ES8506561A1 - Un procedimiento para enriquecer gas de sintesis con el fin de lograr selectividad para alcanos y alcoholes. - Google Patents

Un procedimiento para enriquecer gas de sintesis con el fin de lograr selectividad para alcanos y alcoholes.

Info

Publication number
ES8506561A1
ES8506561A1 ES532048A ES532048A ES8506561A1 ES 8506561 A1 ES8506561 A1 ES 8506561A1 ES 532048 A ES532048 A ES 532048A ES 532048 A ES532048 A ES 532048A ES 8506561 A1 ES8506561 A1 ES 8506561A1
Authority
ES
Spain
Prior art keywords
synthesis gas
upgrading
catalysts
ruthenium
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES532048A
Other languages
English (en)
Other versions
ES532048A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/332,771 external-priority patent/US4377643A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES532048A0 publication Critical patent/ES532048A0/es
Publication of ES8506561A1 publication Critical patent/ES8506561A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/08—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/22—Carbides
    • C07C2527/224—Silicon carbide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/24—Nitrogen compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

METODO DE TRATAMIENTO DE GAS DE SINTESIS PARA LA PRODUCCION PREFERENCIAL DE HIDROCARBUROS E HIDROCARBUROS OXIGENADOS.CONSISTE EN SOMETER LA MEZCLA DE MONOXIDO DE CARBONO E HIDROGENO, EN FASE DE VAPOR, A UNA TEMPERATURA DE REACCION NO INFERIOR A 250JC Y A UNA PRESION ENTRE 35 Y 350 KG/CM2, EN PRESENCIA DE UN CATALIZADOR DE FORMULA AARUBCUCMDNZOX, EN LA QUE A ES UN METAL ALCALINO, MK ES RH, PD, IR O PT, O SUS MEZCLAS, A VALE 0,002 A 0,5, B Y C VALEN 0,5 A 3, D 0,05 A 0,5, Z ES 0 A 1, Y X ES EL NUMERO DE ATOMOS DE OXIGENO NECESARIOS PARA SATISFACER LA VALENCIA.TIENE APLICACIONES PARA LA PRODUCCION DE ALCANOS Y ALCOHOLES.
ES532048A 1981-12-21 1984-04-30 Un procedimiento para enriquecer gas de sintesis con el fin de lograr selectividad para alcanos y alcoholes. Expired ES8506561A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33277281A 1981-12-21 1981-12-21
US06/332,771 US4377643A (en) 1981-12-21 1981-12-21 Upgrading synthesis gas

Publications (2)

Publication Number Publication Date
ES532048A0 ES532048A0 (es) 1985-08-01
ES8506561A1 true ES8506561A1 (es) 1985-08-01

Family

ID=26988375

Family Applications (2)

Application Number Title Priority Date Filing Date
ES518364A Granted ES518364A0 (es) 1981-12-21 1982-12-20 Un procedimiento para enriquecer gas de sintesis con el fin de obtener selectividad para olefinas y acidos carboxilicos.
ES532048A Expired ES8506561A1 (es) 1981-12-21 1984-04-30 Un procedimiento para enriquecer gas de sintesis con el fin de lograr selectividad para alcanos y alcoholes.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES518364A Granted ES518364A0 (es) 1981-12-21 1982-12-20 Un procedimiento para enriquecer gas de sintesis con el fin de obtener selectividad para olefinas y acidos carboxilicos.

Country Status (7)

Country Link
EP (2) EP0082692B1 (es)
KR (1) KR840002890A (es)
AU (2) AU557908B2 (es)
CA (1) CA1195678A (es)
DE (1) DE3278031D1 (es)
ES (2) ES518364A0 (es)
NO (1) NO159144C (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4797382A (en) * 1987-11-27 1989-01-10 Gaf Corporation Hydrogenation catalyst and process for preparing the catalyst
GB9504708D0 (en) * 1995-03-08 1995-04-26 Bp Chem Int Ltd Process
US8502001B2 (en) 2007-11-14 2013-08-06 Bp P.L.C. Process for the production of alcohol from a carbonaceous feedstock
CN105143157B (zh) * 2013-04-24 2018-11-13 沙特基础工业公司 从天然资源产生产物

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1831179A (en) * 1925-08-28 1931-11-10 Selden Co Process of producing reduction products of carbon dioxide
US2779802A (en) * 1953-05-18 1957-01-29 Shell Dev Synthesis of oxygenated compounds
GB825762A (en) * 1955-06-04 1959-12-23 Degussa Process for the catalytic production of hydrocyanic acid and hydrogen from mixtures of hydrocarbon and ammonia
GB1219282A (en) * 1967-01-13 1971-01-13 Gas Council Improvements relating to catalysts
AU475486B2 (en) * 1971-11-19 1976-08-26 Mitsubishi Chemical Industries Limited Process for hydrating an unsaturated nitrile
US3901827A (en) * 1972-09-27 1975-08-26 Exxon Research Engineering Co Multimetallic catalysts
JPS53755B2 (es) * 1973-02-14 1978-01-11
JPS5332358B2 (es) * 1973-05-28 1978-09-07
US4085157A (en) * 1974-10-11 1978-04-18 Societe Francaise Des Produits Pour Catalyse New catalysts for hydrocarbon conversion to aromatics
US4261927A (en) * 1976-07-15 1981-04-14 Phillips Petroleum Company Hydrogenation of olefinically unsaturated compounds
NL7704658A (nl) * 1977-04-28 1978-10-31 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US4206134A (en) * 1979-03-12 1980-06-03 Exxon Research & Engineering Co. Ruthenium supported on manganese oxide as hydrocarbon synthesis catalysts in CO/H2 reactions
ZA802237B (en) * 1979-04-24 1981-11-25 British Petroleum Co Process for the production of c1 to c4 oxygenated hydrocarbons
US4235798A (en) * 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
CA1173059A (en) * 1980-04-21 1984-08-21 David W. Smith Manufacture of oxygenated compounds

Also Published As

Publication number Publication date
NO159144C (no) 1988-12-07
ES8407085A1 (es) 1984-08-16
NO824284L (no) 1983-06-22
AU9091982A (en) 1984-06-28
AU582026B2 (en) 1989-03-09
NO159144B (no) 1988-08-29
EP0196732A1 (en) 1986-10-08
KR840002890A (ko) 1984-07-21
ES532048A0 (es) 1985-08-01
EP0082692A3 (en) 1984-09-12
AU6512686A (en) 1987-02-12
ES518364A0 (es) 1984-08-16
EP0082692A2 (en) 1983-06-29
CA1195678A (en) 1985-10-22
DE3278031D1 (en) 1988-03-03
AU557908B2 (en) 1987-01-15
EP0196732B1 (en) 1989-03-01
EP0082692B1 (en) 1988-01-27

Similar Documents

Publication Publication Date Title
MY110723A (en) Process for the catalytic partial oxidation of hydrocarbons
DE69905467D1 (de) Katalytische teiloxidation mit einem rhodium-iridium legierungskatalysator
ES2002724A6 (es) Procedimiento para la fabricacion de 2-etilhexanol
MY110253A (en) Process for preparing carboxylic acids.
AU596980B2 (en) Hydrogenation of carboxylic acid esters to alcohols
DE60103387D1 (de) Carbonylierung von niedrigen aliphatischen alkoholen und ihre derivate unter verwendung von metallen auf karbonisierten und polysulfonierten divinylbenzol-styrolcopolymeren
ES448240A1 (es) Un procedimiento para la preparacion de productos de hidro- formilacion.
ES8407085A1 (es) Un procedimiento para enriquecer gas de sintesis con el fin de obtener selectividad para olefinas y acidos carboxilicos.
NO308894B1 (no) FremgangsmÕte for Õ fremstille 1,3-propandiol
ES424623A1 (es) Un procedimiento de produccion de hidrocarburos aromaticos.
Inoue et al. Synthesis of formates from alcohols, carbon dioxide, and hydrogen catalysed by a combination of group VIII transition-metal complexes and tertiary amines
NZ196076A (en) Production of oxygenated hydrocarbons from carbon monoxide and hydrogen using rhodium catalyst
ES437152A1 (es) Un procedimiento mejorado para la hidrogenacion de hidrocar-buros olefinicamente insaturados.
GB1165141A (en) Hydrogenation process for Treating a Lignin-Containing Material
IT8922661A0 (it) Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato
ES468569A1 (es) Procedimiento para la fabricacion de 2,3-dimetilpentanal.
JPS54160347A (en) Manufacture of triphenylphosphine
EP0295797A3 (en) Process for the selective reduction of 2-quinoxaline-4-oxides
Tsuji et al. Organic Syntheses by Means of Noble Metal Compounds. XIX. The Hydroformylation Reaction Catalyzed by Metallic Palladium.
JPS56110645A (en) Purifying method of dicarboxylic acid diester
GB1497627A (en) Hydroformylation process
ATE26256T1 (de) Katalytisches system fuer die hydroformylierung von olefinen und hydroformylierungsverfahren.
TW354265B (en) Process for the scrubbing of chlorine from a cmlorine-containing gas
ES8200236A1 (es) Procedimiento para la elaboracion hidrogenadora de los cata-lizadores que contienen cobalto,utilizados para hidrocarbo- xilacion
Goldsworthy et al. Complexes of long alkyl chain tertiary phosphines: Part 5. Homogeneous catalytic hydrogenation of methyl linoleate and methyl linolenate using the complexes [MCl2 (PR3) 2], M= Pd, Pt; R= n-alkyl, pn-alkylphenyl, in the presence of tin (II) chloride