOXIDO DE CARBONO, SE EMPLEA UNA AMIDA TAL COMO N,N-DIMETIL-FORMAMIDA. EL LIGANDO DE TRIORGANOFOSFORO ANHIDRO EMPLEADO ES TRIFENILFOSFINA.
ES508413A 1980-12-30 1981-12-29 Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio. Granted ES508413A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/221,502 US4363764A (en) 1980-12-30 1980-12-30 Preparation of rhodium complex compounds

Publications (2)

Publication Number Publication Date
ES8304583A1 true ES8304583A1 (es) 1983-04-01
ES508413A0 ES508413A0 (es) 1983-04-01

Family

ID=22828092

Family Applications (2)

Application Number Title Priority Date Filing Date
ES508413A Granted ES508413A0 (es) 1980-12-30 1981-12-29 Procedimiento para preparar un compuesto de halocarbonilbis (triorganofosforo) rodio.
ES518851A Expired ES8401980A1 (es) 1980-12-30 1983-01-07 Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES518851A Expired ES8401980A1 (es) 1980-12-30 1983-01-07 Procedimiento para preparar un compuesto de hidrurocarboniltris (triorganofosforo) rodio.

Country Status (13)

Country Link
US (1) US4363764A (es)
EP (1) EP0055487B1 (es)
JP (2) JPS57167998A (es)
KR (1) KR860001612B1 (es)
AT (1) ATE9701T1 (es)
BR (1) BR8108413A (es)
CA (1) CA1174243A (es)
DE (1) DE3166529D1 (es)
ES (2) ES508413A0 (es)
MX (1) MX163334A (es)
PL (2) PL135114B1 (es)
YU (2) YU43059B (es)
ZA (1) ZA818634B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
US4668809A (en) * 1982-05-03 1987-05-26 Exxon Research And Engineering Transition metal complex catalysts
JPS6127994A (ja) * 1984-07-16 1986-02-07 Agency Of Ind Science & Technol ロジウム化合物の製造法
US4788308A (en) * 1986-02-03 1988-11-29 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
US4673753A (en) * 1986-02-03 1987-06-16 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
KR0134494B1 (ko) * 1993-10-20 1998-04-20 성재갑 하이드리도카르보닐트리스(트리오가노포스포러스)로듐의 제조방법
UA27055C2 (uk) * 1993-12-14 2000-02-28 Центр Ембріональних Тканин "Емселл" Лікарський препарат імуhозаміhhої дії hа осhові клітиhhої суспеhзії та спосіб лікуваhhя сиhдрому hабутого імуhодефіциту (віл-іhфекції) з використаhhям цього препарату
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
DE102004028183B4 (de) * 2003-06-10 2008-04-30 Bayer Schering Pharma Aktiengesellschaft Verfahren zum Regenerieren der Katalysatorverbindungen Rh(PX3)3(Y)
CN102382143B (zh) * 2010-08-31 2014-05-28 中国石油化工股份有限公司 一种烯烃氢甲酰化均相络合催化剂的制备方法
WO2016005282A1 (de) 2014-07-11 2016-01-14 Umicore Ag & Co. Kg Verfahren zur herstellung von hydridocarbonyltris(triphenylphosphin)rhodium(i)
JP7014301B2 (ja) 2018-09-03 2022-02-01 日本電気株式会社 情報処理装置、分析システム、分析方法及び分析プログラム
JP7350674B2 (ja) 2020-02-26 2023-09-26 株式会社東芝 情報処理装置、情報処理方法、およびプログラム

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3560539A (en) * 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
US3857895A (en) * 1969-05-12 1974-12-31 Union Oil Co Recovery of catalyst complexes
US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3641076A (en) * 1970-08-24 1972-02-08 Union Oil Co Catalyst recovery
JPS5136799B2 (es) * 1971-10-06 1976-10-12
IT1007026B (it) * 1974-01-23 1976-10-30 Montedison Spa Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen
DE2614799C2 (de) * 1976-04-06 1986-02-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen
JPS5594390A (en) * 1979-01-08 1980-07-17 Toyo Soda Mfg Co Ltd Preparation of catalyst
US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
NO156742C (no) * 1979-03-28 1987-11-18 Union Carbide Corp Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder.

Also Published As

Publication number Publication date
PL234494A1 (es) 1982-09-13
EP0055487B1 (en) 1984-10-03
JPH0120160B2 (es) 1989-04-14
KR860001612B1 (ko) 1986-10-14
YU313381A (en) 1983-10-31
BR8108413A (pt) 1982-10-13
KR830007711A (ko) 1983-11-04
EP0055487A1 (en) 1982-07-07
MX163334A (es) 1992-04-22
ES518851A0 (es) 1984-02-01
YU127483A (en) 1983-12-31
ZA818634B (en) 1982-10-27
YU43059B (en) 1989-02-28
CA1174243A (en) 1984-09-11
ES8401980A1 (es) 1984-02-01
US4363764A (en) 1982-12-14
ATE9701T1 (de) 1984-10-15
ES508413A0 (es) 1983-04-01
PL135114B1 (en) 1985-09-30
PL134893B1 (en) 1985-09-30
JPS57167998A (en) 1982-10-16
JPS62265294A (ja) 1987-11-18
JPS6338036B2 (es) 1988-07-28
DE3166529D1 (en) 1984-11-08

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19970612