ES8306470A1 - Procedimiento para la obtencion continua de cloroformiatos de alquilo. - Google Patents
Procedimiento para la obtencion continua de cloroformiatos de alquilo.Info
- Publication number
- ES8306470A1 ES8306470A1 ES515599A ES515599A ES8306470A1 ES 8306470 A1 ES8306470 A1 ES 8306470A1 ES 515599 A ES515599 A ES 515599A ES 515599 A ES515599 A ES 515599A ES 8306470 A1 ES8306470 A1 ES 8306470A1
- Authority
- ES
- Spain
- Prior art keywords
- reaction
- phosgene
- continuous preparation
- chloroformic
- alkyl esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- -1 alkyl chloroformates Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 238000007872 degassing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/02—Preparation of esters of carbonic or haloformic acids from phosgene or haloformates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE CLOROFORMIATOS DE ALQUILO EN CONTINUO. CONSISTE EN LA REACCION DE LOS ALCOHOLES CORRESPONDIENTES CON FOSGENO EN EXCESO. LA REACCION SE LLEVA A CABO EN CONTRACORRIENTE A TEMPERATURAS ENTRE 0 C Y 30 C, DE MODO QUE HAYA SIEMPRE UN EXCESO DE 3-20% DE FOSGENO. LA MEZCLA DE REACCION SE DESGASIFICA EN UNA ETAPA POSTERIOR Y LOS GASES SE RETORNAN A LA REACCION DESPUES DE SEPARAR EL CLOROFORMIATO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813135947 DE3135947A1 (de) | 1981-09-10 | 1981-09-10 | Verfahren zu kontinuierlichen herstellung von chlorameisensaeurealkylestern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES515599A0 ES515599A0 (es) | 1983-06-01 |
| ES8306470A1 true ES8306470A1 (es) | 1983-06-01 |
Family
ID=6141348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES515599A Expired ES8306470A1 (es) | 1981-09-10 | 1982-09-09 | Procedimiento para la obtencion continua de cloroformiatos de alquilo. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0075145B1 (es) |
| JP (1) | JPS5857345A (es) |
| DE (2) | DE3135947A1 (es) |
| ES (1) | ES8306470A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4574649A (en) * | 1982-03-10 | 1986-03-11 | B. D. Yim | Propulsion and speed change mechanism for lever propelled bicycles |
| US5298646A (en) * | 1993-07-22 | 1994-03-29 | Ppg Industries, Inc. | Synthesis of monochloroethyl chloroformates by free radical initiated chlorination of ethyl chloroformate |
| FR2818640B1 (fr) | 2000-12-22 | 2004-02-13 | Poudres & Explosifs Ste Nale | Procede de synthese de chloroformiates aliphatiques, cycloaliphatiques ou araliphatiques |
| CN109438242A (zh) * | 2018-12-30 | 2019-03-08 | 安徽广信农化股份有限公司 | 一种高纯度氯甲酸乙酯的制备方法 |
| CN112961055B (zh) * | 2021-02-01 | 2026-04-21 | 天津市天地创智科技发展有限公司 | 一种氯甲酸酯的连续制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2778846A (en) * | 1954-02-26 | 1957-01-22 | Columbia Southern Chem Corp | Chloroformate production |
| DE2251206C3 (de) * | 1972-10-19 | 1986-01-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Chlorkohlensäureestern |
-
1981
- 1981-09-10 DE DE19813135947 patent/DE3135947A1/de not_active Withdrawn
-
1982
- 1982-08-31 EP EP82107999A patent/EP0075145B1/de not_active Expired
- 1982-08-31 DE DE8282107999T patent/DE3261006D1/de not_active Expired
- 1982-09-07 JP JP57154743A patent/JPS5857345A/ja active Pending
- 1982-09-09 ES ES515599A patent/ES8306470A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0075145A1 (de) | 1983-03-30 |
| JPS5857345A (ja) | 1983-04-05 |
| ES515599A0 (es) | 1983-06-01 |
| DE3261006D1 (en) | 1984-11-22 |
| EP0075145B1 (de) | 1984-10-17 |
| DE3135947A1 (de) | 1983-03-24 |
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